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Dilution reinitiated oscillations in the Bray-Liebhafsky system

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Abstract

The resumption of oscillatory trains in the non-oscillatory region subsequent to completion of the last oscillation, as a phenomenon interesting for the stability of any reaction which can reach the oscillatory state in principle, is analyzed here for the case of the Bray-Liebhafsky reaction. It is shown that this effect is affected by temperature, acidity, initial concentration of hydrogen peroxide and quantity of added water.

Abstract

Для случая реакций Брэй-Либхавского анализировали явление, характерное для стабильности данной реакции, в принципе способной к достижению осцилляционного состояния, а именно возрождение осцилляционных стадий в неосцилляционном режиме после окончания последней осцилляции. Показано, что температура, кислотность, начальная концентрация перекиси водорода и количество добавленной воды влияют на этот эффект.

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Authors and Affiliations

  1. Institute of Physical Chemistry, Faculty of Science, University of Belgrade, P.O. Box 550, YU-11001, Belgrade, Yugoslavia

    S. Aniċ, Lj. Kolar-Aniċ, D. Stanisavljev, N. Begović & D. Mitić

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  1. S. Aniċ
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  2. Lj. Kolar-Aniċ
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  3. D. Stanisavljev
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  4. N. Begović
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  5. D. Mitić
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Aniċ, S., Kolar-Aniċ, L., Stanisavljev, D. et al. Dilution reinitiated oscillations in the Bray-Liebhafsky system. React Kinet Catal Lett 43, 155–162 (1991). https://doi.org/10.1007/BF02075427

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  • DOI: https://doi.org/10.1007/BF02075427

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