Abstract
The kinetics of oxidation of vanadium(III) by hydroxylamine have been investigated at high acidities in the temperature range 25–30 °C. Rates decreased with increasing acidity of the medium. Both NH2OH and NH3OH+ are capable of oxidizing V(III) in parallel reactions, the order being unity each in oxidant and reductant.
Abstract
Кинетика окисления ванадия(III) гидроксиламином была исследована при высоких кислотностях и в интервале температур 25–30 °C. Скорости уменьшаются с увеличением кислотности среды. Оба NH2OH и NH3OH+ способны окислять V(III) в параллельных реакцях, порядок реакции равен единице как по окислителю, так и по восстановителю.
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Varaprasad, D.V.P.R., Mahadevan, V. Kinetics of oxidation of vanadium(III) by hydroxylamine in acid medium. React Kinet Catal Lett 21, 473–477 (1982). https://doi.org/10.1007/BF02095844
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DOI: https://doi.org/10.1007/BF02095844