Skip to main content
SpringerLink
Log in

Possibilities of two non-isothermal procedures (temperature- or rate-controlled) for kinetical studies

  • Published:
Journal of thermal analysis Aims and scope Submit manuscript

Abstract

The applicability of both conventional Thermal Analysis (TA) and Controlled Rate Thermal Analysis (CRTA) for kinetic analysis is discussed. It is shown that TA method can give a reliable kinetic information and meaningful kinetic parameters especially for solid state transformation. On the other hand the CRTA method is more suitable for decomposition process where one or more gasses are evolved.

A consistent and reliable method of kinetic analysis is proposed for both techniques. This method is illustrated to analyze the crystallization process of chalcogenide glass and the decomposition of dolomite.

Zusammenfassung

Es wird die Anwendbarkeit von herkömmlicher Thermoanalyse (TA) und geschwindigkeitsgesteuerter Thermoanalyse (CRTA) bei kinetischen Untersuchungen diskutiert. Die TA Technik kann eine zuverlässige kinetische Information und sinnvolle kinetische Parameter besonders bei Feststoffumsetzungen liefern. Die CRTA Technik ist andererseits mehr für Zersetzungsprozesse geeignet, bei denen ein oder mehrere Gase freigesetzt werden.

Für beide Techniken wird eine einheitliche und geeignete Methode zu kinetischen Analyse vorgeschlagen. Als Beispiel wird diese Methode zur Analyse des Kristallisationsprozesses von Chalkogenidgläsern sowie der Zersetzung von Dolomit angewendet.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. Sesták, Thermophysical Properties of Solids, Their Measurements and Theoretical Analysis, Elsevier, Amsterdam 1984.

    Google Scholar 

  2. J. Rouquerol, Bull. Chem. Soc. Fr., (1964) 31, J. Thermal. Anal., 2 (1970) 123, Thermochim. Acta, 144 (1989) 209.

  3. N. Koga, J. šesták, Thermochim. Acta, 182 (1991) 201.

    Article  Google Scholar 

  4. H. E. Kissinger, Anal. Chem., 29 (1957) 1702.

    Article  Google Scholar 

  5. J. M. Criado, A. Ortega, J. Non-Cryst. Solids, 87 (1986) 302.

    Article  Google Scholar 

  6. T. Ozawa, J. Therm. Anal., 2 (1979) 301.

    Google Scholar 

  7. E. S. Freeman, B. Carroll, J. Phys. Chem., 62 (1958) 394.

    Article  Google Scholar 

  8. J. M. Criado, J. Málek, A. Ortega, Thermochim. Acta, 147 (1989) 377.

    Article  Google Scholar 

  9. J. Málek, Thermochim. Acta, 138 (1989) 337.

    Article  Google Scholar 

  10. G. I. Senum, R. T. Yang, J. Thermal Anal., 11 (1977) 445.

    Article  Google Scholar 

  11. J. Málek, V. Smrcka, Thermochim. Acta, 186 (1991) 153.

    Article  Google Scholar 

  12. J. Málek, J. M. Criado, Thermochim. Acta, 175 (1991) 305.

    Article  Google Scholar 

  13. V. M. Gorbatchev, J. Thermal. Anal., 27 (1983) 151.

    Article  Google Scholar 

  14. V. šatava, Thermochim. Acta, 2 (1971) 423.

    Article  Google Scholar 

  15. S. Bordère, R. Fourcade, F. Rouquerol, A. Floreancig, J. Rouquerol, J. Chim. Phys., 87 (1990) 1233.

    Google Scholar 

  16. J. M. Criado, A. Ortega, F. Gotor, Thermochim. Acta, 157 (1990) 171.

    Article  Google Scholar 

  17. J. M. Criado, J. Málek, F. J. Gotor, Thermochim. Acta, 158 (1990) 205.

    Article  Google Scholar 

  18. J. H. Sharp, W. Brindley, B. M. Narahari Acker, J. Amer. Ceram. Soc., 49 (1966) 379.

    Google Scholar 

  19. F. Rouquerol, J. Rouquerol in H. G. Wiedeman (Ed.) Thermal Analysis vol. 1, Birkhäuser, Basel 1972, p. 373.

    Google Scholar 

  20. S. Bordère, F. Rouquerol, J. Rouquerol, J. Estienne, A. Floreancig, J. Thermal Anal., 36 (1990) 1651.

    Article  Google Scholar 

  21. A. Ortega, S. Akhouayri, F. Rouquerol, J. Rouquerol, Thermochim. Acta, 163 (1990) 25.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Joint Laboratory of Solid State Chemistry of the Czech Acad. sci. and the University of Chemical Technology, CS. Legi Sq. 565, 532 10, Pardubice, Czech and Slovak F.R.

    J. Málek

  2. Institute of Physics of the Czech Academy of Sciences, NA Slovance 2, 180 40, Prague, Czech and Slovak F.R.

    J. šesták

  3. Universite de Provence, Place Victor Hugo, 133 31, Marseille, France

    F. Rouquerol

  4. Centre de Thermodynamique et de Microcalorimetrie du CNRS, 26 Rue du 141 EME R.I.A., 130 03, Marseille, France

    J. Rouquerol

  5. Instituto de Ciencias de Matriales, C.S.I.C., Universidad de Sevilla, 41 071, Sevilla, Spain

    J. M. Criado & A. Ortega

Authors
  1. J. Málek
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. šesták
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. F. Rouquerol
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. J. Rouquerol
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. J. M. Criado
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. Ortega
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

This text includes one invited lecture and two poster contributions presented during the 5th European Symposium on Thermal Analysis and Calorimetry, Nice.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Málek, J., šesták, J., Rouquerol, F. et al. Possibilities of two non-isothermal procedures (temperature- or rate-controlled) for kinetical studies. Journal of Thermal Analysis 38, 71–87 (1992). https://doi.org/10.1007/BF02109109

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02109109

Keywords

Search

Navigation