Skip to main content
SpringerLink
Log in

A simple molecular model for adsorption chromatography. VII. Relationship between the RM value and the composition for phenols in systems of the type (cyclohexane+polar solvent)/silica

  • Originals
  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

The effect of the composition of binary developing solvents on RM values of phenols with one, two or three hydroxyl groups was investigated. In most cases linear RM vs. (log XS) relationship were obtained for wide composition ranges (XS — mole fraction of polar solvent; diluting solvent: cyclohexane), the slope of the lines being related to the molecular mechanism of adsorption. The slopes of some derivatives of quinoline, aniline and phenols are compared and the effects of the molecular structure of the solute and the eluen strength of solvent are discussed. The experimental data for phenols are interpreted in terms of competitive solvation in the mobile phase by electron donor solvents; practical rules concerning optimization of TLC systems for the analysis of the compounds investigated are formulated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L. R. Snyder, Principles of Adsorption Chromatography, Marcel Dekker, New York, N. Y. 1968

    Google Scholar 

  2. L. R. Snyder, in J. J. Kirkland ed., Modern Practice of N. H. 1972, Chapter 4.

  3. I. R. Snyder, Anal. Chem. Instrument.3, 251 (1964)

    CAS  Google Scholar 

  4. L. S. Bark, R. J. T. Graham, J. Chromatogr.27, 109 (1967).

    CAS  Google Scholar 

  5. L. S. Bark, R. J. T. Graham, J. Chromatogr.27, 116 (1967)

    CAS  Google Scholar 

  6. S. Hermanek, V. Schwartz, Z. Cekan, Collection Czech. Chem. Commun.28, 2031 (1963)

    CAS  Google Scholar 

  7. M. H. Klouwen, R. Ter Heide, J. G. J. Kok, inL. R. Snyder, Principles of Adsorption Chromatography, Marcel Dekker, New York, N. H. 1968, p 219

    Google Scholar 

  8. L. R. Snyder, J. Chromatogr.63, 15 (1971).

    CAS  Google Scholar 

  9. A. Waksmundzki, J. Rozylo, Chem. Anal.14, 1217 (1969)

    CAS  Google Scholar 

  10. E. Soczewinski, Anal. Chem.41, 179 (1969)

    Article  CAS  Google Scholar 

  11. E. Soczewinski, Ann. Univ. M. Curie Sklodowska, Lublin, Polonia, Sec. D.24, 21 (1969)

    CAS  Google Scholar 

  12. E. Soczewinski, W. Golkiewicz, Chromatographia5, 431 (1972)

    CAS  Google Scholar 

  13. W. Golkiewicz, E. Soczewinski, Chromatographia5, 594 (1972)

    CAS  Google Scholar 

  14. E. Soczewinsky, W. Golkiewicz, H. Szumilo, J. Chromatogr.45, 1 (1969)

    Google Scholar 

  15. E. Soczewinski, G. Matysik, J. Chromatogr.48, 57 (1970)

    Article  CAS  Google Scholar 

  16. E. Soczewinski, G. Matysik, Intern. Symp. VI. Chromatogr. Electrophorese, Presses Acad. Eur. Bruxelles (1971)

    Google Scholar 

  17. E. Soczewinski, W. Golkiewicz, Chromatographia4, 501 (1971)

    CAS  Google Scholar 

  18. G. C. Pimentel, A. L. McClellan, The Hydrogen Bond, Freeman, San Francisco, Calif., 1960

    Google Scholar 

  19. A. B. Littlewood, F. W. Willmott, Anal. Chem.38, 1031 (1966)

    CAS  Google Scholar 

  20. M. Przyborowska, in press

  21. J. Oscik, J. K. Różyło, Chromatographia4, 516 (1971)

    CAS  Google Scholar 

  22. E. Soczewinski, W. Golkiewicz, Chem. Analit., Warsaw14, 465 (1969)

    CAS  Google Scholar 

  23. E. Soczewinski, H. Szumilo, inpress (J. Chromatog.)

  24. W. Ia. Davidov, A. W. Kiselev, W. I. Lygin, Koll. Zhurn.21, 152 (1963)

    Google Scholar 

  25. L. R. Snyder, inM. Lederer, ed., Chromatogr. Revs., Vol 7 (1965)

Download references

Author information

Authors and Affiliations

  1. Department of Inorganic and Analytical Chemistry, Medical Academy, Lublin, Poland

    E. Soczewinski & W. Golkiewicz

Authors
  1. E. Soczewinski
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. W. Golkiewicz
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Soczewinski, E., Golkiewicz, W. A simple molecular model for adsorption chromatography. VII. Relationship between the RM value and the composition for phenols in systems of the type (cyclohexane+polar solvent)/silica. Chromatographia 6, 269–273 (1973). https://doi.org/10.1007/BF02282823

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02282823

Keywords

Search

Navigation