Abstract
The Na+-humate sol is studied as a surface active substance (surfactant) capable of lowering the surface tension of water, and of spreading on the water surface with observable velocity to form a thin film. Based on these properties, it is concluded that sol should contain molecules of intermediate molecular weight as well as their associates (micelles) whose weight depends on the number of molecules in the micelles.
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References
Braids, O. C. and Miller, R. H. 1975 Fats, waxes and resins in soils.In Soil Components, Vol. 1 Organic Components Ed. J. E. Gieseking pp. 343–368. N.Y. Springer-Verlag.
Chen, V. and Schnitzer, M. 1977 The surface tension of aqueous solutions of soil humic substances. Soil Sci.125, 7–22.
Dragunov, S. S. 1962 The chemistry of humic acid.In Humic Fertilisers,3, 11–20. Kiev.
Davies, J. T. 1951 The distribution of ions under a charged monolayer and a surface equation of state for charged films. Proc. Roy. Soc. (L)208, 224–247.
Dubach, P. and Mehta, N. C. 1963 The chemistry of soil humic substances. Soil Fert.24, 293–300.
Everett, D. H. 1972 Definition, terminology and symbols in colloid and surface chemistry. Pure Appl. Chem.31, 579–638.
Flaig, W., Beutelspacher H. and Reitz, E. 1975 Chemical composition and physical properties of humus substances.In Soil Components. Vol. 1 Organic Components. Ed. J. E. Gieseking pp. 1–211, Springer-Verlag, New York.
Greenland, D.J. and Cades, J. M. 1975 SaccharidesIn Soil Components. Vol. 1 Organic Components. Ed. J. E. Gieseking. pp. 213–261, N.Y.. Springer-Verlag.
Ghosh, K. and Schnitzer, M. 1980 Macromolecular structures of humic substances. Soil Sci.129, 266–276.
Kononova, M. M. 1966 Soil Organic Matter: Pergamon, London.
McCleary, J. J. and Snoeyink., V. L. 1980 Characterisation and activated carbon adsorption of several humic substances. Water Res.14, 151–160.
O'Brien, R. N., Feherer, A. I. and Leja, J. 1976 Spreading of monolayers at the air-water interface. II. Spreading speeds for alcohols, acids, esters, suphonates, amines, quaternary ammonium ions and some binary mixtures. J. Colloid Intert.56, 474–482.
Oden, S. 1919 The humus acid in their chemistry physics and soil science. Kolloid Beih.2, 75–260.
Scheffer, F. and Ulrich, B. 1960. Humus und Humus Bildung I, Stuttgart, F. Enke.
Schnitzer, M. and Khan, S. U. 1972 The humic substances in the environment Dekker, New York.
Schnitzer, M. and Neyron, J. A. 1975 Alkanes and fatty acids in humic substances. Fuel54 17–19.
Schwartz, E. G. and Reid, W. G. 1965 Chemistry and Physics of Interface, pp. 65–71. Am. Chem. Soc.
Shitz, L. A., Dikhtievskaya, L. V., Krukovskii, S. P., Cherednichenko, L. V. and Ponomarenko, V. A. 1976 Colloidal chemical properties of the solutions of surfactants on the basis of perfluorpropylene oxide oligomers. Kolloidn. Zh.38, 1130–1134.
Stevenson, F. T. and Gog, K. M. 1971 Infrared spectra of humic acid and related substances. Geoch. Cosmochim. Acta35, 534–557.
Tanford, C. 1973 The hydrophobic effect. J. Wiley, N.Y.
Tschapek, M. and Wasowki, C. 1976 The surface activity of humic acid. Geoch. Cosmochim. Acta40, 1343–1345.
Tschapek, M., Scoppa, C. and Wasowski, C. 1978 On the surface activity of humic acid. Z. Pflanzenernaehr. Bodenkd.141, 203–207.
Tschapek, M., Wasowski, C., Scoppa, C. and Torres Sánchez, R. M. 1980 On the surface activity of humic acid. Agrochimica24, 30–38.
Tschapek, M. und Sakun, N. 1941 Uber die Wechselwirkung des humates mit den mineralischen Bestandteilen des Boden. Kolloid-Z107, 41–55.
Tschapek, M., Pozzo Ardizi, G. and de Bussetti, S. 1973 Wettability of humic acid and its salts. Z. Pflanzenernaehr. Bodenkd.135, 16–31.
Wennerstrom, H. and Lindman, B. 1979 Micelles, physical chemistry of surfactant association. Phys. Rep.52, 1–86.
Van Dijk, H. 1971. Colloidal chemical properties of humic matter.In: Soil Biochemistry. Ed. Laren-Skyins. pp 16–35, Dekker, New York.
Wershaw, R. L. and Bohner, G. E. 1969 Pyrolysis of humic and fulvic acids. Geoch. Cosmochim. Acta33, 757–762.
Woytski, S. S. 1975 Colloid Chemistry, 2nd Ed Khimia, Moscow.
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Tschapek, M., Wasowski, C. & Sánchez, R.M.T. Humic acid as a colloidal surfactant. Plant Soil 63, 261–271 (1981). https://doi.org/10.1007/BF02374604
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DOI: https://doi.org/10.1007/BF02374604