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Effect of oxides on binder burnout during ceramics processing

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Abstract

The burnout of poly (vinyl butyral) from green bodies of oxide ceramics was studied by thermogravimetric analysis and infrared spectroscopy. The decomposition of the polymer to release butyraldehyde, in air or in argon, was enhanced by the presence of the oxide powders. The degree of enhancement was much greater in the presence of oxygen. Ceria gave rise to a separate oxidation process at lower temperatures. The concentration of carbon remaining after treatment to 1000° C was correlated with surface activity.

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Author notes

  1. Paul D. Calvert

    Present address: School of Chemistry and Molecular Sciences, University of Sussex, Falmer, BN1 9QJ, Brighton, UK

Authors and Affiliations

  1. Ceramics Processing Research Laboratory, Materials Processing Center, Massachusetts Institute of Technology, 02139, Cambridge, Massachusetts, USA

    Steven Masia, Paul D. Calvert, Wendell E. Rhine & H. Kent Bowen

Authors
  1. Steven Masia
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  2. Paul D. Calvert
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  3. Wendell E. Rhine
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  4. H. Kent Bowen
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Masia, S., Calvert, P.D., Rhine, W.E. et al. Effect of oxides on binder burnout during ceramics processing. J Mater Sci 24, 1907–1912 (1989). https://doi.org/10.1007/BF02385397

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  • DOI: https://doi.org/10.1007/BF02385397

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