Abstract
The existence of fast electron exchange between pairs of Fe3+⇄Fe2+ ions was detected in Mössbauer spectra of non-stoichiometric CoNiZn ferrites containing an excess of Fe2O3. Analysis of spectra from a number of samples of various preparations showed correlation of bulk magnetic properties with hyperfine parameters of ferric ions at octahedral sites in the spinel structure.
Similar content being viewed by others
References
P.J. Slick, in Ferromagnetic materials, ed. E.P. Wohlfarth, vol. 2 (North Holland, Amsterdam, 1980) p. 189.
J.G.M. De Lau and A. Brose Van Groenou, Jour. Physique Colloq. 38 (1977) C1–17
C.M. Srivastava, S.N. Shringi, M.J. Patni and S.M. Joglekar, Bull. Mat. Sci 6 (1984) 7.
M. Drofenik, S. Beseničar, D. Kolar, Ceram. Bull. 63 (1984) 699. S. Beseničar and M. Drofenik, British Ceramics, in press
A.M. Van Diepen and F.K. Lotgering, Sol. State Com. 27 (1978) 255.
Z.M. Stadnik and Y. Kawai, J. Phys. Soc. Jap. 53 (1984) 2761.
T.M. Uen and P.K. Tseng, Phys. Rev. B25 (1982) 1848. S.C. Bhargava and N. Zeeman, Phys. Rev. B21 (1980) 1717.
J.M.D. Coey, Phys. Rev. B6 (1972) 3240.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Hanžel, D., Beseničar, S. & Hanzel, D. Mössbauer effect study of nonstoichiometric CoNiZn ferrites. Hyperfine Interact 29, 1487–1490 (1986). https://doi.org/10.1007/BF02399516
Issue Date:
DOI: https://doi.org/10.1007/BF02399516