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Transfer hydrogenation of ketones catalyzed by ruthenium complexes

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Abstract

Catalytic hydrogen transfer in the acetophenone/propan-2-ol system by complexes formedin situ of RuCl3 and the ligands ofo-phenylene diamine (PDA);o-aminophenol (APO);o-aminobenzoic acid (ABA); 2,2′-dipyridyl (BIPY), has been studied. The effect of APO/Ru ratio indicates the homogeneous nature of the catalytic process, proved by the absence of the inhibiting effect of added mercury (Hg). The experimental results show that RuCl3/APO exhibits fairly high catalytic activity even if under the air.

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Authors and Affiliations

  1. Department of Applied Chemistry, Fushun Petroleum Institute, 113001, Fushun, P. R. China

    H. Jiang, Q. D. Qiao & H. Gong

Authors
  1. H. Jiang
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  2. Q. D. Qiao
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  3. H. Gong
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Jiang, H., Qiao, Q.D. & Gong, H. Transfer hydrogenation of ketones catalyzed by ruthenium complexes. React Kinet Catal Lett 65, 193–197 (1998). https://doi.org/10.1007/BF02475334

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  • DOI: https://doi.org/10.1007/BF02475334

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