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Kinetic studies on the aminolysis of someO-aryl oximes in benzene

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Abstract

Pyrrolidinolysis and piperidinolysis ofO-aryl oximes show third order dependence on amine with no uncatalytic route. The effect of temperature on separate routes and overall rate is reported and explained.

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References

  1. J.F. Bunnett, C.F. Bernasconi:J. Org. Chem.,35, 70 (1970).

    Article  CAS  Google Scholar 

  2. J.A. Orvik, J.F. Bunnett:J. Am. Chem. Soc.,92, 4217 (1970).

    Article  Google Scholar 

  3. T.O. Bamkole, J. Hirst:J. Chem. Soc. Perkin Trans. 2, 1317 (1979).

    Google Scholar 

  4. O. Banjoko, P. Otiono:J. Chem. Soc. Perkin Trans. 2, 399 (1981).

    Google Scholar 

  5. J. Hirst, G. Hussain, I. Onyido:J. Chem. Soc. Perkin Trans. 2, 397 (1986).

    Google Scholar 

  6. N.S. Nudelman, K. Marder, A. Gurevich:J. Chem. Soc. Perkin Trans. 2, 229 (1993).

    Google Scholar 

  7. N.S. Nudelman:J. Phys. Org. Chem.,2, 1 (1989).

    Article  CAS  Google Scholar 

  8. O. Banjoko, I.A. Bayeroju:J. Chem. Soc. Perkin Trans. 2, 1853 (1988).

    Google Scholar 

  9. J. Hirst, G.N. Onuoha, I. Onyido:J. Chem. Soc. Perkin Trans. 2, 971 (1988).

    Google Scholar 

  10. E.T. Akinyele, I. Onyido, J. Hirst:J. Chem. Soc. Perkin Trans. 2, 1859 (1988).

    Google Scholar 

  11. L. Forlani:Gazz. Chim. Ital., 0112, 205 (1982).

    CAS  Google Scholar 

  12. L. Forlani:Gazz. Chim. Ital.,121, 475 (1991).

    CAS  Google Scholar 

  13. O. Banjoko, C. Ezeani:J. Chem. Soc. Perkin Trans. 2, 1357 (1982).

    Google Scholar 

  14. N.S. Nudelman, D. Palleros:J. Org. Chem.,48, 1607 (1983).

    Article  CAS  Google Scholar 

  15. A.K. Jain, V.K. Gupta, A. Kumar,J. Chem. Soc. Perkin Trans. 2, 11 (1990).

    Google Scholar 

  16. A.K. Jain, V.K. Gupta, A. Kumar, P. Singh.Ind. J. Chem.,31B, 690 (1992).

    CAS  Google Scholar 

  17. A.I. Vogel:Textbook of Practical Organic Chemistry, p. 812, Longman, London, (1978).

    Google Scholar 

  18. CIBA Ltd., Neth. Pat. 6600834 (1966): Chem. Abstr., 66, 28501a (1967).

  19. P. Sykes:A Guidebook to Mechanism in Organic Chemistry, p. 156, Orient Longman, New Delhi (1989).

    Google Scholar 

  20. J. March:Advanced Organic Chemistry, p. 456, Wiley Eastern Ltd., New Delhi (1992).

    Google Scholar 

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Jain, A.K., Sahoo, B.B., Atray, N. et al. Kinetic studies on the aminolysis of someO-aryl oximes in benzene. React Kinet Catal Lett 63, 171–178 (1998). https://doi.org/10.1007/BF02475447

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  • DOI: https://doi.org/10.1007/BF02475447

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