Abstract
Pyrrolidinolysis and piperidinolysis ofO-aryl oximes show third order dependence on amine with no uncatalytic route. The effect of temperature on separate routes and overall rate is reported and explained.
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J.F. Bunnett, C.F. Bernasconi:J. Org. Chem.,35, 70 (1970).
J.A. Orvik, J.F. Bunnett:J. Am. Chem. Soc.,92, 4217 (1970).
T.O. Bamkole, J. Hirst:J. Chem. Soc. Perkin Trans. 2, 1317 (1979).
O. Banjoko, P. Otiono:J. Chem. Soc. Perkin Trans. 2, 399 (1981).
J. Hirst, G. Hussain, I. Onyido:J. Chem. Soc. Perkin Trans. 2, 397 (1986).
N.S. Nudelman, K. Marder, A. Gurevich:J. Chem. Soc. Perkin Trans. 2, 229 (1993).
N.S. Nudelman:J. Phys. Org. Chem.,2, 1 (1989).
O. Banjoko, I.A. Bayeroju:J. Chem. Soc. Perkin Trans. 2, 1853 (1988).
J. Hirst, G.N. Onuoha, I. Onyido:J. Chem. Soc. Perkin Trans. 2, 971 (1988).
E.T. Akinyele, I. Onyido, J. Hirst:J. Chem. Soc. Perkin Trans. 2, 1859 (1988).
L. Forlani:Gazz. Chim. Ital., 0112, 205 (1982).
L. Forlani:Gazz. Chim. Ital.,121, 475 (1991).
O. Banjoko, C. Ezeani:J. Chem. Soc. Perkin Trans. 2, 1357 (1982).
N.S. Nudelman, D. Palleros:J. Org. Chem.,48, 1607 (1983).
A.K. Jain, V.K. Gupta, A. Kumar,J. Chem. Soc. Perkin Trans. 2, 11 (1990).
A.K. Jain, V.K. Gupta, A. Kumar, P. Singh.Ind. J. Chem.,31B, 690 (1992).
A.I. Vogel:Textbook of Practical Organic Chemistry, p. 812, Longman, London, (1978).
CIBA Ltd., Neth. Pat. 6600834 (1966): Chem. Abstr., 66, 28501a (1967).
P. Sykes:A Guidebook to Mechanism in Organic Chemistry, p. 156, Orient Longman, New Delhi (1989).
J. March:Advanced Organic Chemistry, p. 456, Wiley Eastern Ltd., New Delhi (1992).
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Jain, A.K., Sahoo, B.B., Atray, N. et al. Kinetic studies on the aminolysis of someO-aryl oximes in benzene. React Kinet Catal Lett 63, 171–178 (1998). https://doi.org/10.1007/BF02475447
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DOI: https://doi.org/10.1007/BF02475447