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Oxidation of secondary alcohols byN-methylmorpholine-N-oxide (NMO) catalyzed by atrans-dioxo ruthenium(VI) complex or perruthenate complex: A kinetic study

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Abstract

Thetrans-dioxo ruthenium (VI) complex, [P(C6H5)3C6H5CH2]+[Ru(O)2OAcCl2] or tetrapropylammonium perruthenate catalyzes the oxidation of secondary alcohols to ketones byN-methylmorpholine-N-oxide (NMO). Kinetic studies showed the formation of a complex between catalyst and substrate (alcohol) as the first step in the mechanism.

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References

  1. G. Green, W.P. Griffith, D.M. Hollinshead, S.V. Ley, M. Schroder:J. Chem. Soc. Perkin Trans., 681 (1984).

  2. A.D. White, W.P. Griffith:Proc. Indian Natnl. Sci. Acad.,52, 804 (1986).

    Google Scholar 

  3. W.P. Griffith:Platinum Metals Rev.,33, 181 (1989).

    CAS  Google Scholar 

  4. H. Nataka:Tetrahedron,19 1959 (1963).

    Article  Google Scholar 

  5. C.M. Che, C.Ho, T.C. Lau:J. Chem. Soc. Dalton Trans., 1901 (1991).

  6. C.M. Che:Advances in Inorganic Chemistry,21, 315 (1993).

    Google Scholar 

  7. W.P. Griffith:Chem. Rev., 179 (1992).

  8. A.J. Bailey, W.P. Griffith, S.I. Mustafa, P.A. Sherwood:Inorg. Chem.,32, 268 (1993).

    Article  CAS  Google Scholar 

  9. A.C. Dengel, A.M. EI.Hendawy, W. P. Griffith, C.H.O. Mahoney, D.J. Williams.J. Chem. Soc., Dalton Trans., 737 (1990).

  10. W.P. Griffith, J.M. Jolliffe, S.V. Ley, D.J. Williams:J. Chem. Soc., Chem. Commun., 1219 (1990).

  11. W.P. Griffith, S. V. Ley, G.P. Whitcombe, A.D. White:J. Chem. Soc.,Chem. Commun., 1625 (1987).

  12. D.D. Perrin, W.L.F. Armarego:Purification of Laboratory Chemicals. Pergamon Press, Oxford 1986.

    Google Scholar 

  13. D.G. Lee, L.N. Congson:Can. J. Chem.,68, 1774 (1990).

    Article  CAS  Google Scholar 

  14. K. Behri, H. Narayan, R.S. Shukla, K.C. Gupta:Int. J. Chem. Kinet.,16, 195 (1984).

    Article  Google Scholar 

  15. A.K. Rappe, W.A. Goddard III:J. Am. Chem. Soc.,104, 448, 3287 (1982).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Indian Institute of Technology, 600 036, Madras, India

    K. J. Tony, V. Mahadevan, J. Rajaram & C. S. Swamy

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  1. K. J. Tony
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  2. V. Mahadevan
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  3. J. Rajaram
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  4. C. S. Swamy
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Tony, K.J., Mahadevan, V., Rajaram, J. et al. Oxidation of secondary alcohols byN-methylmorpholine-N-oxide (NMO) catalyzed by atrans-dioxo ruthenium(VI) complex or perruthenate complex: A kinetic study. React Kinet Catal Lett 62, 105–116 (1997). https://doi.org/10.1007/BF02475720

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  • DOI: https://doi.org/10.1007/BF02475720

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