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3-Alkenyl-5-ferrocenyl-2-pyrazolines in reactions with azodicarboxylic acidN-phenylimide

  • Organic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

Azodicarboxylic acidN-phenylimide reacts with 1-acetyl-3-(2-ferrocenylethenyl)-5-ferrocenyl-2-pyrazoline according to the [4+2]-cycloaddition mechanism to form a Diels—Alder adduct. Under analogous conditions, 1-acetyl-5-ferrocenyl-3-(1-cyclohexenyl)-substituted 2-pyrazolines containing allylic hydrogen atoms give monoene addition products.

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Authors and Affiliations

  1. Department of Chemistry, National Autonomous University of Mexico, C. P. 04510, Mexico, D.F., Mexico

    E. I. Klimova, T. Klimova & L. Ruiz Ramirez

  2. Institute of Chemistry, National Autonomous University of Mexico, C.P. 04510, Mexico, D.F., Mexico

    M. Martinez Garcia

Authors
  1. E. I. Klimova
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  2. M. Martinez Garcia
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  3. T. Klimova
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  4. L. Ruiz Ramirez
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 908–913, May, 2000.

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Klimova, E.I., Martinez Garcia, M., Klimova, T. et al. 3-Alkenyl-5-ferrocenyl-2-pyrazolines in reactions with azodicarboxylic acidN-phenylimide. Russ Chem Bull 49, 906–911 (2000). https://doi.org/10.1007/BF02494717

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  • DOI: https://doi.org/10.1007/BF02494717

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