Abstract
The Cp2ZrCl2-catalyzed reaction of arylolefins (styrene,o- andp-methylstyrenes,trans-stilbene, 1,4-diphenyl-1,3-butadiene) with AlEt3 resulting in mono- and disubstituted alumacyclopentanes and substituted alumacyclopropanes was studied. The yield and ratio of cyclic organoaluminum compounds depend on the structure of the initial arylolefins and conditions of cycloalumination.
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For Part 19, see Ref. 1.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1594–1600, August, 1999.
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Ibragimov, A.G., Khafizova, L.O., Satenov, K.G. et al. Synthesis and transformations of metallacycles. Russ Chem Bull 48, 1574–1580 (1999). https://doi.org/10.1007/BF02496415
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DOI: https://doi.org/10.1007/BF02496415