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Cyclization ofN-acetyl-ortho-cycloalkenylanilines on treatment with bromine andN-bromosuccinimide

  • Organic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The reaction ofN-acetyl-2-(cyclohex-1-enyl)aniline with Br2 orN-bromsuccinimide at 20°C is accompanied by intramolecular cyclization to give brominated 3,1-benzoxazines or 4-acetyl-(3-bromo-5-methyl-1,2,3,3a,4,8b-hexahydrocyclopenta[b]indole.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054, Ufa, Russian Federation

    R. R. Gataullin, I. S. Afon'kin, A. A. Fatykhov, L. V. Spirikhin & I. B. Abdrakhmanov

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  1. R. R. Gataullin
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  2. I. S. Afon'kin
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  3. A. A. Fatykhov
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  4. L. V. Spirikhin
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  5. I. B. Abdrakhmanov
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 118–120, January, 2000.

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Gataullin, R.R., Afon'kin, I.S., Fatykhov, A.A. et al. Cyclization ofN-acetyl-ortho-cycloalkenylanilines on treatment with bromine andN-bromosuccinimide. Russ Chem Bull 49, 122–124 (2000). https://doi.org/10.1007/BF02499076

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  • DOI: https://doi.org/10.1007/BF02499076

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