Skip to main content
Log in

Equilibres liquide-vapeur isothermes de melanges binaires formes de composes heterocycliques tels que: Morpholine, tetrahydropyranne, piperidine et 1,4-dioxane

  • Published:
Journal of Thermal Analysis Aims and scope Submit manuscript

Abstract

The authors have measured the vapour pressure of four binary systems, morpholine+piperidine, morpholine+1,4-dioxane, morpholine+tetrahydropyrane and 1,4-dioxane+tetrahydropyrane. The measurements were carried out using an isoteniscope built by J. Jose [1]. The vapour pressure, excess Gibbs free energies at 298.15, 303.15, 313.15, 323.15, 333.15 and 343.15 K are reported for these mixtures. The excess Gibbs free energies have been fitted to the Redlich-Kister equation.

Zusammenfassung

Von den Autoren wurde der Gasdruck der vier binären Systeme Morpholin+Piperidin, Morpholin+1,4-Dioxan, Morpholin+Tetrahydropyran und 1,4-Dioxan+Tetrahydropyran vermessen. Die Messungen wurden mit Hilfe eines von J. Jose [1] gebauten Isoteniskopes durchgeführt. Für diese Gemische werden Gasdruck und überschüssige Gibbs’che freie Energie für 298.15K, 303.15 K, 313.15 K, 323.15 K, 333.15 K und 343.15 K angegeben. Die überschüssige Gibbs’sche freie Energie wurde nach der Redlich-Kister-Gleichung bemessen.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Bibliographie

  1. J. Jose, Thèse de Doctorat de 3ème Cycle, Lyon I, 1970.

  2. J. A. Barker, Austr. J. Chem., 6 (1953) 23.

    Google Scholar 

  3. E. Hala et T. Boublik, Vapour Pressure of Compounds, Elsevier, 1973.

  4. D. V. S. Jain et R. S. Sidhu, J. Chem. Thermodyn., 16 (1984) 111.

    Article  Google Scholar 

  5. S. Cabani et N. Ceccanti, J. Chem. Thermodyn., 5 (1973) 9.

    Article  CAS  Google Scholar 

  6. J. Timmermans, Physico-Chemical Constants of Pure Organic Compounds, Vols 1 and 2, Elsevier, Amsterdam 1950.

    Google Scholar 

  7. Physical Properties of Chemical Compounds, Vols 1 and 2, Advanced Chemical Series 1959.

  8. R. C. Reid, J. M. Prausnitz et B. E. Poling, The properties of Gases and Liquids, 4th ed. McGraw-Hill, 1987.

  9. H. V. Kehiaian, J. P. Grolier et G. C. Benson, J. Chem. Phys. 11/12 (1978) 75.

    Google Scholar 

  10. C. Tsonopoulos, AICHE J., 20 (1974) 263.

    Article  CAS  Google Scholar 

  11. C. Tsonopoulos, AICHE J., 21 (1975) 827.

    Article  CAS  Google Scholar 

  12. C. Pettenati, P. Alessi, M. Fermeglia et I. Kikic, Fluid Phase Equilibria, 54 (1990) 81.

    Article  CAS  Google Scholar 

  13. M. Palczewska-Tulinska, M. Cholinski, A. Safranski et D. Wyrzykowska-Stankiewicz, Fluid Phase Equilibria, 11 (1983) 233.

    Article  CAS  Google Scholar 

  14. B. I. Lee et M. G. Kesler, AICHE J., 21 (1975) 510.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Belaribi, F.B., Belaribi-Boukais, G., Ait-Kaci, A. et al. Equilibres liquide-vapeur isothermes de melanges binaires formes de composes heterocycliques tels que: Morpholine, tetrahydropyranne, piperidine et 1,4-dioxane. Journal of Thermal Analysis 44, 911–927 (1995). https://doi.org/10.1007/BF02547275

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02547275

Keywords

Navigation