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Benzoquinone derived 1,3-dithiole-2-ones and thiones

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Abstract

The syntheses and structures of 1,3-dithiole and tetrathiafulvalene derivatives of benzoquinone have been investigated. This work extends earlier investigations of naphthoquinone analogues. The X-ray structures, NMR, IR, UV, mass spectra, and E0 1/2 values from cyclic voltammetry measurements are reported.Ab initio STO-6-31G calculations are used to correlate the cyclic voltammetry and UV data for selected compounds.

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References

  1. Williams, J.M.; Wang, H.H.; Emge, T.J.; Geiser, U.; Beno, M.A.; Leung, P.C.W.; Carlson, K.D.; Thorn, R.J.; Schultz, A.J.; Whangbo, M.H.Prog. Inorg. Chem. 1987,35, 51.

    Article  CAS  Google Scholar 

  2. Watson, W.H.; Eduok, E.E.; Kashyap, R.P.; Krawiec, M.Tetrahedron 1993,49, 3035.

    Article  CAS  Google Scholar 

  3. Eduok, E.E.; Krawiec, M.; Buisson, Y.-S.L.; O'Conner, C.J.; Sun, D.; Watson, W.H.J. Chem. Crystallogr. 1996,26, 621.

    Article  CAS  Google Scholar 

  4. Harris, R.L.N.; Oswald, L.T.Aust. J. Chem. 1974,27, 1309.

    Article  CAS  Google Scholar 

  5. Sheldrick, G.M.SHELXS86. Program for the Solution of Crystal Structures; Univ. of Göttingen: Germany,1986.

    Google Scholar 

  6. TEXSAN-TEXRAYStructure Analysis Package; Molecular Structure Corporation, Vers. 1.7-1, March1995.

  7. Spek, A.L.,Acta Crystallogr.,1982,29, 203.

    Google Scholar 

  8. Cremer, D.; Pople, J.A.J. Am. Chem. Soc. 1975,97, 1354.

    Article  CAS  Google Scholar 

  9. Gagne, R.R.; Koval, C.A.; Lisensky, G.C.Inorg. Chem. 1980,19, 2854.

    Article  CAS  Google Scholar 

  10. Bondi, A.J. Phys. Chem. 1964,68, 441.

    CAS  Google Scholar 

  11. Ha, T.-K.Mol. Phys. 1983,49, 1471.

    Article  CAS  Google Scholar 

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Sun, D., Krawiec, M. & Watson, W.H. Benzoquinone derived 1,3-dithiole-2-ones and thiones. J Chem Crystallogr 27, 515–526 (1997). https://doi.org/10.1007/BF02576442

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  • DOI: https://doi.org/10.1007/BF02576442

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