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Crystal structure of NH3(CH2)2NH3(BiI4)2·4H2O

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Abstract

The ethylenediammonium bis tetraiodobismuthate(III) tetrahydrate salt is monoclinic with the following unit cell dimensions:a=7.476(3)Å,b=13.194(3)Å,c=13.916(9)Å, β=95.22(6)°, space groupP21 lc withZ=2. The structure consists of disordered ethylenediammonium cations, water molecules and polynuclear anions in which slightly distored [BiI6]3− octahedra sharingcis edges are interconnected into chains. The [BiI4]− anions are connected through O(W2)−H...I hydrogen bonds, so that infinite two dimensional chains parallel to thea axis with anionic period [BiI4(H2O)]− are formed in the structure. These chains are themselves interconnected by means of the O−H...I and N...O(I) bonds originating respectively from the water molecules and the ethylenediammonium entities, forming a three-dimensional network.

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Authors and Affiliations

  1. Laboratoire de Cristallochimie du Solide, ENIS, 3038, Sfax, (Tunisia)

    S. Chaabouni & S. Kamoun

  2. Centre d'Elaboration de Matériaux et d'Etudes Structurales, CNRS, BP 4347, 31055, Toulouse Cedex, France

    J. Jaud

Authors
  1. S. Chaabouni
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  2. S. Kamoun
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  3. J. Jaud
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Chaabouni, S., Kamoun, S. & Jaud, J. Crystal structure of NH3(CH2)2NH3(BiI4)2·4H2O. J Chem Crystallogr 27, 527–531 (1997). https://doi.org/10.1007/BF02576443

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  • DOI: https://doi.org/10.1007/BF02576443

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