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Crystal structure of pentakis ethylenediammonium bis undecachlorodiantimonate(III) tetrahydrate, (NH3(CH2)2NH3)5(Sb2Cl11)2·4H2O

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Abstract

The pentakis ethylenediammonium bis undecachlorodiantimonate(III) tetrahydrate salt is monoclinic with the following unit cell dimensions:a=16.271(5) Å,b=13.004(4) Å,c=13.932(4) Å, β=111.72(2)°, space groupP21/c withZ=2. The structure was solved by Patterson methods and refined to a finalR value of 0.023 for 4435 reflections withF 0>4σ(F 0). The structure shows a layer arrangement perpendicular to thea axis: planes of the [Sb2Cl11]5− bioctahedra alternate with planes of [NH3(CH2)2NH3]2+ dications. The [Sb2Cl11]5− bioctahedra are connected through O−H...Cl hydrogen bonds, such that infinite chains of composition [Sb2Cl11(H2O]n 5n− are formed in the structure, parallel to the twofold axis. These chains are themselves interconnected by means of N−H...Cl and O−H...Cl bonds originating from the [NH3(CH2)2NH3]2+ entities and the water molecules, respectively, and form a threedimensional network.

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References

  1. Porter, S.K.; Jacobson, R.A.J. Chem. Soc. A. 1970, 1356.

  2. Lipka, A.Z.Anorg. Allg. Chem. 1980,469, 218.

    Article  CAS  Google Scholar 

  3. Ensinger, U.; Schwarz, W.; Schmidt, A.Z. Naturforsch. 1982,Teil B,37, 1584.

    Google Scholar 

  4. Whealy, R.D.; Linder, D.E.Inorg. Chem. 1968,2, 49.

    CAS  Google Scholar 

  5. Kallel, A.; Bats, J.W.Acta Crystallogr. 1985,C41, 1022.

    CAS  Google Scholar 

  6. Jakubas, R.; Galewski, Z.; Sobczyk, L. Matuszewski, J.J. Phys. C. Solid State Phys. 1985,18, L857.

    Article  CAS  Google Scholar 

  7. Pauling, L.The Nature of the Chemical Bond, Ithaca: Cornell Univ. Press.,1960, p 260.

    Google Scholar 

  8. Konaka, S., Kimura, M.Bull. Chem. Soc. Jpn. 1973,46, 404.

    Article  CAS  Google Scholar 

  9. Sheldrick, G.M.Program for Crystal Structure Determination; SHELX-86,1990.

  10. Sheldrick, G.M.Program for Crystal Structure Determination; SHELXL-93,1993.

  11. Chaabouni, S.; Kamoun, S.; Daoud, A.,J Alloys Comp. 1995,224, 207.

    Article  CAS  Google Scholar 

  12. Kamoun, S.; Jouini A.; Kamoun, M.; Daoud, A.Acta Crystallogr. 1989,C45, 481.

    CAS  Google Scholar 

  13. El Aoud, Z.; Chaabouni, S.; Daoud, A.; Kamoun, S.C.R. Acad. Sci. Paris 1995,t320, 551.

    Google Scholar 

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Authors and Affiliations

  1. Laboratoire de Cristallochimie du Solide, E.N.I.S., 3038, Sfax, Tunisie

    Slaheddine Chaabouni, Slaheddine Kamoun & Abdelaziz Daoud

  2. Département de Chimie, Faculté des Sciences, 1060, Tunis, Tunisie

    Tahar Jouini

Authors
  1. Slaheddine Chaabouni
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  2. Slaheddine Kamoun
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  3. Abdelaziz Daoud
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  4. Tahar Jouini
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Chaabouni, S., Kamoun, S., Daoud, A. et al. Crystal structure of pentakis ethylenediammonium bis undecachlorodiantimonate(III) tetrahydrate, (NH3(CH2)2NH3)5(Sb2Cl11)2·4H2O. J Chem Crystallogr 27, 401–404 (1997). https://doi.org/10.1007/BF02576474

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  • DOI: https://doi.org/10.1007/BF02576474

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