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Crystal structure and properties ofcatena-poly[manganese(II)-μ-dichloro-μ-L-proline-k 2 o,o′] monohydrate

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Abstract

The crystal structure and some physico-chemical properties of MnCl2·Pro·H2O (Pro=L-proline) were studied. This compound is stable up to approximately 313 K. Upon heating the complex loses a molecule of water and is transformed into the oxide in two steps. The IR spectrum was recorded. The compound crystallizes in the orthorhombic space groupP212121 witha=7.112(2) Å,b=10.196(2) Å,c=13.249(3) Å andZ=4. The manganese atoms in the polymeric chain are bridged by two chlorine atoms and oxygen atoms from the carboxylate group of L-proline. The Mn−Cl bond distances range from 2.535(1) Å to 2.581(1) Å, the Mn−O bond distances range from 2.135(2) Å to 2.153(2) Å and Mn−Mn bond distances are 3.556(1) Å. One molecule of water is hydrogen-bonded with a nitrogen atom of the L-proline ring.

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Authors and Affiliations

  1. Faculty of Chemistry, Maria Curie-Skłodowska University, Sq. M. Curie-Skłodowska 2, 20-031, Lublin, Poland

    Z. Rzączyńska & R. Mrozek

  2. Faculty of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50-383, Wrocław, Poland

    T. G/klowiak

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  1. Z. Rzączyńska
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  2. R. Mrozek
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  3. T. G/klowiak
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Rzączyńska, Z., Mrozek, R. & G/klowiak, T. Crystal structure and properties ofcatena-poly[manganese(II)-μ-dichloro-μ-L-proline-k 2 o,o′] monohydrate. J Chem Crystallogr 27, 417–422 (1997). https://doi.org/10.1007/BF02576477

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  • DOI: https://doi.org/10.1007/BF02576477

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