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The crystal and molecular structure of ammonium-bis(malonato) oxovanadium(IV) dihydrate

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Abstract

The title compound, (NH4)2[VO(C3H2O4)2]·2H2O, crystallizes in the monoclinic space group P21/n, with a=7.1889(7), b=19.254(2), c=9.879(2) Å, β=108.19(1)o, and Z=4. The VO2+ cation is five-fold coordinated with two malonate anions acting as bidentate ligands and a water molecule. Infrared and Raman spectra are also reported to attain a wider insight into the compound characteristics.

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Authors and Affiliations

  1. Departamento de Física, Facultad de Ciencias Exactas, Universidad Nacional de La Plata and Programa Profimo(Conicet), C.C. 67, 1900, La Plata, Argentina

    O. E. Piro

  2. Cequinor (Conicet), Universidad Nacional de La Plata, C.C. 962, 1900, La Plata, Argentina

    E. J. Baran

Authors
  1. O. E. Piro
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  2. E. J. Baran
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Piro, O.E., Baran, E.J. The crystal and molecular structure of ammonium-bis(malonato) oxovanadium(IV) dihydrate. J Chem Crystallogr 27, 475–479 (1997). https://doi.org/10.1007/BF02576587

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  • DOI: https://doi.org/10.1007/BF02576587

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