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Investigation of the iron-rich corner of the Fe-Hf-Zr system

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Journal of Phase Equilibria

Abstract

The Fe-Hf-Zr phase diagram was determined at 900 °C in the Fe-rich corner by powder x-ray diffraction (XRD) and electron probe microanalysis (EPMA). Iron-rich parts of the Fe-Hf and Fe-Zr binary systems were also reviewed. The existence of Fe23Zr6 with a cubic Mn23Th6 structure was confirmed. A calorimetric study by direct reaction at high temperatures gave the enthalpies of formation of Fe23Zr6, Fe0.70Hf0.30(λ), and some ternary alloys: Fe0.66(Hf, Zr)0.34 and Fey(Hf, Zr)l-y with 76≤y≤100at.%Fe.

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Cited References

  1. M. Hansen,Constitution of Binary Alloys, McGraw-Hill Publishing Co.,New York, 661 (1958).

    Google Scholar 

  2. W.B. Pearson,A Handbook of Lattice Spacings and Structures of Metals and Alloys, Pergamon Press, New York (1958).

    Google Scholar 

  3. R.P. Elliott,Trans. ASM, 53, 321–329 (1961).

    Google Scholar 

  4. V.N. Svechnikov and A.T. Spector,Proc. Akad. Sci. USSR, Chem. Sect.,142(3), 231–233 (1962).

    Google Scholar 

  5. V.N. Svechnikov, V.M. Pan, and A.T. Spector,J. Inorganic Chem.,8(9), 1106–1109(1963).

    Google Scholar 

  6. P.I. Kripyakevich, VS. Prosatov, and E.E. Cherkashin,J. Inorganic Chem.,10, 151–152(1965).

    Google Scholar 

  7. W. Brukner, K. Kleinstuck, and G.E.R. Schultze,Phys. Status Solidi, 23, 475–480 (1967).

    Article  Google Scholar 

  8. V.N. Svechnikov, V.Y. Markiv, and V.V. Petkov,Akad. Nauk Ukr. SSSR, Metallofiz.,40, 95–97 (1972) in Russian.

    Google Scholar 

  9. L.N. Guseva and T.O. Malakhova,Akad. Nauk Ukr SSR, Metallofiz.,46, 111–113 (1973) in Russian.

    Google Scholar 

  10. F.P. Livi, J.D. Rogers, and P.J. Viccaro,Phys. Status Solidi (a), 37, 133–138(1976).

    Article  ADS  Google Scholar 

  11. K. Ikeda,Z. Metallkd.,68(3), 195–198(1977).

    Google Scholar 

  12. F.P. Livi,SolidState Commun.,22, 107–108 (1977).

    Article  ADS  Google Scholar 

  13. Y. Muraoka, M. Shiga, and Y. Nakamura,Phys. Status Solidi (a), 42, 369–374(1977).

    Article  ADS  Google Scholar 

  14. K. Yvon, W. Jeitschko, and E. Parthe,J. Appl. Crystallogr, 10, 73–74(1977).

    Article  Google Scholar 

  15. F.P. Livi, L. Amaral, and S.G. Fries,Phys. Status Solidi (a), 53, 379–381 (1979).

    Article  ADS  Google Scholar 

  16. T.O. Malakhova,Splavy At. Energ., O.S. Ivanov, Ed., Izv. Nauka, Moscow, 123–130 (1979) in Russian.

    Google Scholar 

  17. G.K. Ryasny, A.D. Yevdokimova, B.A. Komissarova, L.N. Kryukova, K.P. Mitrophanof, and A.A. Sorokin,Prikl. Yadernaya Spectroskopiya,9, 123–133 (1979) in Russian.

    Google Scholar 

  18. J.P. Abriata, J.C. Bolcich, and H.A. Peretti,Bull. Alloy Phase Diagrams, 3(1), 29–34 (1982).

    Article  Google Scholar 

  19. D.A. Ditmars, S. Ishihara, S.S. Chang, G. Bernstein, and E.D. West,J. Res. Natl. Bur. Stand.,87(2), 159–163 (1982).82Sos: M. Sostarich and Y. Khan, Z.Metallkd., 73(11), 706–709 (1982).

    Article  Google Scholar 

  20. Z.Z. Akselrud, M. Budzynski, T. Khazratov, B.A. Komissarova, L.N. Kryukova, S.I. Reiman, G.K. Ryasny, and A.A. Sorokin,Hyperflne Interactions, 14, 7–19(1983).

    Article  ADS  Google Scholar 

  21. J.C. Gachon and J. Hertz,Calphad.7, 1–12 (1983).

    Article  Google Scholar 

  22. R.M. Waterstrat,J. Less-Common Met.,95, 335–344 (1983).

    Article  Google Scholar 

  23. P. Chaudouet, B. Lambert, R. Madar, and R. Fruchart,Ann. Chim. Fr.,9, 119–121 (1984).

    Google Scholar 

  24. F. Aubertin, U. Gonser, S.J. Campbell, and H.G. Wagner,Z. Metallkd., 76(4), 237–244 (1985).

    Google Scholar 

  25. M. Matsuura,J. Phys. F, Met. Phys.,15, 257–262 (1985).

    Article  ADS  Google Scholar 

  26. P. Villars and L.D. Calvert,Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, American Society for Metals, Metals Park, OH (1985).

    Google Scholar 

  27. D. Arias and J.P. Abriata,Bull. Alloy Phase Diagrams, 9(5) 597–604(1988).

    Article  Google Scholar 

  28. O.Y. Sidorov, M.G. Valisher, Y.O. Esin, and P.V. Gel’d,lzv. Akad. Nauk SSSR, Met.,6, 23 (1988).

    Google Scholar 

  29. J.M. Alekseeva and N.V. Korotkova,Izv. Akad. Nauk SSSR, Met.,4, 202 (1989) in Russian.

    Google Scholar 

  30. I.Barin, F. Sauert, E. Schultze-Rhonhof, and W. Shu Sheng,Thermochemical Data of Pure Substances, Part I and II, VCH, Weinheim (1989).

    Google Scholar 

  31. T.B. Massalski, H. Okamoto, P.R. Subramanian, and L. Kacprzak,Binary Alloy Phase Diagrams, ASM International, Materials Park, OH, 2nd ed. (1990).

    Google Scholar 

  32. N. Selhaoui, Thèse d’Université, Nancy I, France (1990).

  33. P. Rehbein, F. Aubertin, S. Yang, and U. Gonser, Z.Metallkd.,82(7), 532–538 (1991).

    Google Scholar 

  34. J.C. Gachon, N. Selhaoui, B. Aba, and J. Hertz,J. Phase Equilibria, 13(5), 506–511 (1992).

    Article  Google Scholar 

  35. D. Arias, M.B. Granovsky, and J.P. Abriata,Phase Diagrams of Binary Iron Alloys, H. Okamoto, Ed., ASM International, Materials Park, OH, 467–472 (1993).

    Google Scholar 

  36. K. Bhanumurthy and G.B. Kale,Scr. Metall. Mater.,28, 753–756 (1993).

    Article  Google Scholar 

  37. H. Okamoto,J. Phase Equilibria, 14(5), 652–653 (1993).

    Article  MathSciNet  Google Scholar 

  38. V. Raghavan,Phase Diagrams of Ternary Iron Alloys, Part 6, Indian Institute of Metals, Calcutta (1993).

    Google Scholar 

  39. C. Servant, C. Gueneau, and I. Ansara,J. Alloy. Compd.,220, 19–26(1995).

    Article  Google Scholar 

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Authors and Affiliations

  1. Laboratoire de Chimie du Solide Minéral, URA 158 Service de Thermodynamique Métallurgique Domaine Scientifique Victor Grignard Université Henri Poincaré, Nancy 1, B.P. 239 F-54506 Vandœuvre lès, Nancy cedex, France

    K. Mahdouk & J. C. Gachon

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  1. K. Mahdouk
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  2. J. C. Gachon
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Mahdouk, K., Gachon, J.C. Investigation of the iron-rich corner of the Fe-Hf-Zr system. JPE 17, 218–227 (1996). https://doi.org/10.1007/BF02648490

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  • DOI: https://doi.org/10.1007/BF02648490

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