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A thermodynamic analysis of the phase equilibria of the Fe-Ni system above 1200 K

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Abstract

A quasi-subregular solution model is used to describe the thermodynamic properties of the liquid phase; values of the solution parameters are obtained from extensive and consistent thermochemical data reported in the literature. For the fcc and bcc phases, the same model is used to account for the nonmagnetic part of the Gibbs energy and the magnetic contribution is taken from the previous paper. Again, the values for the quasi-subregular solution parameters for the fcc phase are obtained from extensive and consistent thermochemical data reported in the literature at high temperatures. The values of the solution parameters for the bcc phase are obtained from the thermodynamic values of the liquid and fcc phases and the known phase boundary data. The calculated phase equilibria are in good agreement with the available data. Based on the thermodynamic data, the metastablel + γ andl + δ phase boundaries as well as theT 0 (γ + l) andT 0(δ +l) curves are calculated.

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References

  1. Y.-Y. Chuang, Y. A. Chang, and R. Schmid:Metall. Trans. A, 1986, vol. 17A, pp. 1361–72.

    CAS  Google Scholar 

  2. R. Hultgren, P.D. Desai, D.T. Hawkins, M. Gleiser, and K.K. Kelley:Selected Values of the Thermodynamic Properties of Binary Alloys, American Society for Metals, Metals Park, OH, 1973, p. 847.

    Google Scholar 

  3. O. Kubaschewski:Iron Binary Phase Diagrams, Springer-Verlag, Berlin, Heidelberg, New York, 1982, p. 73.

    Google Scholar 

  4. K. C. Mills, K. Kinashita, and P. Grieveson:J. Chem. Thermodyn., 1972, vol. 4, p. 581.

    Article  CAS  Google Scholar 

  5. O. Kubaschewski, K-H. Geiger, and K. Hack:Z. Metallk., 1977, vol. 68, p. 337.

    CAS  Google Scholar 

  6. B.R. Conard, T. B. McAneney, and R. Sridhar:Metall. Trans. B, 1978, vol. 9B, p. 463.

    CAS  Google Scholar 

  7. W. Rammensee and D. G. Fraser:Ber. Bunsenges. Phys. Chem., 1981, vol. 85, p. 588.

    CAS  Google Scholar 

  8. G. I. Batalin, N. N. Mineko, and V. S. Sudavtsova:Izv. Akad. Nauk USSR, Met., 1974, no. 5, p. 99;Russ. Metall., 1974, no. 5, p. 82.

  9. B. Predel and R. Mohs:Arch. Eisenhüttenwes., 1970, vol. 41, p. 143.

    CAS  Google Scholar 

  10. B. Fleischer and J. F. Elliott: Proc. NPL Symps. no. 9, 1958, “Met. Chem.”, HMSO, 1959, paper 2F.

  11. D. Henriet, C. Gatellier, and M. Olette: Proc. NPL Symps. 1971, “Met. Chem.”, HMSO, 1972, p. 97.

  12. K. Ono, Y. Ueda, A. Yamaguchi, and J. Moriyama:J. Jap. Inst. Metals, 1972, vol. 36, p. 188.

    CAS  Google Scholar 

  13. A.D. Dalvi and R. Sridhar:Can. Met. Q., 1976, vol. 15, p. 349.

    CAS  Google Scholar 

  14. M-C. Trinel-Dufour and P. Perrot:C. R. Acad. Sci., (Paris), Series C, 1975, vol. 281, p. 589.

    CAS  Google Scholar 

  15. P.J. Spencer, F.H. Hayes, and L. Elford:Chem. Metall, Iron Steel, Proc. Intn. Symp. Metall. Chem.-Appl. Ferrous Metall., Pub. Iron Steel Inst., London, 1971, p. 322.

    Google Scholar 

  16. Y. -Y. Chuang, R. Schmid, and Y. A. Chang:Metall. Trans. A, 1984, vol. 15A, p. 1921.

    CAS  Google Scholar 

  17. R.C. Sharma:Trans. IIM, 1982, vol. 35, p. 372.

    CAS  Google Scholar 

  18. Y.-Y. Chuang: Ph.D. Thesis, University of Wisconsin-Madison, Madison, WI, 1983.

  19. Y. -Y. Chuang, K-C Hsieh, and Y. A. Chang:Metall. Trans. B, 1985, vol. 16B, p. 277.

    CAS  Google Scholar 

  20. R.C. Sharma and Y. A. Chang:Metall. Trans. B, 1980, vol. 11B, p. 139.

    CAS  Google Scholar 

  21. R.C. Sharma and Y. A. Chang:Metall. Trans. B, 1980, vol. 11B, p. 575.

    CAS  Google Scholar 

  22. M. Hillert, T. Wada, and H. Wada:J. Iron Steel Inst., 1967, p. 539.

  23. M.M. Rao, R.J. Russell, and P.G. Winchell:Trans. TMS-AJME, 1967, vol. 239, p. 634.

    CAS  Google Scholar 

  24. L. Kaufman and H. Nesor:Z. Metallk., 1973, vol. 64, p. 249.

    CAS  Google Scholar 

  25. M. Hasebe and T. Nishizawa: in “Applications of Phase Diagrams in Metallurgy and Ceramics,” Proceedings of Workshop held at NBS, Gaithersburg, MD, Jan. 10–12, 1977, p. 911.

  26. T. Nishizawa: Tohoku University, Sendai, Japan, private communication, 1982.

  27. J.M. Larrain:CALPHAD, 1980, vol. 4, p. 155.

    Article  CAS  Google Scholar 

  28. Y. -Y. Chuang, R. Schmid, and Y. A. Chang:Metall. Trans. A, 1985, vol. 16A, p. 153.

    CAS  Google Scholar 

  29. J. Ågren:Metall. Trans. A, 1979, vol. 10A, p. 1847.

    Google Scholar 

  30. R. L. Orr and J. Chipman:Trans. TMS-AIME, 1967, vol. 239, p. 630.

    CAS  Google Scholar 

  31. Y.-Y. Chuang, R. Schmid, and Y.A. Chang:Acta Metall., 1985, vol. 33, p. 1369.

    Article  CAS  Google Scholar 

  32. M. Onillon and M. Olette:Compt. Rend., 1966, vol. C263, p. 1122.

    Google Scholar 

  33. G.R. Belton and R.J. Fruehan:J. Phys. Chem., vol. 71, p. 1403.

  34. G. R. Zellars, S. L. Payne, J. P. Morris, and R. L. Kipp:Trans. TMS- AIME, 1959, vol. 215, p. 181.

    CAS  Google Scholar 

  35. R. Speiser, A. J. Jacobs, and J.W. Spretnak:Trans. TMS-AIME, 1959, vol. 215, p. 185.

    CAS  Google Scholar 

  36. A. El’Khasan, K. Abdel-Aziz, A. A. Vertman, and S. A. Samarin:Izvest. AN SSSR, Metally, 1966, vol. 3, p. 19.

    Google Scholar 

  37. Y. Tozaki, Y. Iguchi, S. Ban-ya, and T. Fuwa: in “Chemical Metallurgy of Iron and Steel,” Proc. of the Intn. Symp. on Met. Chem., Application in Ferrous Met., held Univ. of Sheffield, 19–21 July 1971, Iron and Steel Inst., London, 1973, p. 130.

    Google Scholar 

  38. M-C. Trinel-Dufour, G. Pouillard, and P. Perrot:J. Chem. Res., 1979, p. 280.

  39. R. A. Oriani:Acta Metall., 1953, vol. 1, p. 448.

    Article  CAS  Google Scholar 

  40. O. Kubaschewski and O. Goldbeck:Trans. Faraday Soc., 1949, vol. 45, p. 948.

    Article  CAS  Google Scholar 

  41. W. A. Dench:Trans. Faraday Soc, 1963, vol. 59, p. 1279.

    Article  CAS  Google Scholar 

  42. O. Kubaschewski and L. F. H. Stuart:J. Chem. Engin. Data, 1967, vol. 12, p. 418.

    Article  CAS  Google Scholar 

  43. W. Steiner and D. Krisement:Arch. Eisenhüttenwes., 1961, vol. 32, p. 701.

    CAS  Google Scholar 

  44. A. Hellawell and W. Hume-Rothery:Phil. Trans. Roy. Soc. London, 1957, vol. A249, p. 417.

    Article  Google Scholar 

  45. D. Hanson and J. R. Freeman:Iron Steel Inst., 1923, vol. 107, p. 301.

    Google Scholar 

  46. E. Schürmann and J. Brauckmann:Arch. Eisenhüttenwes., 1977, vol. 48, p. 3.

    Google Scholar 

  47. W. Hume-Rothery and R. A. Buckley:J. Iron Steel Inst., 1964, vol. 202, p. 531.

    CAS  Google Scholar 

  48. L. Crovini, R. E. Bedford, and A. Moser:Metrologia, 1979, vol. 13, p. 197.

    Article  Google Scholar 

  49. Bulletin Alloy Phase Diagrams, 1981, vol. 2, p. 262.

  50. Metals Handbook, 8th ed., vol. 8, Metallography, Structures and Phase Diagrams, ASM, Metals Park, OH, 1973, p. 293.

  51. M. Hansen and K. Anderko:Constitution of Binary Alloys, 2nd ed., McGraw-Hill, New York, NY, 1958, p. 677.

    Google Scholar 

  52. R.E. Cech:Trans. AIME, 1956, vol. 206, p. 585.

    Google Scholar 

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Authors and Affiliations

  1. Department of Metallurgical and Mineral Engineering, University of Wisconsin-Madison, 1509 University Avenue, 53706, Madison, WI

    Ying-Yu Chuang (Project Associate), Ker-Chang Hsieh (Project Associate) & Y.Austin Chang (Professor)

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  1. Ying-Yu Chuang
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  2. Ker-Chang Hsieh
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  3. Y.Austin Chang
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Chuang, YY., Hsieh, KC. & Chang, Y. A thermodynamic analysis of the phase equilibria of the Fe-Ni system above 1200 K. Metall Trans A 17, 1373–1380 (1986). https://doi.org/10.1007/BF02650118

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