Abstract
This study of Al-Zn-Mg alloys was undertaken to establish the specific combination of mechanical and thermal conditions which is necessary for stress-corrosion susceptibility to occur in these alloys. The work included a study by electron transmission microscopy of the microstructure of this alloy system. A new mechanism is proposed to account for the observations made. It suggests that the high corrosion potential at grain boundaries in stress-corrosion susceptibile Al-Zn-Mg alloys is due to segregation of zinc and magnesium. By taking precautions to reduce this segregation, the stress-corrosion life can be increased.
Similar content being viewed by others
References
H. G. Petri, G. Siebel, and H. Vosskühler:Light Metal Age, 1945, vol. 3, no. 11, p. 21.
R. Chadwick, N. B. Muir, and H. B. Grainger:J. Inst. Metals, 1956-57, vol. 85, p. 161.
I. Taylor:Metal Progr., 1963, vol. 84, no. 5, p. 74.
T. A. Vlasova, E∼. K. Zenkova, L. M. Polyakova, and V. E. Silis:Phys. Metals Metallog., 1967, vol. 23, no. 2, p. 357.
D. O. Sprowls and R. H. Brown:Metal Progr., 1962, vol. 81, no. 4, p. 79 and 1962, vol. 81, no. 5, p. 77.
W.C. Rotsell and J. R. Long:Metal Progr., 1967, vol. 91, no. 5, p. 106.
M. O. Speidel: Proceedings on the conference of fundamental aspects of Stress-Corrosion Cracking, Ohio State University, Columbus, Ohio, September 11–15, 1967. Published by N.A.C.E. 1969.
K. G. Kent:J. Inst. Metals, 1969, vol. 97, p. 127.
R. W. Elkington:J. Inst. Metals, 1961-62, vol. 90, p. 267.
M. K. B. Day, A. J. Cornish, and T. P. Dent:Metal Sci. J., 1969, vol. 3, p. 175.
H. A. Holl:Corrosion, 1967, vol. 23, p. 173.
W. Gruhl and H. Cordier:Aluminium, 1968, vol. 44, p. 403.
A. J. Jacobs:Trans. ASM, 1965, vol. 58, p. 579.
E. H. Dix:Trans. AIME, 1940, vol. 137, p. 11.
F. H. Cocks:Metallography, 1969, vol. 2, p. 247.
A. J. Sedriks, P. W. Slattery, and E. N. Pugh:Trans. ASM, 1969, vol. 62, p. 238.
Stress-Corrosion Testing, ASTM publication STP 425, July 1966.
P. Lacombe and M. Mouflard:MÊtaux Corrosion-Ind., 1953, vol. 28, p. 471.
R. C. Spooner:Plating, 1966, vol. 53, p. 451.
R. A. Swalin:Thermodynamics of Solids, John Wiley & Sons, New York, 1962.
D. McLean:Grain Boundaries in Metals, Clarendon Press, Oxford, 1957.
J. McMillan, J. Corey, and M. V. Hyatt: Report No. D6-60091, The Boeing Company, April 1968.
S. L. Cundy, A. J. F. Netherell, M. J. Whelan, P. N. T. Unwin, and R. B. Nicholson:Proc. Roy. Soc., 1968, vol. 307, p. 267.
L. D. Kharitonova:Metalloved. i Termich. Obrabotka Metallov., No. 3, March 1959, p. 51. Brutcher translation no. 4547.
K. T. Aust, R. E. Hanneman, P. Neissen, and J. H. Westbrook:Acta. Met., 1968, vol. 16, p. 291.
Nature, 1968, vol. 218, p. 117.
K. T. Aust, J. S. Armijo, E. F. Koch, and J. H. Westbrook:Trans. ASM, 1968, vol. 61, p. 270.
Edgar A. Starke, Jr.:J. Metals, 1970, vol. 22, no. 1, p. 54.
M. Kubota: Paper presented at the 35th Annual meeting of Japan Inst. of Light Metals, Nagoya, Japan on 12–13 May 1970.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Taylor, I.T., Edgar, R.L. A study of stress-corrosion in Al-Zn-Mg alloys. Metall Trans 2, 833–839 (1971). https://doi.org/10.1007/BF02662743
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02662743