Skip to main content
SpringerLink
Log in

Standard enthalpy of formation of Sc5Si3

  • Physical Chemistry
  • Published:
Metallurgical Transactions B Aims and scope Submit manuscript

Abstract

The standard enthalpy of formation of Sc5Si3 has been determined by solute-solvent drop calorimetry at (1473±2) K. The following value is reported: ΔH of (mean)=−(719.1±34.0) kJ mol−1. This result is compared with corresponding published values for the enthalpies of formation of Me5Si3, with Me=Mn, Cr, V, Ti. This comparison shows regularly increasing negative enthalpies of formation from Mn5Si3 to Sc5Si3.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. Hägg:Z. Phys. Chem., 1931, vol. 12B, pp. 33–56.

    Google Scholar 

  2. H. J. Goldschmidt:Interstitial Alloys, Plenum Press, New York, NY, 1967, p. 296.

    Book  Google Scholar 

  3. B. Aronsson:Ark. Kemi, 1960, vol. 16, pp. 379–423.

    Google Scholar 

  4. L. Topor and O. J. Kleppa:Metall. Trans. A, 1986, vol. 17A, pp. 1217–21.

    Article  Google Scholar 

  5. L. Topor and O. J. Kleppa:J. Chem. Thermodyn., 1987, vol. 19, pp. 69–75.

    Article  Google Scholar 

  6. L. Topor and O. J. Kleppa:Z. Metallkd., 1986, vol. 77, pp. 65–71.

    Google Scholar 

  7. L. Topor and O. J. Kleppa:Z. Metallkd., 1988, vol. 79, pp. 623–28.

    Google Scholar 

  8. O. J. Kleppa and L. Topor:Thermochim. Acta, 1989, vol. 139, pp. 291–97.

    Article  Google Scholar 

  9. L. Topor and O. J. Kleppa:Metall. Trans. A, 1988, vol. 19A, pp. 1827–31.

    Article  Google Scholar 

  10. Y. M. Golutvin, E. G. Maslennikova, and L. G. Titov:Izv. Akad. Nauk SSSR Met, 1984, vol. 6, pp. 47–55.

    Google Scholar 

  11. F. R. de Boer, R. Boom, W. C. M. Mattens, A. R. Miedema, and A. K. Niessen:Cohesion in Metals. Transition Metal. Alloys, North-Holland, Amsterdam, 1988, p. 111.

    Google Scholar 

  12. R. Hultgren, P. D. Desai, D. T. Hawkins, M. Gleiser, and K. K. Kelley:Selected Values of the Thermodynamic Properties of Binary Alloys, ASM, Metals Park, OH, 1973, p. 1320.

    Google Scholar 

  13. D. A. Robins and I. Jenkins:Acta Metall., 1955, vol. 3, pp. 598–604.

    Article  Google Scholar 

  14. Yu. M. Golutvin:Zh. Fiz. Khim., 1956, vol. 30, pp. 2251–58.

    Google Scholar 

  15. T. G. Chart:High Temp.-High Pressures, 1973, vol. 5, pp. 241–52.

    Google Scholar 

  16. O. S. Gorelkin and S. V. Mikhailikov:Russ. J. Phys. Chem., 1971, vol. 45, pp. 1523–24.

    Google Scholar 

  17. O. S. Gorelkin, A. S. Dubrovin, O. D. Kolesnikova, and N. A. Chrikov:Russ. J. Phys. Chem., 1972, vol. 46, pp. 431–32.

    Google Scholar 

  18. Yu. M. Golutvin and T. M. Kozlovskaya:Russ. J. Phys. Chem., 1960, vol. 34, pp. 1116–18.

    Google Scholar 

  19. E. K. Storms and C. E. Myers:High Temp. Sci., 1985, vol. 20, pp. 87–96

    Google Scholar 

  20. Yu. M. Golutvin and Liang Chin-k'uei:Russ. J. Phys. Chem., 1961, vol. 35, pp. 62–67.

    Google Scholar 

  21. V. N. Yeremenko, G. M. Lukashenko, and V. R. Sidorko:Rev. Int. Hautes Temp. Réfract., 1975, vol. 12, pp. 237–40.

    Google Scholar 

  22. Yu. M. Golutvin, T. M. Kozlovskaya, and E. G. Maslennikova:Russ. J. Phys. Chem., 1963, vol. 37, pp. 723–27.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Geology, Princeton University, 08544, Princeton, NJ

    Letitia Topor

  2. Deparments of Chemistry and Geophysical Sciences, University of Chicago, 5640 S. Ellis Ave., 60637, Chicago, IL

    O. J. Kleppa (Professor)

Authors
  1. Letitia Topor
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. J. Kleppa
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

LETTTIA TOPOR, formerly Senior Research Associate, The James Franck Institute, The University of Chicago,

Rights and permissions

Reprints and permissions

About this article

Cite this article

Topor, L., Kleppa, O.J. Standard enthalpy of formation of Sc5Si3 . Metall Trans B 20, 879–882 (1989). https://doi.org/10.1007/BF02670193

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02670193

Keywords

Search

Navigation