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Mathematical modeling of minor-element behavior in flash smelting of copper concentrates and flash converting of copper mattes

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Abstract

A mathematical model has been developed to describe the behavior of minor elements during flash smelting and flash converting. The model incorporates equations describing volatilization of minor elements from the molten particles and distribution of these elements between the molten phases in the settler. The basic premise of the volatilization model is that at the surface of the molten particle, the partial pressures of the minor-element species are those at equilibrium. Transport of the minor-element species to the gas then is described by external mass transfer. Good agreement has been obtained between observed and predicted behaviors. The effects of oxygen enrichment, matte grade, and wall temperature, as well as the bath temperature, on minor-element behavior have been elucidated.

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References

  1. M. Nagamori and P.C. Chaubal:Metall. Trans. B, 1982, vol. 13B, pp. 319–29.

    CAS  Google Scholar 

  2. M. Nagamori and P.C. Chaubal:Metall. Trans. B, 1982, vol. 13B, pp. 331–38.

    CAS  Google Scholar 

  3. P.C. Chaubal and M. Nagamori:Metall. Trans. B, 1982, vol. 13B, pp. 339–48.

    CAS  Google Scholar 

  4. P.C. Chaubal and M. Nagamori:Metall. Trans. B, 1983, vol. 14B, pp. 303–06.

    Article  CAS  Google Scholar 

  5. P.C. Chaubal, M. Nagamori, and H.Y. Sohn:Can. Met. Quart., 1984, vol. 23, pp. 405–11.

    CAS  Google Scholar 

  6. K. Itagaki and A. Yazawa: inAdvances in Sulfide Smelting, H.Y. Sohn, D.B. George, and A.D. Zunkel, eds., TMS-AIME, Warrendale, PA, 1983, pp. 119–42.

    Google Scholar 

  7. H.K. Jalkanen, L.E. Holappa, and J.K. Makinen: inAdvances in Sulfide Smelting, H.Y. Sohn, D.B. George, and A.D. Zunkel, eds., TMS-AIME, Warrendale, PA, 1983, pp. 277–92.

    Google Scholar 

  8. J. Makinen and G. Hafs:J. Metals, 1982, vol. 34, no. 6, pp. 54–60.

    CAS  Google Scholar 

  9. K.J. Richards, D.B. George, and L.K. Bailey: inAdvances in Sulfide Smelting, H.Y. Sohn, D.B. George, and A.D. Zunkel, eds., TMS-AIME, Warrendale, PA, 1983, pp. 489–98.

    Google Scholar 

  10. J.A. Asteljoki, L.K. Bailey, D.B. George, and D.W. Rodolff:J. Metals, 1985, vol, 37, no. 5, pp. 20–23.

    CAS  Google Scholar 

  11. J.A. Asteljoki and S.M.I. Kyto: TMS Paper No. A86-57, TMS- AIME, Warrendale, PA, 1986.

    Google Scholar 

  12. S. Ruottu:Combustion and Flame, 1979, vol. 34, pp. 1–11.

    Article  CAS  Google Scholar 

  13. Y.B. Hahn and H.Y. Sohn: inMathematical Modeling of Materials Processing Operations, J. Szekelyet al., eds., TMS- AIME, Warrendale, PA, 1987, pp. 799–834.

    Google Scholar 

  14. P.C. Chaubal and H.Y. Sohn: inGas-Solid Reactions in Pyro- metallurgy, D.G.C. Robertson and H.Y. Sohn, eds., Center for Pyrometallurgy, Rolla, MO, 1986, pp. 17–38.

    Google Scholar 

  15. R.B. Bird, W.E. Steward, and E.N. Lightfoot:Transport Phenomena, John Wiley & Sons, New York, NY, 1968, pp. 510–11.

    Google Scholar 

  16. J.C. Yannopoulos, C.E. Swanson, and J.W. Ahlrichs: inExtractive Metallurgy of Copper, J.C. Agarwal and J.C. Yannapoulos, eds., TMS-AIME, New York, NY, 1976, vol. 1, pp. 49–65.

    Google Scholar 

  17. M. Nagamori and P.J. Mackey:Metall. Trans. B, 1978, vol. 9B, pp. 255–65.

    Article  CAS  Google Scholar 

  18. W.M. Krivsky and R. Schuhmann:Trans. AIME, 1957, vol. 209, pp. 981–88.

    Google Scholar 

  19. P.C. Chaubal and M. Nagamori: unpublished research, 1987.

  20. O. Kubaschewski, E. Evans, and C.B. Alcock:Metallurgical Thermochemistry, Pergamon Press, New York, NY, 1976, pp. 326–35.

    Google Scholar 

  21. Selected Values of the Thermodynamic Properties of the Ele- ments, R. Hultgren, P. Desai, D.Y. Hawkins, M. Gleiser, K.K. Kelley, and D.D. Wagman, eds., ASM, Metals Park, OH, 1973, pp. 146–50.

    Google Scholar 

  22. K. Itagaki, M. Hino, and A. Yazawa:Erzmetall., 1983, vol. 36, pp. 59–64.

    CAS  Google Scholar 

  23. A. Roine and H. Jalkanen:Metall. Trans. B, 1985, vol. 16B, pp. 129–41.

    Article  CAS  Google Scholar 

  24. S.N. Sinha, M. Nagamori, and H.Y. Sohn:Metall. Trans. B, 1984, vol. 15B, pp. 441–49.

    Article  CAS  Google Scholar 

  25. M. Nagamori, P.J. Mackey, and P.J. Tarasoff:Metall. Trans. B, 1975, vol. 6B, pp. 295–301.

    Article  CAS  Google Scholar 

  26. S. Goto, O. Ogawa, and C.T. Nae:J. of the Min. and Met. Inst. of Japan, 1982, vol. 98, pp. 436–40.

    CAS  Google Scholar 

  27. Y. Takeda, S. Ishiwata, and A. Yazawa:Trans. Japan Inst. of Metals, 1983, vol. 24, pp. 518–28.

    CAS  Google Scholar 

  28. K.E. Atkinson:An Introduction to Numerical Analysis, John Wiley & Sons, New York, NY, 1978.

    Google Scholar 

  29. P.C. Chaubal: Ph.D. Dissertation, University of Utah, Salt Lake City, UT, 1986.

    Google Scholar 

  30. P. Fisher: inAdvances in Sulfide Smelting, H.Y. Sohn, D.B. George, and A.D. Zunkel, eds., TMS-AIME, Warrendale PA, 1983, pp. 513–27.

    Google Scholar 

  31. E.O. Nermes and T.T. Talonen:J. Metals, 1982, vol. 34, no. 11 pp. 54–57.

    Google Scholar 

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Formerly Assistant Professor, Department of Metallurgy and Metallurgical EngineeringUniversity of Utah, Salt Lake City, UT

Formerly Metallurgical Engineer Kennecott, Salt Lake City, UT

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Chaubal, P.C., Sohn, H.Y., George, D.B. et al. Mathematical modeling of minor-element behavior in flash smelting of copper concentrates and flash converting of copper mattes. Metall Trans B 20, 39–51 (1989). https://doi.org/10.1007/BF02670348

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  • DOI: https://doi.org/10.1007/BF02670348

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