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A thermodynamic analysis of the Fe-Mn-C system

  • Physical Chemistry
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Abstract

The experimental information on the solid state phase equilibria in the Fe−Mn−C system was analyzed in thermodynamic terms. Gibbs free energy of each phase was described by a regular or subregular solution model and the numerical values of the parameters were determined. The results were used to calculate isothermal sections between 873 and 1373 K. They show a reasonable agreement with all the experimental information available.

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References

  1. R. Vogel and W. Döring:Arch. Eisenhuettenw., 1935–36, vol. 9, p.247.

    CAS  Google Scholar 

  2. M. Isobe:Sci. Rep. Res. Inst. Tohoku Univ. Ser. A, 1951, vol. 3, p. 540.

    Google Scholar 

  3. K. Kuo and L. E. Persson:J. Iron Steel Inst., 1954, vol. 178, p. 39.

    CAS  Google Scholar 

  4. T. Nishizawa:Report 4602 to the Swedish Council for Applied Research Div. of Phys. Met., Royal Inst. of Techn., Stockholm, 1967.

    Google Scholar 

  5. T. Nishizawa and B. Uhrenius: Report, Royal Inst. of Techn., Stockholm, TRITA-MAC-004, 1971.

    Google Scholar 

  6. T. Wada, H. Wada, J. F. Elliott, and J. Chipman:Met. Trans., 1972, vol. 3, p. 1657.

    Article  CAS  Google Scholar 

  7. R. Benz, J. F. Elliott, and J. Chipman:Met. Trans., 1973, vol. 4, p. 1975.

    Article  CAS  Google Scholar 

  8. R. Benz:Met. Trans., 1974, vol. 5, p. 2217.

    Article  CAS  Google Scholar 

  9. M. V. Rao and W. A. Tiller:Mater. Sci. Engl., 1974, vol. 14, p. 47.

    Article  CAS  Google Scholar 

  10. M. Hillert and L.-I. Staffansson:Acta Chem. Scand., 1970, vol. 24, p. 3618.

    CAS  Google Scholar 

  11. B. Uhrenius and S. Frondell: Report, Royal Inst. of Techn., Stockholm, TRITA-MAC-0096, 1976.

    Google Scholar 

  12. H. Harvig:Jernkontorets Ann., 1971, vol. 155, p. 157.

    CAS  Google Scholar 

  13. R. L. Orr and J. Chipman:Trans. TMS-AIME, 1967, vol. 239, p. 630.

    CAS  Google Scholar 

  14. R. Hultgren, P. D. Desai, D. T. Hawkins, M. Gleiser, K. K. Kelley, and D. D. Wagman:Selected Values of the Thermodynamic Properties of the Elements, p. 301, ASM, Metals Park, Ohio 1973.

    Google Scholar 

  15. R. Benz, J. F. Elliott, and J. Chipman:Met. Trans., 1973, vol. 4, p. 1449.

    Article  CAS  Google Scholar 

  16. M. Isobe:Sci. Rep. Res. Inst., Tohoku Univ., Ser. A, 1951, vol. 3, p. 468.

    CAS  Google Scholar 

  17. M. Hansen and K. Anderko:Constitution of Binary Alloys, 2nd ed., p. 367, McGraw-Hill, New York, 1958.

    Google Scholar 

  18. R. P. Smith:J. Amer. Chem. Soc., 1948, vol. 70, p. 2724.

    Article  CAS  Google Scholar 

  19. T. Wada, H. Wada, J. F. Elliott, and J. Chipman:Met. Trans., 1972, vol. 3, p. 1657.

    Article  CAS  Google Scholar 

  20. H. Harvig, T. Nishizawa, and B. Uhrenius: inMetallurgical Chemistry, O. Kubaschewski, ed., p. 431, London, 1972.

  21. B. Uhrenius:Scand. J. Met., 1973, vol. 2, p. 177.

    CAS  Google Scholar 

  22. G. Kirchner, T. Nishizawa, and B. Uhrenius:Met. Trans., 1973, vol. 4, p. 167.

    CAS  Google Scholar 

  23. A. R. Troiano and F. T. McGuire:Trans. ASM, 1943, vol. 31, p. 341.

    Google Scholar 

  24. J. F. Butler, C. L. McCabe, and H. W. Paxton:Trans. TMS-AIME, 1961, vol. 22, p. 479.

    Google Scholar 

  25. R. Smith and R. Shuttleworth:Acta Met., 1965, vol. 13, p. 623.

    Article  CAS  Google Scholar 

  26. P. Roy and R. Hultgren:Trans. TMS-AIME, 1965, vol. 223, p. 1811.

    Google Scholar 

  27. V. N. Eremenko, G. M. Lukashenko, and V. R. Sidorko:Izv. Akad. Nauk, USSR, Metal., 1969, vol. 2, p. 170.

    Google Scholar 

  28. M. Hillert:Proc. ICSTIS, Suppl. Trans. Iron Steel Inst. Jap., 1971, vol. 11, p. 1153.

    Google Scholar 

  29. A. R. Troiano and F. T. McGuire:Trans. ASM, 1943, vol. 31, p. 340.

    Google Scholar 

  30. A. Helawell and W. Hume-Rothery:Phil. Trans. Roy. Soc., 1957, vol. 249, p. 417.

    Article  Google Scholar 

  31. M. Hillert, T. Wada, and H. Wada:J. Iron Steel Inst., 1967, vol. 205, p. 539.

    Google Scholar 

  32. R. J. Weiss and K. J. Tauer:Phys. Rev., 1956, vol. 102, p. 1490.

    Article  CAS  Google Scholar 

  33. B. Predel and W. Gust:Arch. Eisenhuettenw., 1972, vol. 43, p. 721.

    CAS  Google Scholar 

  34. R. W. Gurry, J. Chirstakos, and L. S. Darken:Trans. ASM, 1961, vol. 53, p. 187.

    CAS  Google Scholar 

  35. W. Koch and H. Keller:Arch. Eisenhuettenw., 1964, vol. 35, p. 1173.

    CAS  Google Scholar 

  36. K. Kuo and A. Hultgren:Jernkontorets Ann., 1951, vol. 135, p. 449.

    Google Scholar 

  37. T. Kunitake:Jap. Inst. Metals, 1966, vol. 7, p. 253.

    Google Scholar 

  38. E. C. Bain, E. S. Davenport, and W. S. N. Waring:Trans. TMS-AIME, 1932, vol. 100, p. 228.

    Google Scholar 

  39. J. B. Gilmour, G. R. Purdy, and J. S. Kirkaldy:Met. Trans., 1972, vol. 3, p. 1455.

    Article  CAS  Google Scholar 

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Hillert, M., Waldenström, M. A thermodynamic analysis of the Fe-Mn-C system. Metall Trans A 8, 5–13 (1977). https://doi.org/10.1007/BF02677257

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  • DOI: https://doi.org/10.1007/BF02677257

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