Abstract
The extensive literature on oxygen chemisorption and solubility in metals is briefly reviewed, with special emphasis on the reduction of surface tension associated with oxygen adsorption. A thermodynamic model based on the adsorption equations of Gibbs and Langmuir is developed to determine the relative stability in the presence of oxygen of the void compared to the dislocation loop and stacking fault tetrahedron. Representative calculations are performed for copper, nickel, and austenitic stainless steel. Atomistic and elastic continuum calculations predict that void formation should not occur in most pure face-centered cubic metals during quenching or irradiation. However, the thermodynamic model predicts that oxygen concentrations of 30 to 1000 appm will stabilize void formation in copper, nickel, and stainless steel. Foils of copper and several Fe-Cr-Ni stainless steels containing various amounts of oxygen have been examined with electron microscopy following ion bombardment. The presence of 30 to 1000 appm O resulted in significant amounts of void formation, whereas no voids were observed in low-oxygen specimens, in agreement with the model predictions. Oxygen introduced by ion implantation was more effective in promoting void formation than residual oxygen. Solutes such as phosphorus in stainless steel reduced the effectiveness of oxygen as a void-stabilizing agent.
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J.A. Sigler and D. Kuhlmann-Wilsdorf:Phys. Status Solidi, 1967, vol. 21, pp. 545–56.
S.J. Zinkle, L.E. Seitzman, and W.G. Wolfer:Phil. Mag. A, 1987, vol. 55, pp. 111–25.
R.A. Johnson:Phys. Rev., 1966, vol. 152, pp. 629–34.
M.I. Baskes:Trans. Am. Nucl. Soc., 1977, vol. 27, pp. 320–21.
A.G. Crocker, M. Doneghan, and K.W. Ingle:Phil. Mag. A, 1980, vol. 41, pp. 21–32.
C.C. Matthai and D.J. Bacon:J. Nucl. Mater., 1985, vol. 135, pp. 173–80.
N.Q. Lam, N.V. Doan, and L. Dagens:J. Phys. F, 1985, vol. 15, pp. 799–808.
M.J. Sabochick, S. Yip, and N.Q. Lam:J. Phys. F, 1988, vol. 18, pp. 349–61.
V.G. Kapinos, Yu.N. Osetskii, and P.A. Platonov:Sov. Phys. Solid State, 1986, vol. 28, pp. 2031–34.
C.J. Bell:Scripta Metall., 1981, vol. 15, pp. 665–68.
V.G. Chudinov and V.l. Protasov:Radiat. Eff., 1984, vol. 81, pp. 83–88.
R.E. Stoller and G.R. Odette:Phil. Mag. A, 1988, vol. 58, pp. 523–32.
K. Farrell:Radiat. Eff., 1980, vol. 53, pp. 175–94.
Lattice Defects in Quenched Metals, R.M.J. Cotterill, M. Doyama, J.J. Jackson, and M. Meshii, eds., Academic Press, New York, NY, 1965.
L.M. Clarebrough, R.L. Segall, and M.H. Loretto:Acta Metall., 1967, vol. 15, pp. 1007–23.
Y. Shimomura and S. Yoshida:J. Phys. Soc. Jpn., 1967, vol. 22, pp. 319–31.
K. Urban:Phys. Status Solidi A, 1970, vol. 3, pp. K167–68.
D.I.R. Norris:Radiat. Eff., 1972, vol. 15, pp. 1–22.
R.S. Nelson, J.A. Hudson, D.J. Mazey, G.P. Walters, and T.M. Williams: inRadiation-Induced Voids in Metals, J.W. Corbett and L.C. Ianniello, eds., United States Atomic Energy Commission, CONF 710601, Springfield, VA, 1972, pp. 430–45.
S.J. Zinkle, W.G. Wolfer, G.L. Kulcinski, and L.E. Seitzman:Phil. Mag. A, 1987, vol. 55, pp. 127–40.
L.E. Seitzman, L.M. Wang, G.L. Kulcinski, and R.A. Dodd:J. Nucl. Mater., 1986, vol. 141–143, pp. 738–42.
L.E. Seitzman, G.L. Kulcinski, and R.A. Dodd: inRadiation-Induced Changes in Microstructure, 13th Int. Symp., Part I, ASTM STP 955, F.A. Gamer, N.H. Packan, and A.S. Kumar, eds., ASTM, Philadelphia, PA, 1987, pp. 279–86.
E. Fromm and G. Hörz:Int. Met. Rev., 1980, vol. 25, pp. 269–311.
C.J. Altstetter:Bull. Alloy Phase Diagrams, 1984, vol. 5, pp. 543–53.
K. Wandelt:Surf. Sci. Rep., 1982, vol. 2, pp. 1–121.
I. Toyoshima and G.A. Somorjai:Catal. Rev.—Sci. Eng., 1979, vol. 19, pp. 105–59.
Gase und Kohlenstoff in Metallen, E. Fromm and E. Gebhardt, eds., Springer-Verlag, New York, NY, 1976.
R.L. Pastorek and R.A. Rapp:Trans. AIME, 1969, vol. 245, pp. 1711–20.
J. Takada, S. Yamamoto, S. Kikuchi, and M. Adachi:Metall. Trans. A, 1986, vol. 17A, pp. 221–29.
J.-W. Park and C.J. Altstetter:Metall. Trans. A, 1987, vol. 18A, pp. 43–50.
H.E. Schaefer:in Positron Annihilation, P.G. Coleman, S.C. Sharma, and L.M. Diana, eds., North-Holland, Amsterdam, 1982, pp. 369–80.
P.H. Holloway:J. Vac. Sci. Technol., 1981, vol. 18, pp. 653–59.
J. Haase and H.-J. Kuhr:Surf. Sci., 1988, vol. 203, pp. L695–99.
Y. Sakisaka, T. Miyano, and M. Onchi:Phys. Rev. B, 1984, vol. 30, pp. 6849–55.
C. Benndorf, B. Egert, G. Keller, H. Seidel, and F. Thieme:J. Phys. Chem. Solids, 1979, vol. 40, pp. 877–86.
R.W. Judd, P. Hollins, and J. Pritchard:Surf. Sci., 1986, vol. 171, pp. 643–53.
P. Hofman, R. Unwin, W. Wyrobisch, and A.M. Bradshaw:Surf. Sci., 1978, vol. 72, pp. 635–44.
W. Jacob, V. Dose, and A. Goldmann:Appl. Phys. A, 1986, vol. 41, pp. 145–50.
Th.M. Hupkens, J.M. Fluit, and A. Niehaus:Surf. Sci., 1986, vol. 165, pp. 327–36.
S. Hofmann and J. Steffen:Surf. Interface Anal., 1989, vol. 14, pp. 59–65.
C. Nyberg:Surf. Sci., 1975, vol. 52, pp. 1–9.
P.R. Norton, P.E. Binder, and T.E. Jackman:Surf. Sci., 1986, vol. 175, pp. 313–24.
A.G. Baca, L.E. Klebanoff, M.A. Schulz, E. Parapazzo, and D.A. Shirley:Surf. Sci., 1986, vol. 173, pp. 215–33.
I.P. Batra and L. Kleinman:J. Electron Spectrosc. Relat. Phenom., 1984, vol. 33, pp. 175–241.
C. Jardin, B.M. Duc, J.P. Gauthier, G. Thollet, and P. Michel:J. Electron Spectrosc. Relat. Phenom., 1980, vol. 19, pp. 213–22.
J.C. Langevoort, I. Sutherland, L.J. Hanekamp, and P.J. Gellings:Appl. Surf. Sci., 1987, vol. 28, pp. 167–79.
M. Polak and B. Schiffman:J. Vac. Sci. Technol. A, 1987, vol. 5, pp. 590–92.
R.J. Fruehan:Trans. TMS-AIME, 1969, vol. 245, pp. 1215–18.
K. Nishikawa, A. Kusano, K. Ito, and K. Sano:Trans. Iron Steel Inst. Jpn., 1970, vol. 10, pp. 83–88.
E.T. Turkdogan and R.J. Fruehan:Can. Metall. Q., 1972, vol. 11, pp. 371–82.
M. Hone, S. Houot, and M. Rigaud:Can. Metall. Q., 1974, vol. 13, pp. 619–23.
S.E. Feldman and J.S. Kirkaldy:Can. Metall. Q., 1974, vol. 13, pp. 625–30.
S. Ueno, Y. Waseda, and Y.A. Chang:Z. Metallkd., 1988, vol. 79, pp. 435–39.
V.E. Shevtsov:Russ. Metall., 1979, no. 2, pp. 58–61.
H. Schenck, E. Steinmetz, and P.C.-H. Rhee:Arch. Eisenhüttenwes., 1968, vol. 39, pp. 803–08.
B.I. Leonovich, G.G. Mikhaylov, and G.A. Khasin:Russ. Metall., 1980, no. 3, pp. 49–53.
P. Pho and H.-J. Eckstein:Neue Hütte, 1980, vol. 6, pp. 218–20.
E.A. Guggenheim:Trans. Faraday Soc., 1940, vol. 36, pp. 397–412.
R. Defay, I. Prigogine, and A. Bellemans:Surface Tension and Adsorption, John Wiley & Sons, New York, NY, 1966.
J.R. Eriksson:Surf. Sci., 1969, vol. 14, pp. 221–46.
G.A. Somorjai:Chemistry in Two Dimensions: Surfaces, Cornell University Press, Ithaca, NY, 1981.
Adsorption on Metal Surfaces, J. Benard, ed., Elsevier Science Publishing Company, New York, NY, 1983.
A. Kasama, A. McLean, W.A. Miller, Z. Monta, and M.J. Ward:Can. Metall. Q., 1983, vol. 22, pp. 9–17.
E.D. Hondros:Acta Metall., 1968, vol. 16, pp. 1377–80.
B.J. Keene:Int. Mater. Rev., 1988, vol. 33, pp. 1–37.
E.E. Tret′yakova, E.A. Klimenkov, B.A. Baum, and G.V. Tyagunov:Steel USSR, 1985, vol. 15, pp. 391–92.
F.H. Buttner, E.R. Funk, and H. Udin:J. Phys. Chem., 1952, vol. 56, pp. 657–60.
R. Sangriorgi, M.L. Muolo, and A. Passerone:Acta Metall., 1982, vol. 30, pp. 1597–1604.
D.R. Stickle, J.P. Hirth, G. Meyrick, and R. Speiser:Metall. Trans. A, 1976, vol. 7A, pp. 71–74.
E.A. Clark, R. Yeske, and H.K. Birnbaum:Metall. Trans. A, 1980, vol. 11A, pp. 1903–08.
K. Ogino and H. Taimatsu:J. Jpn. Inst. Met., 1979, vol. 43, pp. 871–76.
K. Monma and H. Suto:Trans. Jpn. Inst. Met., 1961, vol. 2, pp. 148–53.
T.E. O’Brien and A.C.D. Chaklader:J. Amer. Ceram. Soc., 1974, vol. 57, pp. 329–32.
E.D. Hondros and M. McLean: inStructure et Proprietes des Surfaces des Solides, Colloques Int. CNRS, No. 187, M.J. Benard, ed., Centre National de la Recherche Scientifique, Ed. 15, Paris, 1970, pp. 221–29.
C.E. Bauer, R. Speiser, and J.P. Hirth:Metall. Trans. A, 1976, vol. 7A, pp. 75–79.
M.F. Felsen and P. Regnier:Surf. Sci., 1977, vol. 68, pp. 410–18.
B. Gallois and C.H.P. Lupis:Metall. Trans. B, 1981, vol. 12B, pp. 549–57.
Z. Morita and A. Kasama:Trans. Jpn. Inst. Met., 1980, vol. 21, pp. 522–30.
K. Ogino, S. Hara, T. Miwa, and S. Kimoto:J. Iron Steel Inst. Jpn. (Tetsu-to-Haganè), 1979, vol. 65, pp. 2012–21.
G. Bernard and C.H.P. Lupis:Surf. Sci., 1974, vol. 42, pp. 61–85.
G.R. Beiton:Metall. Trans. B, 1976, vol. 7B, pp. 35–42.
T. Utigard and J.M. Toguri:Metall. Trans. B, 1987, vol. 18B, pp. 695–702.
P. Sahoo, T. DebRoy, and M.J. McNallan:Metall. Trans. B, 1988, vol. 19B, pp. 483–91.
E. Ricci, A. Passerone, and J.C. Joud:Surf. Sci., 1988, vol. 206, pp. 533–53.
R. Schmid:Metall. Trans. B, 1983, vol. 14B, pp. 473–81.
F.H.P.M. Habraken, C.M.A.M. Mesters, and G.A. Bootsma:Surf. Sci., 1980, vol. 97, pp. 264–82.
L.S. Darken and E.T. Turkdogan:Heterogeneous Kinetics at Elevated Temperatures, G.R. Belton and W.L. Worrell, eds., Plenum Press, New York, NY, 1970, pp. 25–95.
H.J. Grabke and H. Viefhaus:Surf. Sci., 1981, vol. 112, pp. L779–84.
K.C. Russell:Acta Metall., 1978, vol. 26, pp. 1615–30.
K.C. Russell:Scripta Metall., 1973, vol. 7, pp. 755–60.
W.G.Wolfer:J. Nucl. Mater., 1984, vol. 122–123, pp. 367–78.
R.L. Sindelar, R.A. Dodd, and G.L. Kulcinski:Effects of Radiation on Materials, 12th Int. Symp., ASTM STP 870, F.A. Garner and J.S. Perrin, eds., ASTM, Philadelphia, PA, 1985, pp. 330–43.
M.F. Wehner and W.G. Wolfer:Phil. Mag. A, 1985, vol. 52, pp. 189–205.
C.A. English, B.L. Eyre, and J.W. Muncie:Phil. Mag. A, 1987, vol. 56, pp. 453–84.
V.E. Ostrovskii:Russ. Chem. Rev., 1974, vol. 43, pp. 921–32.
I.G. Murgulescu and M.I. Vass:Rev. Roum. Chim., 1969, vol. 14, pp. 1201–14.
R.D. Holmes, H.St.C. O’Neill, and R.J. Arculus:Geochim. Cosmochim. Acta, 1986, vol. 50, pp. 2439–52.
W.R. Tyson:Can. Metall. Q., 1975, vol. 14, pp. 307–14.
W.F. Egelhoff, Jr.:Phys. Rev. B, 1984, vol. 29, pp. 3681–83.
I. Savchenko, G.K. Boreskov, A.V. Kalinkin, and A.N. Salanov:Kinet. Catal., 1984, vol. 24, pp. 983–90.
A. Mattsson, I. Panas, P. Siegbahn, U. Wahlgren, and H. Akeby:Phys. Rev. B, 1987, vol. 36, pp. 7389–7401.
V.G. Venugopal, V.S. Iyer, V. Sundaresh, Z. Singh, P. Prasad, and D.D. Sood:J. Chem. Thermodyn., 1987, vol. 19, pp. 19–25.
B. Adolphi and H.-J. Müssig:Krist. Tech., 1978, vol. 13, pp. 317–30.
J. Steffan and S. Hofmann:Surf. Interface Anal., 1988, vol. 11, pp. 617–26; vol. 12, pp. 437-38.
Smithell’s Metal Reference Book, 6th ed., E.A. Brandes, ed., Butterworth’s, Boston, MA, 1983.
O. Kubaschewski and C.B. Alcock:Metallurgical Thermochemistry, 5th ed., Pergamon Press, New York, NY, 1979.
E.H. Lee and L.K. Mansur:Phil. Mag. A, 1990, vol. 107, in press.
S.J. Zinkle and R.L. Sindelar:J. Nucl. Mater., 1988, vol. 155–157, pp. 1196–1200.
M.F. Wehner: Lawrence Livermore National Lab., Livermore, CA, private communication, 1985.
M.B. Lewis, N.H. Packan, G.F. Wells, and R.A. Buhl:Nucl. Instrum. Methods B, 1979, vol. 167, pp. 233–47.
S.J. Zinkle and R.L. Sindelar:Nucl. Instrum. Methods B, 1986, vol. B16, pp. 154–62.
L.E. Seitzman, R.A. Dodd, and G.L. Kulcinski:Metall. Trans. A, in press. Preprint available as UWFDM-771, University of Wisconsin-Madison, Madison, WI.
B. Badger, Jr., D.L. Plumton, S.J. Zinkle, R.L. Sindelar, G.L. Kulcinski, R.A. Dodd, and W.G. Wolfer: inEffects of Radiation on Materials, 12th Int. Symp., ASTM STP 870, F.A. Garner and J.S. Perrin, eds., ASTM, Philadelphia, PA, 1985, pp. 297–316.
M.R. Mruzik and K.R. Russell:Surf. Sci., 1977, vol.67, pp. 205–25.
V.I. Protasov and V.G. Chudinov:Radiat. Eff., 1982, vol. 66, pp. 1–7.
R. Bullough and R.C. Perrin: inRadiation Damage in Reactor Materials, International Atomic Energy Agency, Vienna, 1969, vol. II, pp. 233–51.
B.N. Singh and A.J.E. Foreman:J. Nucl. Mater., 1988, vol. 155–157, pp. 1258–62.
S. Kojima, Y. Sano, T. Yoshiie, N. Yoshida, and M. Kiritani:J. Nucl. Mater., 1986, vol. 141–143, pp. 763–66.
A.A. Gadalla, W. Jäger, and P. Ehrhart:J. Nucl. Mater., 1986, vol. 137, pp. 73–76.
P. Ehrhart, A.A. Gadalla, W. Jäger, and N. Tsukuda:Acta Metall., 1987, vol. 35, pp. 1929–41.
K.H. Westmacott:Cryst. Lattice Defects, 1976, vol. 6, pp. 203–08.
G. Lindner and G. Weyer:Mater. Sci. Forum, 1987, vol. 15–18, pp. 569–74.
L.D. Glowinski:J. Nucl. Mater., 1976, vol. 61, pp. 8–21.
L.D. Glowinski and C. Fiche:J. Nucl. Mater., 1976, vol. 61, pp. 29–40; L.D. Glowinski, C. Fiche, and M. Lott:J. Nucl. Mater., 1973, vol. 47, pp. 295–310.
S.J. Zinkle, G.L. Kulcinski, and R.W. Knoll:J. Nucl. Mater., 1986, vol. 138, pp. 46–56.
D.B. Bullen: Ph.D. Thesis, University of Wisconsin-Madison, Madison, WI, 1984.
L.M. Wang, R.A. Dodd, and G.L. Kulcinski:J. Nucl. Mater., 1986, vol. 141–143, pp. 713–17.
J.B. Whitley: Ph.D. Thesis, University of Wisconsin-Madison, Madison, WI, 1978.
R.L. Sindelar, G.L. Kulcinski, and R.A. Dodd:J. Nucl. Mater., 1984, vol. 122–123, pp. 246–51.
R.L. Sindelar, G.L. Kulcinski, and R.A. Dodd:J. Nucl. Mater., 1985, vol. 133–134, pp. 544–48.
R.L. Sindelar: Ph.D. Thesis, University of Wisconsin- Madison, Madison, WI, UWFDM-637, 1985.
J.H. Swisher and E.T. Turkdogan:Trans. TMS-AIME, 1967, vol. 239, pp. 426–31.
J.T. Buswell, S.B. Fisher, J.E. Harbottle, and D.I.R. Noms: inPhysical Metallurgy of Reactor Fuel Elements, J.E. Harris and E.C. Sykes, eds., The Metals Society, London, 1975, pp. 170–74.
L.D. Glowinski and C. Fiche:J. Nucl. Mater., 1976, vol. 61, pp. 22–28.
V.E. Shevtsov and V.L. Lekhtmets:Russ. Metall., 1977, no. 6, pp. 30–32.
L.K. Mansur, E.H. Lee, P.J. Maziasz, and A.F. Rowcliffe:J. Nucl. Mater., 1986, vol. 141–143, pp. 633–46.
R.E. Stoller and G.R. Odette: inRadiation-Induced Changes in Microstructure, 13th Int. Symp., Part I, ASTM STP 955, F.A. Garner, N.H. Packan, and A.S. Kumar, eds., ASTM, Philadelphia, PA, 1987, pp. 371–92.
R.E. Stoller and G.R. Odette: inRadiation-Induced Changes in Microstructure, 13th Int. Symp., Part I, ASTM STP 955, F.A. Garner, N.H. Packan, and A.S. Kumar, eds., ASTM, Philadelphia, PA, 1987, pp. 358–70.
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This paper is based on a presentation made in the symposium “Irradiation-Enhanced Materials Science and Engineering” presented as part of the ASM INTERNATIONAL 75th Anniversary celebration at the 1988 World Materials Congress in Chicago, IL, September 25–29, 1988, under the auspices of the Nuclear Materials Committee of TMS-AIME and ASM-MSD
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Zinkle, S.J., Lee, E.H. Effect of oxygen on vacancy cluster morphology in metals. Metall Trans A 21, 1037–1051 (1990). https://doi.org/10.1007/BF02698236
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DOI: https://doi.org/10.1007/BF02698236