Skip to main content
Log in

Water-borne non-toxic high-performance inorganic silicate coatings

Des revêtements au silicate hydrodiluables non-toxiques inorganiques de haute performance

Wasserlösliche ungiftige anorganische Hochleistungslacke auf Silikatbasis

  • Papers
  • Published:
Surface Coatings International Part B: Coatings Transactions

Summaries

Silicate coatings are reactive inorganic coatings. These provide weather-, chemical- and temperature-resistance coatings with lasting decoration and protection of steel against corrosion. Properties of these coatings depend on the ratio of silica to alkali metal oxide. The drying rate and chemical resistance properties of the film increase with increasing ratio of silica to alkali metal oxide. However, water miscibility of the system decreases. Their curing mechanism shows an explicit difference between the curing on masonry and iron substrates. These coatings exhibit a unique property, namely their chemical reaction with the substrate, which accounts for their excellent abrasion resistance, thus making them a permanent part of the system.

Résumé

Les revêtements au silicate sont des revêtements inorganiques réactifs. Ils sont résistants aux intempéries, aux attaques chimiques et aux températures nuisibles tout en fournissant une décoration durable et en protégeant l’acier contre la corrosion. Les propriétés de ces revètements dépendent du rapport de leur silice à leur oxide métallique alcalin. La vitesse de séchage et les propriétés de résistance aux attaques chimiques du film augment au fur et à mesure qu’augmente le rapport silice sur oxide métallique alcalin. Cependant, la miscibilité avec l’eau diminue dans le système. Leur méchanisme de séchage montre une différence explicite entre le séchage du revêtement sur les substrats de maconnerie et sur les substrats de fer. Ces revêtements montrent une propriété unique, c’est à dire leur réaction chimique avec le substrat, ce qui explique leur excellente résistance à l’abrasion. Grace à cette propriété ils font partie permanente du système.

Zusammenfassung

Silikatlacke sind reaktive anorganische Lacke. Sie verleihen Resistenz zu Witterungseinflüssen, Temperaturschwangkungen und aggressiven Chemikalien, und sind gleichzeitig eine dekorative und korrosionshemmende Anstrichfarbe für Stahl. die Eigenschaften dieser Lacke hängen stark von ihrem Verhältnis von Silikat zu Alkalimetalloxid ab. Allerdings geht das einher mit einer geringere Mischbarkeit mit Wasser. Der Härteprozeß zeigt einen deutlichen Unterschied zwischen der Härtung auf Stuck und Stein, und der Härtung auf Eisensubstraten. Die Lacke reagieren mit den Substraten und werden ein dauerhafter Teil des Systemes, was ihnen ihre hervorragende Abrasionsresistenz verleiht.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Gettwert G, W Rieber and J Bonarius, ‘One-component silicate binder systems for coatings’,Surface Coatings International,81, (12), 596–603, 1998

    Article  CAS  Google Scholar 

  2. Hare C H, ‘Silicate binders’,Paintindia,48, (4), 47–51, 1998

    CAS  Google Scholar 

  3. Boxall J and J A V Fraunhofer,Paint Formulation: Principles and Practice, George Godwin Limited, London, 1980

    Google Scholar 

  4. Gimblett F G R,Inorganic Polymer Chemistry, Butterworths and Co Limited, London, 1963

    Google Scholar 

  5. Oil and Colour Chemists’ Association Australia,Surface Coatings,2, Chapman and Hall Ltd, New York, 1984

    Google Scholar 

  6. Vail J G,Soluble Silicates in Industry, Reinhold Pub Corp, New York, 1952

    Google Scholar 

  7. James S F, Kirk-Othmer:Encyclopedia of Chemical Technology,20, John Wiley & Sons, New York, 1984

    Google Scholar 

  8. Payne H F,Organic Coating Technology,2, John Wiley & Sons, New York, 1961

    Google Scholar 

  9. Hisashi S, Japanese Patent 78 144 940, 1978

  10. Mamoru O, Japanese Patent 79 52 124, 1979

  11. Masahiko H and I Ichiro, Japanese Patent 79 148 821, 1979

  12. Allan J L H, P D Readio, A M Bengali and R F Zuendt, US Patent 4 225 350, 1980

  13. Dainippon, Japanese Patent 60 64 667, 1985

  14. Nippon, Japanese Patent 61 115 965, 1986

  15. Figovskii O L, N K Narkovich, A A Kozlov, V G Dudakov, A V Osadchii, V Y Petrenko, Y S Rysmagambetov and E V Popova, USSR Patent 1 680 739, 1991

  16. Campbell L E and S D Stookey, US Patent 4 125 651, 1978

  17. Schutt J B, US Patent 862 880, 1978

  18. Shirotsuka M and K Narita, Japanese Patent 79 134 784, 1979

  19. Osaka, Japanese Patent 80 09 871, 1980

  20. Petrova T N, V V Pimenov, C I A Sokol, N B Kamlyuk, T G Bezvoditskaya and N N Temlyak, USSR Patent 823 402, 1981

  21. Pentel, Japanese Patent 81 152 870, 1981

  22. Osaka, Japanese Patent 81 161 477, 1981

  23. Kubota, Japanese Patent 79 40 839, 1979

  24. Dainippon, Japanese Patent 80 03 439, 1980

  25. Kansai, Japanese Patent 62 127 366, 1987

  26. Otsuka, Japanese Patent 63 99 268, 1988

  27. Otsuka, Japanese Patent 63 100 987, 1988

  28. Holcombe C E J and L R Chapman, US Patent 4 810 300, 1989

  29. Nakamura R, Japanese Patent 78 124 539, 1978

  30. Miyashita T and K Ijizuka, Japanese Patent 78 34 204, 1978

  31. Brown W F, US Patent 4 178 273, 1979

  32. Puzhanov G T, N A Falaleeva, K K Kuatbeav, A A Vakhitov and V V Ni, USSR Patent 767 154, 1980

  33. Shikoku, Japanese Patent 81 24 456, 1981

  34. Nippon, Japanese Patent 59 196 782, 1984

  35. Frey G T, D H Strong and J B Urbanski, US Patent 4 555 445, 1985

  36. Gavril C V Z and E A Badalov, USSR Patent 1 180 379, 1985

  37. Harder U, P Preuss and D Klaeger, Ger Patent 00 241 420, 1986

  38. Dey A K and A N Mukherjee, ‘Development of zinc-rich primer ethyl silicate −40 for corrosion protection of steel’,Paintindia,42, (4), 21–4, 1992

    CAS  Google Scholar 

  39. Parashar G, D Srivastava and P Kumar, ‘Ethyl silicate binders for high performance coatings’,Progress in Organic Coatings,42, (6), 1–14, 2001

    Article  CAS  Google Scholar 

  40. Bhakre V S, ‘Zinc silicate coatings’,Paintindia,29, (3), 85–90, 1979

    CAS  Google Scholar 

  41. Tanaka S, Japanese Patent 7839437, 1979

  42. Minoru T, M Takahashi, O Ishii, M Naito, Y Kusuhara and N Imahigashi, Japanese Patent 7929340, 1979

  43. Tanaka S, Japanese Patent 07 939 439, 1979

  44. Rotenberg D H, P M Cuffe, B L Laurin and P R Ramirez, US Patent 4 173 490, 1979

  45. Dianippon, Japanese Patent 81 24 464, 1981

  46. Brown K H and K M Wolma, US Patent 4 290 811, 1981

  47. Tanabe Y, N Matsuzoe, H Endo and K Adachi, Japanese Patent 06 340 848, 1984

  48. Dainippon, Japanese Patent 81 129 270, 1981

  49. Fukushima T, Japanese Patent 61 204 282, 1986

  50. Nippon, Japanese Patent 57 198 767, 1982

  51. Mitsui, Japanese Patent 58 185 660, 1983

  52. Kansai, Japanese Patent 05 945 361, 1984

  53. Hitachi, Japanese Patent 5951 951, 1984

  54. Otsuka, Japanese Patent 5936 157, 1984

  55. Matsushita, Japanese Patent 59 129 268, 1984

  56. Nippon, Japanese Patent 6051 756, 1985

  57. Fukushima T, Japanese Patent 61 204 283, 1986

  58. Ito H and M Yokota, Japanese Patent 62 181 370, 1987

  59. Toyo T and K K Toryo, Japanese Patent 81 159 256, 1981

  60. Wojnowaki W, J M Mawak, J Gaszkowski, M Jaczewaki, S Kanieczny, K Sienkiewicz and P Rosciszewski, Polish Patent 122 889, 1984

  61. Nippon, Japanese Patent 8124 464, 1981

  62. Sono S and Y Chihara, Japanese Patent 61 101 566, 1986

  63. Emblem H G, ‘Manufacture and uses of ethyl silicate’,Research and Industry,23, (12), 207–14, 1978

    CAS  Google Scholar 

  64. Charles G M, Structural Steel Painting Council, 1982

  65. Haller W, ‘Silicate paints for exterior use’,Advances in Organic Science and Technology,12, 55–7, 1990

    CAS  Google Scholar 

  66. Mukherjee S, ‘Ethyl silicate-based zinc-rich coatings’,Paintindia,49, (7), 31–8, 1999

    CAS  Google Scholar 

  67. Cavalcanti E and O Ferraz, ‘The use of electrochemical impedance measurements to assess the performance of organic coating systems on noval steel’,Progress in Organic Coatings,23, (8), 185–200, 1993

    Article  CAS  Google Scholar 

  68. Rani B, ‘Protective paints for ferrous metals’,Paintindia,31, (7), 3–7, 1981

    CAS  Google Scholar 

  69. Marphatia R K, ‘Zinc-rich coatings an alternative to galvanizing’,Paintindia,33, (3), 19–21, 1988

    Google Scholar 

  70. Nirvan Y P S and J H Jagannath, ‘Zinc paints and their uses in the navy’,Paintindia,38, (8), 31–7, 1988

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to PK Kamani.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Parashar, G., Bajpayee, M. & Kamani, P. Water-borne non-toxic high-performance inorganic silicate coatings. Surface Coatings International Part B: Coatings Transactions 86, 209–216 (2003). https://doi.org/10.1007/BF02699655

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02699655

Keywords

Navigation