Abstract
The elastic moduli (Y, η, σ andH) and some thermodynamical parameters, such as Debye temperatureθ D, diffusion constantD i and latent heat of melting ΔH m, of ZnF2-PbO-TeO2 glasses doped with some rare earth (Pr3+, Nd3+, Eu3+ and Tb3+) ions are determined as functions of temperature using piezo electric composite oscillator technique. All the parameters are found to decrease with increase in the atomic number Z of the rare earth ions and with increase in the temperature of measurement. The results are explained on the basis of the density of localized bonding defect states within the band gap of the material.
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Berthareau A, Flem Y Le, Couzi M, Conioni L, Segonds P, Sarger L and Ducase A 1994Mater. Res. Bull. 29 933
Brady G W 1986J. Chem. Phys. 27 300
Brodbeck C M and Iton L E 1985J. Chem. Phys. 83 428
Dimitrova-Pankova M, Dimetriov Y, Aranaudov M and Dimetrov V 1989Phys. Chem. Glasses 30 260
Hart S 1993J. Mater. Sci. (GB) 18 1264
Kartha P E S, Lakshman Kumar S J, Podaki V C and Gopal E S R 1983J. Acc. Soc. VII 15
Kozhukharov V, Burger H, Neovs S and Sidzhimov B 1986Polyhedron 5 91
Malla Wany R El 1993J. Appl. Phys. 73 4878
Malla Wany R El, Sidkey M, Khafasy S and Afifi H 1994Mater. Chem. Phys. 37 295
Mott N F and Davis V A 1979Electronic processes in non-crystalline materials (Oxford: Oxford Univ. Press)
Rami Reddy M, Ravi Kumar V, Veeraiah N and Apparao B 1995Indian J. Pure & Appl. Phys. 33 48
Ravi Kumar V, Veeraiah N and Sriram Murthy J 1994J. Mater. Sci. Lett. (GB) 13 1558
Ravi Kumar V, Rami Reddy M and Veeraiah N 1995Phys. Status Solidi (a) 14 56
Ravi Kumar V and Veeraiah N 1997aJ. Phys. Chem. Solids (accepted)
Ravi Kumar V, Veeraiah N, Bhuddudu S and Jaya Tyagaraju V 1997 bJ. Phys. III (accepted)
Ravi Kumar V, Veeraiah N and Apparao B 1997cIndian J. Pure & Appl. Phys. 35 129
Sekiya T 1992J. Non-Cryst. Solids 144 128
Satyanarayana J V and Bhuddudu S 1994J. Alloys & Compounds 214 97
Shelby J E 1994Key Engg. Mater. 94 43
Singh K, Singh D P and Bhatti S S 1992J. Pure Appl. Ultrason. 14 56
Sridhar B, Indra P and Bhatnagar A K 1995Indian J. Pure & Appl. Phys. 33 253
Swarna Latha N and Padmini A R K L 1986Indian J. Pure & Appl. Phys. 24 33
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Ravi Kumar, V., Veeraiah, N. Elastic properties of ZnF2-PbO-TeO2 glasses doped with certain rare earth ions. Bull Mater Sci 20, 667–675 (1997). https://doi.org/10.1007/BF02745074
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DOI: https://doi.org/10.1007/BF02745074