Skip to main content
Log in

Thermal expansion and heat capacity of GaAs and InAs

  • Devoted to the 100th Anniversary of Academician A. V. Novoselova
  • Published:
Inorganic Materials Aims and scope

Abstract

Thermal expansion of GaAs and InAs was measured in the temperature ranges from 396 to 1149 and from 441 to 1206 K, respectively. The thermal-expansion coefficients, Debye temperatures, and root-meansquare atomic displacements were calculated. These parameters were found to depend on the root-mean-square atomic weights of the compounds. Based on the published data and our heat capacity measurements on GaAs and InAs, the coefficients appearing in the equation for the temperature dependence of heat capacity in the temperature ranges from 200 K to the melting points of GaAs and InAs were determined

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Novikova, S.I.,Teplovoe rasshirenie tverdykh tel (Thermal Expansion of Solids), Moscow: Nauka, 1974.

    Google Scholar 

  2. Glazov, V.M., Glagoleva, N.N., and Evgen’ev, S.B., Volume Changes Accompanying Melting of Rock-Salt-Structure Materials,Izv. Akad. Nauk SSSR, Neorg. Mater., 1966, vol. 11, no. 3, pp. 418–423.

    Google Scholar 

  3. Glazov, V.M., Vobst, M., and Timoshenko, V.I.,Metody issledovaniya svoistv zhidkikh metallov i poluprovodnikov (Methods for Studying the Properties of Liquid Metals and Semiconductors), Moscow: Metallurgiya, 1989.

    Google Scholar 

  4. Chatillon, C., Ansara, I., Watson, A.,et al., Re-Assessment of the Thermodynamic Properties and Phase Diagrams of Ga-As and In-As Systems,CALPHAD: Comput. Coupling Phase Diagrams Thermochem., 1990, vol. 14, no. 2, pp. 203–214.

    CAS  Google Scholar 

  5. Sirota, N.N. and Chizhevskaya, S.N., Characteristic Temperatures of Mg2Si, Mg2Sn, and Si, inFizikokhimicheskii analiz (Physicochemical Analysis), Moscow: Gosstroiizdat, 1957, pp. 175–191.

    Google Scholar 

  6. Frantsevich, I.N., Elastic Constants of Metals and Alloys,Vopr. Poroshk. Metall. Prochn. Mater., 1956, no. 3, pp. 14–44.

  7. Glazov, V.M., Nashel’skii, A.Ya., and Lyutfalibekova, A.D., Thermal Expansion of Gallium and Indium Phosphides,Elektron. Tekh., Ser. 14: Mater., 1970, no. 5, pp. 33–35.

  8. Sirota, N.N. and Sidorov, A.A., Temperature-Dependent Heat Capacity and Debye Temperature of Si, GaP, and InAs from the Intensity of Bragg Reflections in the Range 7–310 K,Dokl. Akad. Nauk SSSR, 1988, vol. 303, no. 5, pp. 1123–1126.

    CAS  Google Scholar 

  9. Fiziko-khimicheskie svoistva poluprovodnikovykh veshchestv. Spravochnik (Physicochemical Properties of Semiconductors: A Handbook), Novoselova, A.V. and Lazarev, V.B., Eds., Moscow: Nauka, 1978.

    Google Scholar 

  10. Piesbergen, U., Die durchschnittlichen Atomwarmen der AIIIBIV Halbleiter AlSb, GaAs, GaSb, InP, InAs, InSb und die Atomwarme des elements Germanium zwischen 12 und 273 K,Z. Naturforsch., A: Phys. Sci., 1963, vol. 18, no. 2, pp. 141–147.

    Google Scholar 

  11. Sirota, N.N., Novikov, V.V., and Antyukhov, A.M., Heat Capacity and Thermodynamic Functions of (GaAs)x(InAs)1-x Solid Solutions in the Temperature Range 5–300 K,Dokl. Akad. Nauk SSSR, 1982, vol. 263, no. 1, pp. 96–100.

    CAS  Google Scholar 

  12. Bogdanov, V.I., Vekilov, Yu.Kh., Kadyshevich, A.E.,et al., Temperature-Dependent Heat Capacity and Bonding Characteristics of Some Diatomic Substances,Fiz. Tverd. Tela (Leningrad) 1970, vol. 12, no. 10, pp. 3001–3006.

    CAS  Google Scholar 

  13. Cetas, T.S., Tifford, C.R., and Swenson, A., Specific Heats of Cu, GaAs, GaSb, InAs, and InSb from 1 to 34 K,Phys. Rev., 1968, vol. 174, no. 2, pp. 835–844.

    Article  CAS  Google Scholar 

  14. Termicheskie konstanty veshchestv. Spravochnik (Thermal Constants of Substances: A Handbook), Glushko, V.P., Ed., Moscow: VINITI, 1971.

    Google Scholar 

  15. Sirota, N.N., Antyukhov, A.M., Novikov, V.V.,et al., Heat Capacity and Characteristic Thermodynamic Functions of GaAs-InP Solid Solutions in the Range 5–300 K,Dokl. Akad. Nauk SSSR, 1982, vol. 266, no. 1, pp. 104–108.

    Google Scholar 

  16. Sirota, N.N., Antjukhov, A.M., Novikov, V.V., and Fjodorov, V.A., Thermodynamic Functions of (InP)x(InAs)1-x from 5 to 300 K,Cryst. Res. Technol., 1982, vol. 17, no. 3, pp. 279–287.

    Article  CAS  Google Scholar 

  17. Yamaguchi, K., Chiba, Y., Yoshizava, M.,et al., Low-Temperature Specific Heat of GaP, InP, GaAs, InAs,Nippon Kinzoku Gakkaishi, 1996, vol. 60, no. 12, pp. 1181–1186.

    CAS  Google Scholar 

  18. Cox, R.N. and Pool, M.J., Heat Contents and Heat of Fusion of III–V Compounds,J. Chem. Eng. Data, 1967, vol. 12, no. 12, pp. 247–248.

    Article  CAS  Google Scholar 

  19. Lichter, B.D. and Sommelet, P., Thermal Properties of AIIIBV Compounds: II. High-Temperature Heat Contents and Heat of Fusion of InAs and GaAs,Trans. Metall. Soc. AIME, 1969, vol. 245, no. 2, pp. 1021–1027.

    CAS  Google Scholar 

  20. Dash, A.J., Finch, A., Gardner, P.J.,et al., Heat Capacity of Gallium Arsenide,J. Chem. Eng. Data, 1974, vol. 19, no. 2, pp. 113–114.

    Article  CAS  Google Scholar 

  21. Itagaki, K. and Yamaguchi, K., High Temperature Heat Contents of III–V Semiconductor Systems,Thermochim. Acta, 1990, vol. 163, pp. 1–12.

    Article  CAS  Google Scholar 

  22. Ohmer, M.C., Mitchel, W.C., Graves, G.A.,et al., Thermal Properties of Semi-Insulating GaAs Dilutely Alloyed with InAs,J. Appl. Phys., 1988, vol. 64, no. 5, pp. 2775–2777.

    Article  CAS  Google Scholar 

  23. Wenzl, H., Dahlen, A., Fattach, A.,et al., Phase Relations in GaAs Crystal Growth,J. Cryst. Growth, 1991, vol. 109, pp. 191–204.

    Article  CAS  Google Scholar 

  24. Glazov, V.M., Pashinkin, A.S., and Malkova, A.S., Heat Capacity of Cadmium Selenide from 360 to 760 K,Zh. Fiz. Khim., 1989, vol. 63, no. 1, pp. 38–40.

    CAS  Google Scholar 

  25. Malkova, A.S., Zharov, V.V., Shmoilova, G.I., and Pashinkin, A.S., Heat Capacity of Zinc and Cadmium Tellurides in the Range 360–760 K,Zh. Fiz. Khim., 1989, vol. 63, no. 1, pp. 41–43.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Glazov, V.M., Pashinkin, A.S. Thermal expansion and heat capacity of GaAs and InAs. Inorg Mater 36, 225–231 (2000). https://doi.org/10.1007/BF02757926

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02757926

Keywords

Navigation