Abstract
The borate radical is produced by the flash photolysis of an aqueous alkaline solution of NaBO2 and K2S2O8. The absorption spectrum of the transient borate radical shows two maxima. The self decay of this radical is second order. Rate constants for the reactions of this radical with some organic substrates have been determined.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Anderson J L, Eyring E M and Whittaker M P 1964J. Phys. Chem. 68 1128
Behar D, Czapski G and Duchovny I 1970J. Phys. Chem. 74 2206
Degliotti L and Hayon E 1967J. Phys. Chem. 71 2511
Elango T P, Ramakrishnan V, Vancheesan S and Kuriacose J C 1984Proc. Indian Acad. Sci. (Chem. Sci.) 93 47
Elango T P, Ramakrishnan V, Vancheesan S and Kuriacose J C 1985Tetrahedron 41 3837
Elango T P, Ramakrishnan V and Kuriacose J C 1985J. Indian Chem. Soc. 62 1033
Goulden J D S 1959Spectrochim. Acta 9 657
Hayon E and McGarvey J J 1967J. Phys. Chem. 71 1472
Ingri N 1963Acta Chim. Scand. 17 581
Maya L 1976Inorg. Chem. 15 2179
Morkovnik A F and Okhlobystein O Yu 1979Russ. Chem. Rev. (Engl. Transl.) 48 1055
Nies N P and Campbell G W 1964 inBoron, metallo-boron compounds and boranes (ed) R M Adams (New York: Interscience) p. 80
Roebke W, Renz M and Henglein A 1969Int. J. Radial. Phys. Chem. 1 39
Ross A B and Neta P 1979National standard reference data series (Washington: US Natl. Bur. Stand.) No. 65
Salentine C G 1983Inorg. Chem. 22 3920
Subramanian P, Ramakrishnan V, Rajaram J and Kuriacose J C 1986Proc. Indian Acad. Sci. (Chem. Sci.) 97 573
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Padmaja, S., Ramakrishnan, V., Rajaram, J. et al. Generation and reactions of the borate radical — A flash photolysis study. Proc. Indian Acad. Sci. (Chem. Sci.) 100, 297–303 (1988). https://doi.org/10.1007/BF02840539
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02840539