Abstract
In the light of the equation of motion method a general expression for polarisability calculation has been derived. From this general expression, different approximation methods can be deduced for different choices of ground state and excitation manifold. Among these the coupled Hartree-Fock theory is the most extensively used one for polarisability calculations. It has also been shown that this theory has a simple relationship with random phase approximation.
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References
Caves T C and Karplus M 1969J. Chem. Phys. 50 3649
Cizek J 1966J. Chem. Phys. 45 4256
Dierksen G and McWeeny R 1966J. Chem. Phys. 44 3554
Dodds J L, McWeeny R, Raynes W T and Riley J P 1977Mol. Phys. 33 611
Dunning T H and McKoy V 1967J. Chem. Phys. 47 1735
Langhoff P W, Karplus M and Hurst R P 1966J. Chem. Phys. 44 505
Langhoff P W, Epstein S T and Karplus M 1972Rev. Mod. Phys. 44 602 and references therein.
Loudon R 1978The quantum theory of light (Oxford: University Press)
McCurdy C W, Jr, Rescigno T N, Yeager D L and McKoy V 1977 inMethods of electronic structure theory, (ed) H F Schaefer (New York: Plenum) pp. 339–82
McLachlan A D 1964Mol. Phys. 8 39
McLachlan A D and Ball M A 1964Rev. Mod. Phys. 36 844
McWeeny R 1962Phys. Rev. 126 1028
Monkhorst H J 1977Int. J. Quant. Chem. S11 421
Mukherjee D and Mukherjee P K 1979Chem. Phys. 39 325
Rowe D J 1968Rev. Mod. Phys. 40 153
Shibuya T, Rose J and McKoy V 1973J. Chem. Phys. 58 500
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Gupta, M., Bhattacharyya, S. On the calculation of second order properties: An equation of motion approach. Pramana - J Phys 22, 579–587 (1984). https://doi.org/10.1007/BF02846409
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DOI: https://doi.org/10.1007/BF02846409