Abstract
The kinetics of oxidation of allyl alcohol by chloramine-T (CAT) in presence of 0·02 M hydrochloric acid and at a constant ionic strength (μ=0·5 M) have been studied polarographically at six different temperatures between 30°C and 45°C. The reaction shows first order dependence on concentration of chloramine-T. The energy and entropy of activation have been found to be 13·7 kcal mol−1 and −28·4 e.u. respectively.
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Ganapathy, K., Vijayan, B. Polarographic study of the kinetics of oxidation of allyl alcohol by chloramine-T. Proc. Indian Acad. Sci., A (Chemical Sciences) 87, 215–217 (1978). https://doi.org/10.1007/BF03182134
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DOI: https://doi.org/10.1007/BF03182134