Abstract
The kinetics of oxidation of allyl alcohol by chloramine-T (CAT) in presence of 0·02 M hydrochloric acid and at a constant ionic strength (μ=0·5 M) have been studied polarographically at six different temperatures between 30°C and 45°C. The reaction shows first order dependence on concentration of chloramine-T. The energy and entropy of activation have been found to be 13·7 kcal mol−1 and −28·4 e.u. respectively.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Berka A, Vulterin J and Zyka J 1965 inNewer Redox Titrants (New York: Pergamon) pp. 37–45
Kolthoff I M and Lingane J 1952 inPolarography (New York: Interscience)
Mahadevappa D S and Naidu H M K 1974Aust. J. Chem. 27 1203
Morris J C, Salazar J R and Winemann M A 1948J. Am. Chem. Soc. 70 2036
Moshier R W 1943Ind. Eng. Chem. Anal. Ed.15 107
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ganapathy, K., Vijayan, B. Polarographic study of the kinetics of oxidation of allyl alcohol by chloramine-T. Proc. Indian Acad. Sci., A (Chemical Sciences) 87, 215–217 (1978). https://doi.org/10.1007/BF03182134
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF03182134