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The fascinating implications of new results in gold chemistry

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Abstract

Chemists today are increasingly fascinated by gold’s unique position in the family of elements. In this review, the author looks at important new results emerging from recent research in gold chemistry.

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References

  1. N.N. Greenwood, A. Earnshaw “Chemistry of the Elements’, Pergamon, Oxford 1984, 1364 ff

    Google Scholar 

  2. E. Zintl, J. Goubeau, W.Z. Dullenkopf, Z.Phys. Chem., 1931, A 154 1; A.H. Sommer,Nature (London) 1943,152, 215; W.J. Peer, J.J. Lagowski,J. Amer. Chem. Soc., 1978,100, 6260

  3. J.L. Dye,Angew. Chem., 1979,91, 613;Angew. Chem. Int. Ed. Engl., 1979,18, 587

    Article  CAS  Google Scholar 

  4. T.G. Spiro,Progr. Inorg. Chem., 1970,11, 1; K.A. Gingerich,J. Cryst. Growth, 1971,9, 31; J. Kordis, K.A. Gingerich, R.J. Seyse,J. Chem. Phys., 1974,61, 5114

    Article  CAS  Google Scholar 

  5. A.F. Wells, ‘Structural Inorganic Chemistry’, 5th Ed., Clarendon Press, Oxford, 1987

    Google Scholar 

  6. H. Schmidbaur, K.C. Dash,Adv. Inorg. Chem. Radiochem., 1982,25, 239

    Article  CAS  Google Scholar 

  7. R.J. Puddephatt in ‘Comprehensive Coordination Chemistry’ (G. Wilkinson, R.D. Gillard, J.A. McLeverty, eds.) Vol. 5, Pergamon, Oxford 1987, and in ‘Comprehensive Organometallic Chemistry’ (G. Wilkinson, F.G.A. Stone, E.W. Abel, editors), Vol.2, Pergamon, Oxford, 1985

    Google Scholar 

  8. R.J. Puddephatt ‘The Chemistry of Gold’, Elsevier, Amsterdam, 1978

    Google Scholar 

  9. H. Schmidbaur in ‘Gold 100’, Vol.3, ASIMM, Johannesburg, 1986

    Google Scholar 

  10. D.M.P. Mingos,Gold Bull., 1984,17, 5;

    CAS  Google Scholar 

  11. J. Chem. Soc. Dalton Trans., 1163, 1976

  12. K.P. Hall, D.M.P. Mingos,Progr. Inorg. Chem., 1984,32, 237

    Article  CAS  Google Scholar 

  13. H. Schmidbaur ‘Organogold Compounds’, Gmelin Handbook of Inorganic Chemistry, Springer-Verlag, Berlin, 1980

    Google Scholar 

  14. H. Schmidbaur, A. Wohlleben, F. Wagner, D.F. van der Vondel, G.P. van der Kelen,Chem. Ber., 1977,110, 2758; H. Schmidbaur, J.R. Mandl, A. Frank, G. Huttner, ibid. 1976,109, 466

    Article  CAS  Google Scholar 

  15. P.G. Jones,Gold Bull., 1981,14, 102 and 159;

    CAS  Google Scholar 

  16. ibid., 1983,16, 114;

    CAS  Google Scholar 

  17. ibid., 1986,19, 46

    CAS  Google Scholar 

  18. P. Pyykkö, J.P. Desclaux,Accounts Chem. Res., 1979,12, 276; K.S. Pitzer,ibid., 1979,12, 271, and literature therein

    Article  Google Scholar 

  19. P. Pyykkö,Chem. Rev., 1988,88, 563, and refs. therein

    Article  Google Scholar 

  20. N. Rösch, A. Görling, D.E. Ellis, H. Schmidbaur,Angew. Chem., 1989,101, 1410;Angew. Chem. Int. Ed. Engl., 1989,28, 1357

    Article  Google Scholar 

  21. Y. Jiang, S. Alvarez, R. Hoffmann,Inorg. Chem., 1985,24, 749

    Article  CAS  Google Scholar 

  22. K.M. Merz, R. Hoffmann,Inorg. Chem., 1988,27, 2120; P. K. Mehrotra, R. Hoffmann,ibid., 1978,17, 2187. A. Dedieu, R. Hoffmann,J. Amer. Chem. Soc. 1978,100, 2074

    Article  CAS  Google Scholar 

  23. Ref. l, p. 1369

  24. F. Scherbaum, A. Grohmann, B. Huber, C. Krüger, H. Schmidbaur,Angew. Chem., 1988,100, 1602;Angew. Chem. Int. Ed. Engl., 1988,27, 1544

    Article  CAS  Google Scholar 

  25. Chem. Eng. News,1988, Dec. 5;New Scientist 1989, July 8, p. 39

  26. W.S. Rapson,Gold Bull., 1989,22, 19

    Google Scholar 

  27. R. Hoffmann,American Scientist, 1989,77, 330

    Google Scholar 

  28. H. Schmidbaur,Angew. Chem., 1976,88, 830;Angew. Chem. Int. Ed. Engl., 1976,15, 728

    Article  CAS  Google Scholar 

  29. Ref. 13c, p. 55, and numerous papers from the laboratory of J.P. Fackler

  30. Ref. 13a, p. 105; Ref. 13b, p. 115

  31. P.G. Jones,Z. Naturforsch. B, 1982,37, 823

    Google Scholar 

  32. S. Esperas,Acta Chem. Scand., 1976,A30, 527

    Article  CAS  Google Scholar 

  33. A.A.M. Aly, U. Schubert, D. Neugebauer, H. Schmidbaur,Angew. Chem., 1978,90, 125;Angew. Chem. Int. Ed. Engl., 1978,17, 125; H. Schmidbaur, A.A.M. Aly, U. Schubert,ibid., 1978,90, 905; 1978,17, 846

    Article  CAS  Google Scholar 

  34. Y. Inoguchi, B. Milewski-Mahrla, D. Neugebauer, G.P. Jones, H. Schmidbaur,Chem. Ber., 1983,116, 1487, and ref. therein

    Article  CAS  Google Scholar 

  35. S. Ahrland, B. Noren, A. Oskarsson,Acta Chem. Scand., 1985,24, 1330

    CAS  Google Scholar 

  36. M.G.B. Drew, M.J. Riedl,J. Chem. Soc. Dalton Trans., 1973,52

  37. J. Strähle, W. Hiller, W. Conzelmann,Z. Naturforsch., 1984,39, 538

    Google Scholar 

  38. H.-N. Adams, W. Hiller, J. Strähle,Z. Anorg. Allg. Chem., 1982,485, 81; W. Conzelmann, W. Hiller, J. Strähle,ibid., 1984,512, 169

    Article  CAS  Google Scholar 

  39. P.W.R. Corfield, H.M.M. Shearer,Acta Crystallogr., 1967,23, 156

    Article  CAS  Google Scholar 

  40. J.J. Guy, P.G. Jones, M.J. Mays, G.M. Sheldrick,J. Chem. Soc. Dalton Trans., 1977,8

  41. H. Schmidbaur, G. Weidenhiller, O. Steigelmann, G. Müller,Chem. Ber., in press

  42. H. Schmidbaur, G. Weidenhiller, O. Steigelmann, G. Müller,Z. Naturforsch., B, i. pr.

  43. H. Schmidbaur, A.A.M. Aly,Z. Naturforsch., B, 1979,34, 23

    Google Scholar 

  44. D.B. Dyson, R.V. Parish, C.A. McAuliffe, R.G. Pritchard, R. Fields, B. Beagley,J. Chem. Soc. Dalton Trans., 1989, 907

  45. G.J. Arai,Recl. Trav. Chim. Pays-Bas, 1962,81, 307

    Article  CAS  Google Scholar 

  46. S. Ahrland, K. Dreisch, B. Noren, A. Oskarsson,Acta Chem. Scand., 1987, A41, 173

    Article  Google Scholar 

  47. J. Meyer, H. Piana, H. Wagner, U. Schubert,Chem. Ber., in press

  48. R.F. Baggio, S. Baggio,J. Inorg. Nucl. Chem., 1973,35, 3191; H. Ruben, A. Zalkin, M.O. Faltens, D.H. Templeton,Inorg. Chem., 1974,13, 1836

    Article  CAS  Google Scholar 

  49. Gmelin Handbuch d. Anorg. Chem., 8. Aufl., Silber B3, Verlag Chemie, Weinheim, 1973, 117

  50. H. Schmidbaur, A. Wohlleben, F. Wagner, O. Orama, G. Huttner,Chem. Ber., 1977,110, 1748

    Article  CAS  Google Scholar 

  51. H. Schmidbaur, R. Herr, T. Pollok, G. Reber, A. Schier, G. Müller,Phosphorus & Sulfur, 1987,30, 273, H. Schmidbaur, A. Schier, G. Reber, G. Müller,Inorg. Chim. Acta, 1988,147, 143

    Article  CAS  Google Scholar 

  52. H. Schmidbaur, T. Pollok, G. Reber, G. Müller,Chem. Ber., 1988,121, 1345

    Article  CAS  Google Scholar 

  53. P.A. Bates, J.M. Waters,Inorg. Chim. Acta, 1985,98, 125; M.K. Cooper, L.E. Mitchell, K. Henrick, M. McPartlin, A. Scott,Inorg. Chim. Acta, 1984,84, L9

    Article  CAS  Google Scholar 

  54. R. Uson, A. Laguna, M. Laguna, E. Fernandez, M.D. Villacampa, P.G. Jones, G.M. Sheldrick,J. Chem. Soc. Dalton Trans., 1983, 1679

  55. H. Schmidbaur, C. Paschalidis, O. Steigelmann, G. Müller,Chem. Ber., 1989,122, 1851

    Article  CAS  Google Scholar 

  56. P.G. Jones,Acta Crystallogr., B, 1980,36, 2775

    Article  Google Scholar 

  57. Ref. 5, p. 1033 ff.

    Google Scholar 

  58. H. Schmidbaur, W. Graf, G. Müller,Helv. Chim. Acta, 1986,69, 1748;Angew. Chem., 1988,100, 439;Angew. Chem. Int. Ed. Engl., 1988,27, 417

    Article  CAS  Google Scholar 

  59. H. Schmidbaur, K. Dziwok, A. Grohmann, G. Müller,Chem. Ber:, 1989,122, 893

    Article  CAS  Google Scholar 

  60. K. Dziwok, J. Lachmann, G. Müller, H. Schmidbaur,Chem. Ber., in press

  61. Y. Kai, P. Knochel, S. Kwiatkowski, J.D. Dunitz, J.F.M. Oth, D. Seebach, H.O. Kalinowski,Helv. Chim. Acta, 1982,65, 137

    Article  CAS  Google Scholar 

  62. H. Schmidbaur, A. Wohlleben, U. Schubert, G. Huttner,Chem. Ber., 1977,110, 2751

    Article  CAS  Google Scholar 

  63. M.N.I. Khan, C. King, D.D. Heinrich, J.P. Fackler, L.C. Porter,Inorg. Chem., 1989,28, 2150

    Article  CAS  Google Scholar 

  64. J.D. Basil, H.H. Murray, J.P. Fackler, J. Tocher, A.M. Manany, B.T. Bancroft, H. Knachel, D. Dudis, T.J. Delord, D.O. Marler,J. Amer: Chem. Soc., 1985,107, 6908

    Article  CAS  Google Scholar 

  65. H. Schmidbaur, R. Franke,Inorg. Chim. Acta, 1975,13, 81

    Google Scholar 

  66. H. Schmidbaur, J.R. Mandl, W. Richter, V. Bejenke, A. Frank, G. Huttner,Chem. Ber:, 1977,110, 2236

    Article  CAS  Google Scholar 

  67. H. Schmidbaur, H.P. Scherm, U. Schubert,ibid., 1978,111, 764

    Article  CAS  Google Scholar 

  68. H. Schmidbaur, T. Pollok, R. Herr, F.E. Wagner, R. Bau, J. Riede, G. Müller,Organometallics, 1986,5, 566

    Article  CAS  Google Scholar 

  69. H. Schmidbaur, T. Pollok, G. Reber, G. Müller,Chem. Ber., 1988,121, 1345

    Article  CAS  Google Scholar 

  70. A. Müller, H. Domfield, G. Henkel, B. Krebs, M.P.A. Viegers,Angew. Chem., 1978,90, 57;Angew. Chem. Int. Ed. Engl., 1978,17, 52

    Article  Google Scholar 

  71. C.L. Teske,Z. Anorg. Allg. Chem., 1978,445, 193

    Article  CAS  Google Scholar 

  72. M.N.I. Khan, J.P. Fackler, C. King, J.C. Wang, S. Wang,Inorg. Chem., 1988,27, 1673; O. Piovesana, P.F. Zanazzi,Angew. Chem., 1980,92, 577;Angew. Chem. Int. Ed. Engl., 1980,19, 561

    Google Scholar 

  73. Y. Inoguchi, B. Milewski-Mahrla, H. Schmidbaur,Chem. Ber., 1982,115, 3085

    Article  CAS  Google Scholar 

  74. H. Schmidbaur, J.R. Mandl, J.M. Bassett, G. Blaschke, B. Zimmer-Gasser,Chem. Ber., 1981,114, 433

    Article  CAS  Google Scholar 

  75. C.E. Briant, K.P. Hall, D.M.P. Mingos,J. Organometal. Chem., 1982,229, C5

    Article  CAS  Google Scholar 

  76. W. Ludwig, W. Meyer,Helv. Chim. Acta, 1982,65, 934

    Article  CAS  Google Scholar 

  77. H.-R.C. Jaw, M.M. Savas, R.D. Rogers, W.R. Mason,Inorg. Chem., 1989,28, 1028

    Article  CAS  Google Scholar 

  78. C. King, J.-Ch. Wang, M.N.I. Khan, J.P. Fackler Jr.,Inorg. Chem., 1989,28, 2145

    Article  CAS  Google Scholar 

  79. J. Ebner v. Eschenbach, O. Kumberger, G. Müller, H. Schmidbaur,Chem. Ber:, in press

  80. A. Müller, M. Römer, H. Bögge, E. Krickmeyer, K. Schmitz,Inorg. Chim. Acta, 1984,85, L39;

    Article  Google Scholar 

  81. W.S. Krane, H. Beall,Inorg. Chim. Acta, 1978,31, L469

    Article  Google Scholar 

  82. V.G. Andrianov, Y.T. Struchkov, E.R. Rossinskaya,Zh. Strukt. Khim. 1974,15, 74; Engl. Transl: p. 65.

    CAS  Google Scholar 

  83. T.V. Baukova, Y.L. Shlovokhotov, Y.T. Struchkov,J. Organometal. Chem., 1981,220, 375

    Article  Google Scholar 

  84. E.G. Perevalova, K.I. Grandberg, T.V. Baukova, V.P. Dyadchenko, Y.L. Shlovokhotov, Y.T. Struchkov,Koord. Khim., 1982,8, 1337

    CAS  Google Scholar 

  85. H. Schmidbaur, Y. Inoguchi,Chem. Ber., 1980,113, 1646 and refs. therein

    Article  CAS  Google Scholar 

  86. S. Gambarotta, C. Floriani, A. Chiesi-Villa, C. Guastini,J. Chem. Soc. Chem. Commun., 1983, 1304

  87. J. Vicente, M.T. Chicote, J.A. Cayuelas, J. Fernandez-Baeza, P.G. Jones, G.M. Sheldrick, P. Espinet,J. Chem. Soc., Dalton Trans., 1985, 1163

  88. H. Schmidbaur, F. Scherbaum, B. Huber, G. Müller,Angew. Chem., 1988,100, 441;Angew. Chem. Int. Ed. Engl., 1988,27, 419

    Article  CAS  Google Scholar 

  89. E.I. Smyslova, E.G. Perevalova, V.P. Dyadchenko, K.I. Grandberg, Y.L. Shiovokhotov, Y.T. Struchkov,J. Organometal. Chem., 1981,215, 269

    Article  CAS  Google Scholar 

  90. A.N. Nesmeyanov, G.G. Perevalova, Y.T. Struchkov, M.Y. Antipin, K.I. Grandberg, V.P. Dyadchenko,J. Organometal. Chem., 1980,201, 343

    Article  CAS  Google Scholar 

  91. C. Lensch, P.G. Jones, G.M. Sheldrick,Z. Naturforsch., B, 1982,37, 944; P.G. Jones, C. Lensch, G.M. Sheldrick,ibid., 141

    Google Scholar 

  92. G. Marbach, J. Strähle,Angew. Chem., 1984,96, 695;Angew. Chem. Int., Ed. Engl. 1984,23, 715

    Article  CAS  Google Scholar 

  93. C.E. Briant, K.P. Hall, A.C. Wheeler, D.M.P. Mingos,J. Chem. Soc. Chem. Commun., 1984, 248

  94. P.G. Jones, G.M. Sheldrick, E. Hädicke,Acta Crystallogr., 1980, B36, 2777

    Article  Google Scholar 

  95. Y.L. Shiovokhotov, Y.T. Struchkov,J. Organometal. Chem., 1984,277, 143

    Article  Google Scholar 

  96. Diss. W. Kreß, Univ. Erlangen-Nürnberg, 1983

  97. P.G. Jones, G.M. Sheldrick, R. Uson, A. Laguna,Acta Crystallogr., B, 1980,36, 1486

    Article  Google Scholar 

  98. H. Schmidbaur, F. Scherbaum, B. Huber, G. Müller,Angew. Chem., 1988,100, 441;Angew. Chem. Int. Ed. Engl., 1988,27, 419

    Article  CAS  Google Scholar 

  99. F. Scherbaum, B. Huber, G. Müller, H. Schmidbaur,Angew. Chem., 1988,100, 1600;Angew. Chem. Int. Ed. Engl., 1988,27, 1542

    Article  CAS  Google Scholar 

  100. F. Scherbaum, A. Grohmann, B. Huber, C. Krüger, H. Schmidbaur,Angew. Chem., 1988,100, 1602;Angew. Chem. Int. Ed. Engl., 1988,27, 1544

    Article  CAS  Google Scholar 

  101. F. Scherbaum, A. Grohmann, G. Müller, H. Schmidbaur,Angew. Chem. 1989,101, 464;Angew. Chem. Int., Ed. Engl., 1989,28, 463

    Article  CAS  Google Scholar 

  102. J.J. Steggerda, J.J. Bour, J.W.A. van der Velden,Recl. Trav. Chim. Pays-Bas, 1982,101, 164

    Article  CAS  Google Scholar 

  103. C.E. Briant, K.P. Hall, D.M.P. Mingos,J. Organometal. Chem., 1983,254, C 18

    Article  CAS  Google Scholar 

  104. P.L. Bellon, F. Cariati, Manaserro, L. Maldini, M. Sansoni,Chem. Commun., 1971, 1432; P.L. Bellon, M. Manaserro, M. Sansoni,J. Chem. Soc. Chem. Commun., 1972, 1035

  105. H. Schmidbaur, A. Grohmann, unpubl. results, 1989

  106. R. Uson, A. Laguna, M. Laguna, M.T. Tarton, P.G. Jones,J. Chem. Soc. Chem. Commun., 1988, 740;

  107. H. Schmidbaur, C. Hartmann, G. Reber, G. Müller,Angew. Chem., 1987,99, 1189;Angew. Chem. Int., Ed. Engl., 1987,26, 1146;

    Article  CAS  Google Scholar 

  108. R.G. Raptis, J.P. Fackler, H.H. Murray, L.C. Porter,Inorg. Chem., in press

  109. H.H. Murray, D.A. Briggs, G. Garzon, R.G. Raptis, L.C. Porter, J.P. Fackler,Organometallics, 1987,6, 1992

    Article  CAS  Google Scholar 

  110. S. Wang, J.P. Fackler,Organometallics, 1988,7, 2415; 1989,8, 1578; S. Wang, J.P. Fackler, C. King, J.C. Wang,J. Amer. Chem. Soc. 1988,110, 3308; C. King, D.D. Heinrich, G. Garzon, J.-C. Wang, J.P. Fackler,J. Amer. Chem. Soc. 1989,111, 2300

    Article  CAS  Google Scholar 

  111. A.L. Balch, J.K. Nagle, M.M. Olmstaedt, P.E. Reedy,J. Amer. Chem. Soc., 1987,109, 4123; J.K. Nagle, A.L. Balch, M.M. Olmstaedt,ibid., 1988,110, 319

    Article  CAS  Google Scholar 

  112. Ref. 13c, p. 48

  113. See chapters on compounds with transition metal bonds to gold in ref. 13

  114. P. Braunstein, J. Rosé,Gold Bull., 1985,18, 17

    CAS  Google Scholar 

  115. M. Jansen,Angew. Chem., 1987,99, 1136;Angew. Chem. Int., Ed. Engl., 1987,27, 1098

    Article  CAS  Google Scholar 

  116. W.S. Rapson, T. Groenewald ‘Gold Usage’, Academic Press, London, 1978

    Google Scholar 

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Schmidbaur, H. The fascinating implications of new results in gold chemistry. Gold Bull 23, 11–21 (1990). https://doi.org/10.1007/BF03214710

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