Abstract
Chemists today are increasingly fascinated by gold’s unique position in the family of elements. In this review, the author looks at important new results emerging from recent research in gold chemistry.
Similar content being viewed by others
References
N.N. Greenwood, A. Earnshaw “Chemistry of the Elements’, Pergamon, Oxford 1984, 1364 ff
E. Zintl, J. Goubeau, W.Z. Dullenkopf, Z.Phys. Chem., 1931, A 154 1; A.H. Sommer,Nature (London) 1943,152, 215; W.J. Peer, J.J. Lagowski,J. Amer. Chem. Soc., 1978,100, 6260
J.L. Dye,Angew. Chem., 1979,91, 613;Angew. Chem. Int. Ed. Engl., 1979,18, 587
T.G. Spiro,Progr. Inorg. Chem., 1970,11, 1; K.A. Gingerich,J. Cryst. Growth, 1971,9, 31; J. Kordis, K.A. Gingerich, R.J. Seyse,J. Chem. Phys., 1974,61, 5114
A.F. Wells, ‘Structural Inorganic Chemistry’, 5th Ed., Clarendon Press, Oxford, 1987
H. Schmidbaur, K.C. Dash,Adv. Inorg. Chem. Radiochem., 1982,25, 239
R.J. Puddephatt in ‘Comprehensive Coordination Chemistry’ (G. Wilkinson, R.D. Gillard, J.A. McLeverty, eds.) Vol. 5, Pergamon, Oxford 1987, and in ‘Comprehensive Organometallic Chemistry’ (G. Wilkinson, F.G.A. Stone, E.W. Abel, editors), Vol.2, Pergamon, Oxford, 1985
R.J. Puddephatt ‘The Chemistry of Gold’, Elsevier, Amsterdam, 1978
H. Schmidbaur in ‘Gold 100’, Vol.3, ASIMM, Johannesburg, 1986
D.M.P. Mingos,Gold Bull., 1984,17, 5;
J. Chem. Soc. Dalton Trans., 1163, 1976
K.P. Hall, D.M.P. Mingos,Progr. Inorg. Chem., 1984,32, 237
H. Schmidbaur ‘Organogold Compounds’, Gmelin Handbook of Inorganic Chemistry, Springer-Verlag, Berlin, 1980
H. Schmidbaur, A. Wohlleben, F. Wagner, D.F. van der Vondel, G.P. van der Kelen,Chem. Ber., 1977,110, 2758; H. Schmidbaur, J.R. Mandl, A. Frank, G. Huttner, ibid. 1976,109, 466
P.G. Jones,Gold Bull., 1981,14, 102 and 159;
ibid., 1983,16, 114;
ibid., 1986,19, 46
P. Pyykkö, J.P. Desclaux,Accounts Chem. Res., 1979,12, 276; K.S. Pitzer,ibid., 1979,12, 271, and literature therein
P. Pyykkö,Chem. Rev., 1988,88, 563, and refs. therein
N. Rösch, A. Görling, D.E. Ellis, H. Schmidbaur,Angew. Chem., 1989,101, 1410;Angew. Chem. Int. Ed. Engl., 1989,28, 1357
Y. Jiang, S. Alvarez, R. Hoffmann,Inorg. Chem., 1985,24, 749
K.M. Merz, R. Hoffmann,Inorg. Chem., 1988,27, 2120; P. K. Mehrotra, R. Hoffmann,ibid., 1978,17, 2187. A. Dedieu, R. Hoffmann,J. Amer. Chem. Soc. 1978,100, 2074
Ref. l, p. 1369
F. Scherbaum, A. Grohmann, B. Huber, C. Krüger, H. Schmidbaur,Angew. Chem., 1988,100, 1602;Angew. Chem. Int. Ed. Engl., 1988,27, 1544
Chem. Eng. News,1988, Dec. 5;New Scientist 1989, July 8, p. 39
W.S. Rapson,Gold Bull., 1989,22, 19
R. Hoffmann,American Scientist, 1989,77, 330
H. Schmidbaur,Angew. Chem., 1976,88, 830;Angew. Chem. Int. Ed. Engl., 1976,15, 728
Ref. 13c, p. 55, and numerous papers from the laboratory of J.P. Fackler
Ref. 13a, p. 105; Ref. 13b, p. 115
P.G. Jones,Z. Naturforsch. B, 1982,37, 823
S. Esperas,Acta Chem. Scand., 1976,A30, 527
A.A.M. Aly, U. Schubert, D. Neugebauer, H. Schmidbaur,Angew. Chem., 1978,90, 125;Angew. Chem. Int. Ed. Engl., 1978,17, 125; H. Schmidbaur, A.A.M. Aly, U. Schubert,ibid., 1978,90, 905; 1978,17, 846
Y. Inoguchi, B. Milewski-Mahrla, D. Neugebauer, G.P. Jones, H. Schmidbaur,Chem. Ber., 1983,116, 1487, and ref. therein
S. Ahrland, B. Noren, A. Oskarsson,Acta Chem. Scand., 1985,24, 1330
M.G.B. Drew, M.J. Riedl,J. Chem. Soc. Dalton Trans., 1973,52
J. Strähle, W. Hiller, W. Conzelmann,Z. Naturforsch., 1984,39, 538
H.-N. Adams, W. Hiller, J. Strähle,Z. Anorg. Allg. Chem., 1982,485, 81; W. Conzelmann, W. Hiller, J. Strähle,ibid., 1984,512, 169
P.W.R. Corfield, H.M.M. Shearer,Acta Crystallogr., 1967,23, 156
J.J. Guy, P.G. Jones, M.J. Mays, G.M. Sheldrick,J. Chem. Soc. Dalton Trans., 1977,8
H. Schmidbaur, G. Weidenhiller, O. Steigelmann, G. Müller,Chem. Ber., in press
H. Schmidbaur, G. Weidenhiller, O. Steigelmann, G. Müller,Z. Naturforsch., B, i. pr.
H. Schmidbaur, A.A.M. Aly,Z. Naturforsch., B, 1979,34, 23
D.B. Dyson, R.V. Parish, C.A. McAuliffe, R.G. Pritchard, R. Fields, B. Beagley,J. Chem. Soc. Dalton Trans., 1989, 907
G.J. Arai,Recl. Trav. Chim. Pays-Bas, 1962,81, 307
S. Ahrland, K. Dreisch, B. Noren, A. Oskarsson,Acta Chem. Scand., 1987, A41, 173
J. Meyer, H. Piana, H. Wagner, U. Schubert,Chem. Ber., in press
R.F. Baggio, S. Baggio,J. Inorg. Nucl. Chem., 1973,35, 3191; H. Ruben, A. Zalkin, M.O. Faltens, D.H. Templeton,Inorg. Chem., 1974,13, 1836
Gmelin Handbuch d. Anorg. Chem., 8. Aufl., Silber B3, Verlag Chemie, Weinheim, 1973, 117
H. Schmidbaur, A. Wohlleben, F. Wagner, O. Orama, G. Huttner,Chem. Ber., 1977,110, 1748
H. Schmidbaur, R. Herr, T. Pollok, G. Reber, A. Schier, G. Müller,Phosphorus & Sulfur, 1987,30, 273, H. Schmidbaur, A. Schier, G. Reber, G. Müller,Inorg. Chim. Acta, 1988,147, 143
H. Schmidbaur, T. Pollok, G. Reber, G. Müller,Chem. Ber., 1988,121, 1345
P.A. Bates, J.M. Waters,Inorg. Chim. Acta, 1985,98, 125; M.K. Cooper, L.E. Mitchell, K. Henrick, M. McPartlin, A. Scott,Inorg. Chim. Acta, 1984,84, L9
R. Uson, A. Laguna, M. Laguna, E. Fernandez, M.D. Villacampa, P.G. Jones, G.M. Sheldrick,J. Chem. Soc. Dalton Trans., 1983, 1679
H. Schmidbaur, C. Paschalidis, O. Steigelmann, G. Müller,Chem. Ber., 1989,122, 1851
P.G. Jones,Acta Crystallogr., B, 1980,36, 2775
Ref. 5, p. 1033 ff.
H. Schmidbaur, W. Graf, G. Müller,Helv. Chim. Acta, 1986,69, 1748;Angew. Chem., 1988,100, 439;Angew. Chem. Int. Ed. Engl., 1988,27, 417
H. Schmidbaur, K. Dziwok, A. Grohmann, G. Müller,Chem. Ber:, 1989,122, 893
K. Dziwok, J. Lachmann, G. Müller, H. Schmidbaur,Chem. Ber., in press
Y. Kai, P. Knochel, S. Kwiatkowski, J.D. Dunitz, J.F.M. Oth, D. Seebach, H.O. Kalinowski,Helv. Chim. Acta, 1982,65, 137
H. Schmidbaur, A. Wohlleben, U. Schubert, G. Huttner,Chem. Ber., 1977,110, 2751
M.N.I. Khan, C. King, D.D. Heinrich, J.P. Fackler, L.C. Porter,Inorg. Chem., 1989,28, 2150
J.D. Basil, H.H. Murray, J.P. Fackler, J. Tocher, A.M. Manany, B.T. Bancroft, H. Knachel, D. Dudis, T.J. Delord, D.O. Marler,J. Amer: Chem. Soc., 1985,107, 6908
H. Schmidbaur, R. Franke,Inorg. Chim. Acta, 1975,13, 81
H. Schmidbaur, J.R. Mandl, W. Richter, V. Bejenke, A. Frank, G. Huttner,Chem. Ber:, 1977,110, 2236
H. Schmidbaur, H.P. Scherm, U. Schubert,ibid., 1978,111, 764
H. Schmidbaur, T. Pollok, R. Herr, F.E. Wagner, R. Bau, J. Riede, G. Müller,Organometallics, 1986,5, 566
H. Schmidbaur, T. Pollok, G. Reber, G. Müller,Chem. Ber., 1988,121, 1345
A. Müller, H. Domfield, G. Henkel, B. Krebs, M.P.A. Viegers,Angew. Chem., 1978,90, 57;Angew. Chem. Int. Ed. Engl., 1978,17, 52
C.L. Teske,Z. Anorg. Allg. Chem., 1978,445, 193
M.N.I. Khan, J.P. Fackler, C. King, J.C. Wang, S. Wang,Inorg. Chem., 1988,27, 1673; O. Piovesana, P.F. Zanazzi,Angew. Chem., 1980,92, 577;Angew. Chem. Int. Ed. Engl., 1980,19, 561
Y. Inoguchi, B. Milewski-Mahrla, H. Schmidbaur,Chem. Ber., 1982,115, 3085
H. Schmidbaur, J.R. Mandl, J.M. Bassett, G. Blaschke, B. Zimmer-Gasser,Chem. Ber., 1981,114, 433
C.E. Briant, K.P. Hall, D.M.P. Mingos,J. Organometal. Chem., 1982,229, C5
W. Ludwig, W. Meyer,Helv. Chim. Acta, 1982,65, 934
H.-R.C. Jaw, M.M. Savas, R.D. Rogers, W.R. Mason,Inorg. Chem., 1989,28, 1028
C. King, J.-Ch. Wang, M.N.I. Khan, J.P. Fackler Jr.,Inorg. Chem., 1989,28, 2145
J. Ebner v. Eschenbach, O. Kumberger, G. Müller, H. Schmidbaur,Chem. Ber:, in press
A. Müller, M. Römer, H. Bögge, E. Krickmeyer, K. Schmitz,Inorg. Chim. Acta, 1984,85, L39;
W.S. Krane, H. Beall,Inorg. Chim. Acta, 1978,31, L469
V.G. Andrianov, Y.T. Struchkov, E.R. Rossinskaya,Zh. Strukt. Khim. 1974,15, 74; Engl. Transl: p. 65.
T.V. Baukova, Y.L. Shlovokhotov, Y.T. Struchkov,J. Organometal. Chem., 1981,220, 375
E.G. Perevalova, K.I. Grandberg, T.V. Baukova, V.P. Dyadchenko, Y.L. Shlovokhotov, Y.T. Struchkov,Koord. Khim., 1982,8, 1337
H. Schmidbaur, Y. Inoguchi,Chem. Ber., 1980,113, 1646 and refs. therein
S. Gambarotta, C. Floriani, A. Chiesi-Villa, C. Guastini,J. Chem. Soc. Chem. Commun., 1983, 1304
J. Vicente, M.T. Chicote, J.A. Cayuelas, J. Fernandez-Baeza, P.G. Jones, G.M. Sheldrick, P. Espinet,J. Chem. Soc., Dalton Trans., 1985, 1163
H. Schmidbaur, F. Scherbaum, B. Huber, G. Müller,Angew. Chem., 1988,100, 441;Angew. Chem. Int. Ed. Engl., 1988,27, 419
E.I. Smyslova, E.G. Perevalova, V.P. Dyadchenko, K.I. Grandberg, Y.L. Shiovokhotov, Y.T. Struchkov,J. Organometal. Chem., 1981,215, 269
A.N. Nesmeyanov, G.G. Perevalova, Y.T. Struchkov, M.Y. Antipin, K.I. Grandberg, V.P. Dyadchenko,J. Organometal. Chem., 1980,201, 343
C. Lensch, P.G. Jones, G.M. Sheldrick,Z. Naturforsch., B, 1982,37, 944; P.G. Jones, C. Lensch, G.M. Sheldrick,ibid., 141
G. Marbach, J. Strähle,Angew. Chem., 1984,96, 695;Angew. Chem. Int., Ed. Engl. 1984,23, 715
C.E. Briant, K.P. Hall, A.C. Wheeler, D.M.P. Mingos,J. Chem. Soc. Chem. Commun., 1984, 248
P.G. Jones, G.M. Sheldrick, E. Hädicke,Acta Crystallogr., 1980, B36, 2777
Y.L. Shiovokhotov, Y.T. Struchkov,J. Organometal. Chem., 1984,277, 143
Diss. W. Kreß, Univ. Erlangen-Nürnberg, 1983
P.G. Jones, G.M. Sheldrick, R. Uson, A. Laguna,Acta Crystallogr., B, 1980,36, 1486
H. Schmidbaur, F. Scherbaum, B. Huber, G. Müller,Angew. Chem., 1988,100, 441;Angew. Chem. Int. Ed. Engl., 1988,27, 419
F. Scherbaum, B. Huber, G. Müller, H. Schmidbaur,Angew. Chem., 1988,100, 1600;Angew. Chem. Int. Ed. Engl., 1988,27, 1542
F. Scherbaum, A. Grohmann, B. Huber, C. Krüger, H. Schmidbaur,Angew. Chem., 1988,100, 1602;Angew. Chem. Int. Ed. Engl., 1988,27, 1544
F. Scherbaum, A. Grohmann, G. Müller, H. Schmidbaur,Angew. Chem. 1989,101, 464;Angew. Chem. Int., Ed. Engl., 1989,28, 463
J.J. Steggerda, J.J. Bour, J.W.A. van der Velden,Recl. Trav. Chim. Pays-Bas, 1982,101, 164
C.E. Briant, K.P. Hall, D.M.P. Mingos,J. Organometal. Chem., 1983,254, C 18
P.L. Bellon, F. Cariati, Manaserro, L. Maldini, M. Sansoni,Chem. Commun., 1971, 1432; P.L. Bellon, M. Manaserro, M. Sansoni,J. Chem. Soc. Chem. Commun., 1972, 1035
H. Schmidbaur, A. Grohmann, unpubl. results, 1989
R. Uson, A. Laguna, M. Laguna, M.T. Tarton, P.G. Jones,J. Chem. Soc. Chem. Commun., 1988, 740;
H. Schmidbaur, C. Hartmann, G. Reber, G. Müller,Angew. Chem., 1987,99, 1189;Angew. Chem. Int., Ed. Engl., 1987,26, 1146;
R.G. Raptis, J.P. Fackler, H.H. Murray, L.C. Porter,Inorg. Chem., in press
H.H. Murray, D.A. Briggs, G. Garzon, R.G. Raptis, L.C. Porter, J.P. Fackler,Organometallics, 1987,6, 1992
S. Wang, J.P. Fackler,Organometallics, 1988,7, 2415; 1989,8, 1578; S. Wang, J.P. Fackler, C. King, J.C. Wang,J. Amer. Chem. Soc. 1988,110, 3308; C. King, D.D. Heinrich, G. Garzon, J.-C. Wang, J.P. Fackler,J. Amer. Chem. Soc. 1989,111, 2300
A.L. Balch, J.K. Nagle, M.M. Olmstaedt, P.E. Reedy,J. Amer. Chem. Soc., 1987,109, 4123; J.K. Nagle, A.L. Balch, M.M. Olmstaedt,ibid., 1988,110, 319
Ref. 13c, p. 48
See chapters on compounds with transition metal bonds to gold in ref. 13
P. Braunstein, J. Rosé,Gold Bull., 1985,18, 17
M. Jansen,Angew. Chem., 1987,99, 1136;Angew. Chem. Int., Ed. Engl., 1987,27, 1098
W.S. Rapson, T. Groenewald ‘Gold Usage’, Academic Press, London, 1978
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Schmidbaur, H. The fascinating implications of new results in gold chemistry. Gold Bull 23, 11–21 (1990). https://doi.org/10.1007/BF03214710
Issue Date:
DOI: https://doi.org/10.1007/BF03214710