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Geochemistry of heavy metals and sedimentation rate in a bay adjacent to the Caspian Sea

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Abstract

In the present investigation down core variations of heavy metals such as; Zn, Ni, Co, Mn, Fe and Al in a sediment core from Bay of Gorgan adjacent to the Caspian Sea was studied. Inter-relationship amongst various parameters was brought out through correlation coefficients and cluster analysis. The results of present study reveals that Zn, Ni, Co and Mn possess both lithogenous and non-lithogenous sources. The increasing trend of Al towards top of sediment core is indicative higher erosion in the recent years. Interestingly, concentration of all studied metals increases toward core top (except for Fe) that might be indicative of influence of man’s activities residing in catchment area of Gorgan Bay and also oil exploration in the Caspian Sea. Further, 210Pb and 137Cs techniques were used to find out rate of sedimentation. The result of dating is indicative of sedimentation rate between 1.4 to 2.45 mm/yr. based on 210Pb and 137Cs activities respectively.

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References

  • Al-Masri, M. S., A. Aba, H. Khalil, and Z. Al-Hares, Sedimentation rates and pollution history of a dried lake: Al-Oteibeh Lake. Science of the Total Environment, 293(1–3): 177–189, 2002

    Article  CAS  Google Scholar 

  • Amidi, J., M. M. Beithollahi, and M. Asefi, Calibration of gamma spectrometer with high pure germanium detector. IRNA-NRPD Technical Report, 1998

  • Amano, H. and Y. Onuma, Depth profiles of long lived radionuclides in Chernobyl soils sampled around 10 years after the accident. Journal of Radio analytical and Nuclear Chemistry, 255(1): 217–222, 2003

    Article  CAS  Google Scholar 

  • Ambers, R. K. R., Using the sediment record in a western Oregon flood-control reservoir to assess the influence of storm history and logging on sediment yield. Journal of Hydrology, 244(3–4): 181–200, 2001

    Article  CAS  Google Scholar 

  • Aslani, M.A. A., S. Aytas, S. Akyil, G. Yaprak, G. Yener, and M. Eral, Activity concentration of cesium-137 in agricultural soils. Journal of Environmental Radioactivity, 65(2): 131–145, 2003

    Article  CAS  Google Scholar 

  • Bellucci, L. G., B. El Moumni, F. Collavini, M. Frignani, and S. Albertazzi, Heavy metals in Morocco Lagoon and river sediments. Journal de Physique, IV 107 (Pt. 1): 139–142, 2003

    Google Scholar 

  • Bertolotto, R. M., B. Tortarolo, M. Frignani, L. G. Bellucci, S. Albanese, and C. Cuneo, Heavy metals in coastal sediments of the Ligurian sea off Vado Ligure. Journal de Physique, IV 107 (Pt. 1): 159–162, 2003

    CAS  Google Scholar 

  • Borretzen, P. and B. Salbu, Fixation of Cs to marine sediments estimated by a stochastic modeling approach. Journal of Environmental Radioactivity, 61(1): 1–20, 2002

    Article  CAS  Google Scholar 

  • Butman, B. and Bothner, M. H., Predicting the Long-Term Fate of Sediments and Contaminants in Massachusetts Bay. U.S. Geological Survey Fact Sheet, 172–97, 1998

  • Coker, W. B. and Shilts, W. W., Lacustrine geochemistry around the north shore of Lake Superior: Implications for the evaluation of the effects of acid precipitation: In Current Research, Part C, Geological Survey of Canada, Paper 79–1C: 1–15, 1979

  • Coker, W. B., Hornbrook, E. H. W. and Cameron, E. M., Lake sediment geochemistry applied to mineral exploration: In Geophysics and Geochemistry in the search for Metallic Ores; Peter J. Hood, editor; Geological Survey of Canada, Economic Geology Report 31: 435–478, 1979

    Google Scholar 

  • Coker, W. B., Kettles, I. M. and Shilts, W. W., Comparison of mercury concentrations in modern lake sediments and glacial drift in the Canadian Shield in the region of Ottawa/Kingston to Georgian Bay, Ontario, Canada: Water, Air and Soil Pollution, 80: 1025–1029, 1995

    Article  CAS  Google Scholar 

  • Farmer, J. G., The perturbation of historical pollution records in aquatic systems: Environmental Geochemistry and Health, 13(2): 76–83, 1991

    Article  CAS  Google Scholar 

  • Cline, J. T. and Upchurch, S. B., Mode of heavy metal migration in the upper strata of lake sediment: In Proceedings of the 16th Conference on Great Lakes Research. International Association on Great Lakes Research, 1: 349–356, 1973

    Google Scholar 

  • Friske, P. W. B., Effects of limnological variation on element distribution in lake sediments from Tatin lake, central British Columbia — implications for the use of lake sediment data in exploration and environmental studies: In Current Research 1995-E, Geological survey of Canada, 4: 59–67, 1995

    Google Scholar 

  • Gorham, E. and Swaine, D., The influence of oxidizing and reducing conditions upon the distribution of some elements in lake sediments: Limnology and Oceanography, 10: 268–279, 1965

    Google Scholar 

  • Guevara, S. R. and M. Arribere, Cs-137 dating of lake cores from the Nahuel Huapi National Park, Patagonia, Argentina: Historical records and profiles measurements. Journal of Radioanalytical and Nuclear Chemistry 252(1): 37–45, 2002

    Article  CAS  Google Scholar 

  • Henderson, P. J., The geochemistry of Lake Winnipeg long cores and bottom sediment samples: Namao cruise 94–900: Geological Survey of Canada, Open File Report 5: 3113, 1995

  • Huh, C. and Su, C., Sedimentation dynamics in the east China sea elucidated from Pb-210, Cs-137 and Pu-239-240. Marine Geology, 160: 183–196, 1999

    Article  CAS  Google Scholar 

  • Hutchinson, G. E., A Treatise on Limnology; Volume 1, Geography, Physics and Chemistry: Wiley and Sons, New York, 1015, 1957

    Google Scholar 

  • Jetter, H. W., Determining the ages of recent sediments using measurements of trace radioactivity. Terra et Aqua, 78: 21–28, 2000

    Google Scholar 

  • Karbassi, A. R., Geochemical and magnetic studies of riverine, estuarine and marine sediments. Ph.D. thesis, Mangalore University, India, 196, 1989

    Google Scholar 

  • Karbassi, A.R., Geochemistry of a sediment core and applications of analysis in interpretating data. The 16 th International Geochemical Exploration Symposium, Beijing, China, 1993

  • Karbassi, A. R. Geochemistry of Ni, Zn, Cu, Pb, Co, Cd, V, Mn, Fe, Al and Ca in sediments of North Western part of the Persian Gulf. Intl. J. Env. Studies, 54: 205–212, 1996

    Article  Google Scholar 

  • Karbassi, A. R., and Shankar, R., Geochemistry of two sediment cores from west coasts of India. IAWQ Sediment Conference, Milwaukee, U.S.A, 1993

  • Kettles, I. M., Shilts, W. W. and Coker, W. B., Surficial geochemistry south-central Canadian Shield: Implications for environmental assessment: In Geochemical Exploration 1989, Part II (A. W. Rose and P.M. Taufen, Editors), Journal of Geochemical Exploration, 41 (1/2): 29–57, 1991

  • Lee, S. V. and A. B. Cundy, Heavy metal contamination and mixing processes in sediments from the Humber Estuary, Eastern England. Estuarine Coastal and Shelf Science, 53(5): 619–636, 2001

    Article  CAS  Google Scholar 

  • Mackereth, F.J.H., Chemical investigation of lake sediments and their interpretation: Proceedings of the Royal Society, 161: 285–309, 1965

    Google Scholar 

  • Mortimer, C. H., The exchange of dissolved substances between mud and water in lakes. Part III and IV: Journal of Ecology, 30: 147–207, 1942

    CAS  Google Scholar 

  • Mortimer, C. H., Chemical exchanges between sediments and water in the Great Lakes — speculations on probable regulatory mechanisms: Limnology and Oceanography, 16(2): 387–404, 1971

    Article  CAS  Google Scholar 

  • Orson, R. A., Simpson, R. L., Good, R. E., A mechanism for the accumulation and retention of heavy metals in tidal freshwater marshes of the upper Delaware River estuary. Estuarine Coastal and Shelf Science, 34: 171–186, 1992

    Article  CAS  Google Scholar 

  • Rasmussen, P. E., Current methods of estimating mercury fluxes in remote areas: Environmental Science and Technology, 28(13): 2233–2241, 1994

    Article  CAS  Google Scholar 

  • Robbins, J. A. and Edgington, D. N., Determination of recent sedimentation rates in Lake Michigan using Pb-210 and Cs-137. Geochim Cosmochim Acta, 39: 285–304, 1975

    Article  CAS  Google Scholar 

  • Ruttner, F., Fundamentals of Limnology: University of Toronto Press, Toronto, 295, 1963

    Google Scholar 

  • Sain, K.S. and Neufeld, R.D., A dynamic model of bio-geochemical cycle of heavy and trace metals in natural aquatic systems: Paper presented at the Second International Symposium on Environmental Biogeochemistry, Burlington, Ontario, Canada, 20, 1975

  • Thomson, J., F.M. Dyer, and I. W. Croudace, Records of radionuclides deposition in two salt marshes in the United Kingdom with contrasting redox and accumulation conditions. Geochimica et Cosmochimica Acta 66(6): 1011–1023, 2002

    Article  CAS  Google Scholar 

  • Weis, D.A., J.C. Callaway, and R.M. Gersberg, Vertical accretion rates and heavy metal chronologies in wetland sediments of the Tijuana Estuary. Estuaries 24(6A): 840–850, 2001

    Article  CAS  Google Scholar 

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Karbassi, A.R., Amirnezhad, R. Geochemistry of heavy metals and sedimentation rate in a bay adjacent to the Caspian Sea. Int. J. Environ. Sci. Technol. 1, 191–198 (2004). https://doi.org/10.1007/BF03325832

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