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Chemistry of tetra- and pentavalent chromium

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Bond and Structure Models

Part of the book series: Structure and Bonding ((STRUCTURE,volume 63))

Abstract

This review provides information on synthesis, reactivities, solid state properties, and electronic and molecular structure of chromium(IV) and chromium(V) compounds that have been isolated in pure form. Spectroscopic properties, especially EPR of Cr5+ and Cr4+ ions doped in various host lattices, are also discussed. However, compounds that generated in solution as transient species, or occured as intermediates in redox reactions, lie outside the scope of discussion. The types of compounds which received major consideration are: oxo-compounds, peroxo complexes, halo and oxyhalo complexes, alkoxides, amides, alkyls, hydroxy carboxylates and macrocyclic compounds. Literature through 1984 is covered. It will be apparent from this article that certain aspects of chromium(IV) and chromium(V) chemistry will get enriched in future.

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  1. Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Calcutta, India

    Kamalaksha Nag & Satyendra Nath Base

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Nag, K., Base, S.N. (1985). Chemistry of tetra- and pentavalent chromium. In: Bond and Structure Models. Structure and Bonding, vol 63. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0001705

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