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Spin crossover in iron(II)-complexes

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Metal Complexes

Part of the book series: Structure and Bonding ((STRUCTURE,volume 44))

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Abbreviations

HS:

high-spin

LS:

low-spin

μ:

mean spin-pairing energy

Δ:

cubic ligand field parameter

kB :

Boltzmann factor

Tc :

transition temperature

μ:

magnetic moment

δ:

Mössbauer isomer shift

ΔEQ :

quadrupole splitting

phen:

1,10-phenanthroline

bipy:

2,2′-bipyridine

ox:

oxalate

mal:

malonate

py:

pyridine

2-pic:

2-picolylamine

pi:

α-picoline

pip:

2-pyridinaldehyde-N-isopropylimine

pmi:

2-pyridinaldehyde-N-methylimine

pyim:

2-(2′-pyridyl)imidazole

pyimi:

2-(2′-pyridyl)imidazoline

pyben:

2-(2′-pyridyl)benzimidazole

ppp:

3-phenyl-5-pyridyl-(2)-pyrazole

ppi:

2-pyridinalphenylimine

pythiaz:

2,4-bis(2-pyridyl)thiazole

paptH:

2-(2-pyridylamino)-4-(2-pyridyl)thiazole

dbtp:

2,6-(dibenzothiazol-2-yl)-pyridine

terpy:

2,2′,2″-terpyridyl

dpma:

di-(2-pyridylmethyl)amine

medpma:

di-(2-pyridylmethyl)methylamine

ppa:

N′-(2-pyridylmethyl)picolylamidine

pnp:

2,6-bis-(2-diphenylphosphinoethyl)pyridine

pmp:

2,6-bis-(2-diphenylphosphinomethyl)pyridine

HB(pz)3 :

hydrotris(1-pyrazolyl)borate

btz:

2,2′-bi-4,5-dihydrothiazine

bt:

2,2′-bi-2-thiazoline

dippen:

cis-1,2-bis(diphenylphosphino)ethylene

tren:

tris(2-aminoethyl)amine

[14]dieneN4 :

5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene

[14]aneN4 :

mesa-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane

dtc:

dithiocarbamate

tfd:

trifluoromethyldithiolene

mnt:

maleonitriledithiolene

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  1. Institut für Anorganische und Analytische Chemie, Universität, D-6500, Mainz

    Philipp Gütlich

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Gütlich, P. (1981). Spin crossover in iron(II)-complexes. In: Metal Complexes. Structure and Bonding, vol 44. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0111269

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