Abstract
Attempts to prepare single crystal gallium nitride in thin films and bulk form are reported. The thin films were prepared by reacting GaCl3 and NH3 and depositing on to single crystal silicon carbide substrates. The bulk gallium nitride was prepared by the conversion of single crystals of gallium arsenide using an intermediate oxide phase.
The structural perfection of the gallium nitride material thus formed has been assessed using X-ray diffraction and electron diffraction techniques. Both methods of preparation produced single phase gallium nitride exhibiting a high degree of structural disorder.
Similar content being viewed by others
References
W. C. Johnson, J. B. Parsons, and M. C. Crew, J. Phys. Chem. 36 (1932) 2651.
R. E. Stephens, B. Ke, and D. Trivich, ibid 59 (1955) 966.
H. G. Grimmeiss and H. Koelmans, Z. Naturforsch 14a (1959) 264.
Z. A. Munir and A. W. Searcy, J. Chem. Phys. 42 (1965) 4223.
H. Hahn and R. Juza, Z. anorg. Chem. 244 (1940) 111.
R. Juza and F. Hund, ibid 257 (1948) 13.
A. Addamiano, J. Electrochem. Soc. 108 (1961) 1072.
M. R. Lorenz and B. B. Binkowski, ibid 109 (1962) 24.
R. C. Schoonmaker and C. E. Burton, Inorg. Syn. 7 (1963) 16.
J. C. Gilles, Rev. Hautes Temp. Refractaires 2 (1965) 237.
H. G. Grimmeiss, R. Groth, and J. Maak, Z. Naturforsch. 15a (1960) 799.
R. J. Sime, and J. L. Margrave, J. Phys. Chem. 60 (1956) 810.
R. C. Schoonmaker, A. Buhl, and J. Lemley, ibid 69 (1965) 3455.
S. P. Gordienko, G. V. Samsonov, and V. V. Fesenko, Zh. Fiz. Khim. 38 (1964) 2974.
R. Juza and H. Hahn, Z. anorg Chem. 239 (1938) 282.
A. Rabenau and J. J. Berber, Phys. Lett. 12 (1967) 167.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Faulkner, K.R., Wickenden, D.K., Isherwood, B.J. et al. Gallium nitride formed by vapour deposition and by conversion from gallium arsenide. J Mater Sci 5, 308–313 (1970). https://doi.org/10.1007/PL00020097
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/PL00020097