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Microstructural and tribological behavior of in situ synthesized Ti/Co coatings on Ti-6Al-4V alloy using laser surface cladding technique

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Abstract

The enhancement of the tribological properties of titanium (Ti-6Al-4V) has been the subject of wide range research over the years. The constraints associated with Ti-6Al-4V in severe tribological conditions due of its low hardness and poor wear properties can be enhanced by appropriate enhancement of the microstructure via surface modification technique without altering the bulk material. In this work, Cp-Ti and Co powders were deposited at different admixed percentages by laser cladding on Ti-6Al-4V substrates with respect to laser processing parameters. The laser optimized parameters used are laser power 900 W, powder feed rate 1.0 g/min, beam spot size 3 mm, and gas flow rate 1.2 L/min while scan speed were varied at 0.6and 1.2m/min. The microstructural evolution as well as wear morphology of the coatings were studied using scanning electron microscope equipped with energy dispersed spectrometry (SEM/EDS) while the phase identification were observed using X-ray diffractometer (XRD). Microhardness values of the coatings were obtained while wear test was conducted using a reciprocating set up. The coatings exhibited a good metallurgical bonding between the coatings and the substrate. Results revealed that laser clad sample with high scan speed was more effective in improving the hardness and wear resistance of Ti-Co/Ti6Al4Vcompared to low scan speed. The coatings possess an average hardness value of 730 HV0.1, a value that is about two times greater than that of the substrate. The enhanced wear resistance with high laser scan speed has been attributed to the presence of flower-like structures and formation of fractions of CoTi2, CoTi, AlTi2, AlCo5, AlCo2Ti, and Al2Ti inter-metallic phases dispersed within the coating matrix. In addition, analysis of worn surfaces and wear mechanism indicated improved resistance to tribological actions.

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References

  1. O. Adesina, P. Popoola, and O. Fatoba, Laser surface modification—a focus on the wear degradation of titanium alloy, 2016

  2. Feng S-r, Tang H-b, Zhang S-q, Wang H-m (2012) Microstructure and wear resistance of laser clad TiB–TiC/TiNi–Ti2Ni intermetallic coating on titanium alloy. Transactions Nonferrous Metals Soc China 22:1667–1673, 7//

    Article  Google Scholar 

  3. Banerjee D, Williams JC (2013) Perspectives on titanium science and technology. Acta Materialia 61:844–879, 2//

    Article  Google Scholar 

  4. Weng F, Yu H, Chen C, Liu J, Zhao L, Dai J (2016) Microstructure and property of composite coatings on titanium alloy deposited by laser cladding with Co42+TiN mixed powders. J Alloys Compounds 686:74–81, 11/25/

    Article  Google Scholar 

  5. Bansal DG, Eryilmaz OL, Blau PJ (2011) Surface engineering to improve the durability and lubricity of Ti–6Al–4V alloy. Wear 271:2006–2015, 7/29/

    Article  Google Scholar 

  6. Garbacz H, Wieciński P, Ossowski M, Ortore MG, Wierzchoń T, Kurzydłowski KJ (2008) Surface engineering techniques used for improving the mechanical and tribological properties of the Ti6A14V alloy. Surface Coatings Technol 202:2453–2457, 2/25/

    Article  Google Scholar 

  7. Chikarakara E, Naher S, Brabazon D (2012) High speed laser surface modification of Ti–6Al–4V. Surface Coatings Technol 206:3223–3229, 3/15/

    Article  Google Scholar 

  8. Popoola API, Loto CA, Osifuye CO, Aigbodion VS, Popoola OM (2016) Corrosion and wear properties of Ni-Sn-P ternary deposits on mild steel via electroless method. Alexandria Engineering J 55:2901–2908, 9//

    Article  Google Scholar 

  9. Obadele BA, Andrews A, Olubambi PA, Mathew MT, Pityana S (2015) Effect of ZrO2 addition on the dry sliding wear behavior of laser clad Ti6Al4V alloy. Wear 328–329:295–300, 4/15/

    Article  Google Scholar 

  10. Fu Y, Zhang X-C, Sui J-F, Tu S-T, Xuan F-Z, Wang Z-D (2015) Microstructure and wear resistance of one-step in situ synthesized TiN/Al composite coatings on Ti6Al4V alloy by a laser nitriding process. Optics Laser Technol 67:78–85, 4//

    Article  Google Scholar 

  11. Mu M, Liang J, Zhou X, Xiao Q (2013) One-step preparation of TiO2/MoS2 composite coating on Ti6Al4V alloy by plasma electrolytic oxidation and its tribological properties. Surface Coatings Technol 214:124–130, 1/15/

    Article  Google Scholar 

  12. Yilbas BS, Hashmi MSJ, Shuja SZ (2001) Laser treatment and PVD TiN coating of Ti-6Al-4V alloy. Surface Coatings Technol 140:244–250, 6/1/

    Article  Google Scholar 

  13. Zhang J, Xue Q, Li S (2013) Microstructure and corrosion behavior of TiC/Ti(CN)/TiN multilayer CVD coatings on high strength steels. Appl Surface Sci 280:626–631, 9/1/

    Article  Google Scholar 

  14. Adebiyi DI, Popoola API (2015) Mitigation of abrasive wear damage of Ti–6Al–4V by laser surface alloying. Materials Design 74:67–75, 6/5/

    Article  Google Scholar 

  15. Savalani MM, Ng CC, Li QH, Man HC (2012) In situ formation of titanium carbide using titanium and carbon-nanotube powders by laser cladding. Appl Surface Sci 258:3173–3177, 1/15/

    Article  Google Scholar 

  16. J. Dutta Majumdar and I. Manna, 21—laser surface engineering of titanium and its alloys for improved wear, corrosion and high-temperature oxidation resistance. In: Waugh, J. L.G. (ed). Laser Surface Engineering. Woodhead Publishing, 2015, pp. 483–521

  17. Ion JC (2005) Chapter 12—cladding. In: Ion JC (ed) Laser Processing of Engineering Materials. Butterworth-Heinemann, Oxford, pp 296–326

    Chapter  Google Scholar 

  18. Li HC, Wang DG, Chen CZ, Weng F (2015) Effect of CeO2 and Y2O3 on microstructure, bioactivity and degradability of laser cladding CaO–SiO2 coating on titanium alloy. Colloids Surfaces B: Biointerfaces 127:15–21, 3/1/

    Article  Google Scholar 

  19. Paydas H, Mertens A, Carrus R, Lecomte-Beckers J, Tchoufang Tchuindjang J (2015) Laser cladding as repair technology for Ti–6Al–4V alloy: influence of building strategy on microstructure and hardness. Materials Design 85:497–510, 11/15/

    Article  Google Scholar 

  20. Wu C, Ma M, Liu W, Zhong M, Zhang H, Zhang W (2009) Laser cladding in situ carbide particle reinforced Fe-based composite coatings with rare earth oxide addition. J Rare Earths 27:997–1002, 12//

    Article  Google Scholar 

  21. Yang J, Liu F, Miao X, Yang F (2012) Influence of laser cladding process on the magnetic properties of WC–FeNiCr metal–matrix composite coatings. J Materials Processing Technol 212:1862–1868, 9//

    Article  Google Scholar 

  22. Cai F, Jiang C, Fu P, Ji V (2015) Effects of Co contents on the microstructures and properties of electrodeposited NiCo? Al composite coatings. Appl Surface Sci 324:482–489, 1/1/

    Article  Google Scholar 

  23. Gao L-l, Bian X-f, Tian Y-s, Fu C-x (2009) Effect of Co on microstructure and interfacial properties of Fe-based laser cladding. J Iron Steel Res, Int 16:84–88, 7//

    Article  Google Scholar 

  24. Langelier BC, Esmaeili S (2009) in situ laser-fabrication and characterization of TiC-containing Ti–Co composite on pure Ti substrate. J Alloys Compounds 482:246–252, 8/12/

    Article  Google Scholar 

  25. Xue Y, Wang HM (2005) Microstructure and wear properties of laser clad TiCo/Ti2Co intermetallic coatings on titanium alloy. Appl Surface Sci 243:278–286, 4/30/

    Article  Google Scholar 

  26. Alemohammad H, Esmaeili S, Toyserkani E (2007) Deposition of Co–Ti alloy on mild steel substrate using laser cladding. Materials Sci Engineering: A 456:156–161, 5/15/

    Article  Google Scholar 

  27. Amine T, Newkirk JW, Liou F (2014) Investigation of effect of process parameters on multilayer builds by direct metal deposition. Applied Thermal Engineering 73:500–511, 12/5/

    Article  Google Scholar 

  28. Telasang G, Dutta Majumdar J, Padmanabham G, Tak M, Manna I (2014) Effect of laser parameters on microstructure and hardness of laser clad and tempered AISI H13 tool steel. Surface Coatings Technol 258:1108–1118, 11/15/

    Article  Google Scholar 

  29. Mahamood RM, Akinlabi ET (2015) Effect of laser power and powder flow rate on the wear resistance behaviour of laser metal deposited TiC/Ti6Al4 V composites. Materials Today: Proceedings 2:2679–2686

    Article  Google Scholar 

  30. Liu X-B, Yu R-L (2009) Influences of precursor constitution and processing speed on microstructure and wear behavior during laser clad composite coatings on γ-TiAl intermetallic alloy. Materials Design 30:391–397, 2//

    Article  MathSciNet  Google Scholar 

  31. Sun G, Tong Z, Fang X, Liu X, Ni Z, Zhang W (2016) Effect of scanning speeds on microstructure and wear behavior of laser-processed NiCr–Cr3C2–MoS2–CeO2 on 38CrMoAl steel. Optics Laser Technol 77:80–90, 3//

    Article  Google Scholar 

  32. Dutta Majumdar J, Manna I, Kumar A, Bhargava P, Nath AK (2009) Direct laser cladding of Co on Ti–6Al–4V with a compositionally graded interface. J Materials Processing Technol 209:2237–2243, 3/1/

    Article  Google Scholar 

  33. Xue Y, Wang HM (2009) Microstructure and dry sliding wear resistance of CoTi intermetallic alloy. Intermetallics 17:89–97, 3//

    Article  Google Scholar 

  34. Zhu Y, Chen X, Zou J, Yang H (2016) Sliding wear of selective laser melting processed Ti6Al4V under boundary lubrication conditions. Wear 368–369:485–495, 12/15/

    Article  Google Scholar 

  35. Obadele BA, Masuku ZH, Olubambi PA (2012) Turbula mixing characteristics of carbide powders and its influence on laser processing of stainless steel composite coatings. Powder Technol 230:169–182, 11//

    Article  Google Scholar 

  36. Adesina OS, Mthisi A, Popoola API (2016) The effect of laser based synthesized Ti-Co coating on microstructure and mechanical properties of Ti6al4v alloy. Procedia Manufacturing 7:46–52

    Article  Google Scholar 

  37. Mahamood RM, Akinlabi ET, Shukla M, Pityana S (2013) Scanning velocity influence on microstructure, microhardness and wear resistance performance of laser deposited Ti6Al4V/TiC composite. Materials Design 50:656–666, 9//

    Article  Google Scholar 

  38. Shuja SZ, Yilbas BS (2011) Laser produced melt pool: influence of laser intensity parameter on flow field in melt pool. Optics Laser Technol 43:767–775, 6//

    Article  Google Scholar 

  39. Davydov AV, Kattner UR, Josell D, Waterstrat RM, Boettinger WJ, Blendell JE et al (2001) Determination of the CoTi congruent melting point and thermodynamic reassessment of the Co-Ti system. Metall Mater Trans A 32:2175–2186

    Article  Google Scholar 

  40. Weng F, Yu H, Chen C, Dai J (2015) Microstructures and wear properties of laser cladding Co-based composite coatings on Ti–6Al–4V. Mater Des 80:174–181

    Article  Google Scholar 

  41. Meng Q, Geng L, Ni D (2005) Laser cladding NiCoCrAlY coating on Ti-6Al-4V. Materials Letters 59:2774–2777, 9//

    Article  Google Scholar 

  42. Weng F, Chen C, Yu H (2014) Research status of laser cladding on titanium and its alloys: a review. Materials Design 58:412–425, 6//

    Article  Google Scholar 

  43. de Damborenea J (1998) Surface modification of metals by high power lasers. Surface Coatings Technol 100–101:377–382, 3//

    Article  Google Scholar 

  44. Gordani GR, ShojaRazavi R, Hashemi SH, Isfahani ARN (2008) Laser surface alloying of an electroless Ni–P coating with Al-356 substrate. Optics Lasers Engineering 46:550–557, 7//

    Article  Google Scholar 

  45. Rotella G, Alfano M, Candamano S (2015) Surface modification of Ti6Al4V alloy by pulsed Yb-laser irradiation for enhanced adhesive bonding. CIRP Ann Manuf Technol 64:527–530

    Article  Google Scholar 

  46. Fatoba OS, Popoola API, Aigbodion VS (2016) Experimental study of hardness values and corrosion behaviour of laser alloyed Zn-Sn-Ti coatings of UNS G10150 mild steel. J Alloys Compounds 658:248–254, 2/15/

    Article  Google Scholar 

  47. Emamian A, Corbin SF, Khajepour A (2011) The influence of combined laser parameters on in situ formed TiC morphology during laser cladding. Surface Coatings Technol 206:124–131, 10/15/

    Article  Google Scholar 

  48. Li J, Yu Z, Wang H (2011) Wear behaviors of an (TiB + TiC)/Ti composite coating fabricated on Ti6Al4V by laser cladding. Thin Solid Films 519:4804–4808, 5/31/

    Article  Google Scholar 

  49. Ma Q, Li Y, Wang J, Liu K (2015) Investigation on cored-eutectic structure in Ni60/WC composite coatings fabricated by wide-band laser cladding. J Alloys Compounds 645:151–157, 10/5/

    Article  Google Scholar 

  50. Cai B, Tan Y-f, Tu Y-q, Wang X-l, Tan H (2011) Tribological properties of Ni-base alloy composite coating modified by both graphite and TiC particles. Transactions Nonferrous Metals Soc China 21:2426–2432, 11//

    Article  Google Scholar 

  51. Zhang Y, Qu J, Wang H (2016) Wear characteristics of metallic counterparts under elliptical-locus ultrasonic vibration. Appl Sci 6:289

    Article  Google Scholar 

  52. Guo C, Zhou J, Yu Y, Wang L, Zhou H, Chen J (2012) Microstructure and tribological properties of Ti–Cu intermetallic compound coating. Materials Design 36:482–489, 4//

    Article  Google Scholar 

  53. Ali D, Butt MZ (2015) The inverse Hall-Petch effect in Nd:YAG laser irradiated nickel. Materials Today: Proceedings 2:5302–5307

    Article  Google Scholar 

  54. Zhang L, Wang C, Han L, Dong C (2017) Influence of laser power on microstructure and properties of laser clad Co-based amorphous composite coatings. Surfaces Interfaces 6:18–23, 3//

    Article  Google Scholar 

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Funding

This research is supported by the Tshwane University of Technology, Pretoria, in collaboration with the National Laser Centre (NLC), Council of scientific and industrial research (CSIR), Pretoria, South Africa.

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Authors and Affiliations

  1. Department of Chemical and Metallurgical Engineering, Tshwane University of Technology, P.M.B. X680, Pretoria, 0001, South Africa

    O. S. Adesina & A. P. I. Popoola

  2. Council for Scientific and Industrial Research (CSIR) – National laser Centre, P.O. BOX 395, BLD 46F, Pretoria, 0001, South Africa

    S. L. Pityana

  3. Department of Metallurgical and Materials Engineering, Federal University of Technology, Akure, P.M.B. 704, Akure, Ondo, Nigeria

    D. T. Oloruntoba

Authors
  1. O. S. Adesina
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  2. A. P. I. Popoola
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  3. S. L. Pityana
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  4. D. T. Oloruntoba
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Correspondence to O. S. Adesina.

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Adesina, O.S., Popoola, A.P.I., Pityana, S.L. et al. Microstructural and tribological behavior of in situ synthesized Ti/Co coatings on Ti-6Al-4V alloy using laser surface cladding technique. Int J Adv Manuf Technol 95, 1265–1280 (2018). https://doi.org/10.1007/s00170-017-1300-3

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  • DOI: https://doi.org/10.1007/s00170-017-1300-3

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