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Synthesis, characterization, and analytical application of zirconium(IV) selenoiodate, a new cation exchanger

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Abstract

Zirconium(IV) selenoiodates have been synthesized under a variety of conditions. The most chemically and thermally stable sample is prepared by adding a mixture of aqueous solutions of 0.1 mol L−1 potassium iodate and 0.1 mol L−1 sodium selenite to aqueous solution of 0.1 mol L−1 zirconium(IV) oxychloride. Its ion-exchange capacity for K+ and Pb2+ was found to be 3.20 and 2.35 meq g−1 dry exchanger, respectively. The material has been characterized on the basis of chemical composition, pH titration, and thermogravimetric analysis. The effect on the exchange capacity of drying the exchanger at different temperatures has also been studied. The analytical importance of the material has been established by quantitative separation of Pb2+ from other metal ions.

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References

  1. Velmurugan S, Sathyaseelam VS, Narasinhan SV, Mathur PK (1991) New development in ion exchange. In: Proceedings of international conference ion exchange ICIE’91, Tokyo

  2. Cross JE, Hooper EW (1988) In: Streat M (ed) Ion exchange for industry. Conf Proceeding Cambridge, Ellis Hardwood

  3. Hafez MA, Kenway IMM, Akl MA, Lashein RR (2001) Talanta 53:749

    Article  Google Scholar 

  4. Jaimez E, Robert CT, Slade (1997) J Chem Soc Dalton Trans 8:1435

    Article  Google Scholar 

  5. Quereshi SZ, Jamhour RMAQ, Rahman N (1996) Ann Chim (Paris) 21:609

    Google Scholar 

  6. Zhaong M, Damodar M, Clearfield A, Peng G (1996) Chem Matter 8:1333

    Article  Google Scholar 

  7. Sirlei R, Claudio A (1997) J Chem Soc Dalton Trans 14:2517

    Google Scholar 

  8. Ferragina C, Cafarelli P, Di Stefanis A, Di Rocco R, Giannoccaro P (2001) Mater Res Bull 36:1799

    Article  Google Scholar 

  9. Hayshi H, Onoda Y, Iwasaki T (2002) Nippon ion Kokan Gakkaishi 11:32

    Google Scholar 

  10. Clearfield A, Wang Z (2002) J Chem Soc Dalton Trans 7:2937

    Article  Google Scholar 

  11. Singh P, Rawat JP, Rahman N (2002) Indian J Chem 41A:1616

    Google Scholar 

  12. Singh P, Rawat JP, Rahman N (2003) Talanta 59:443

    Article  Google Scholar 

  13. Choube UN, Turel ZR (2003) Czech J Phys 53(suppl Apt 2):A539

    Google Scholar 

  14. Gupta AP, Verma GL, Ikram S (2000) React Funct Polym 43:31

    Article  Google Scholar 

  15. Varshney KG, Pandith AH, Gupta U (1998) Langmuir 14:7353

    Article  Google Scholar 

  16. Quereshi SZ, Khan MA, Rahman N (1995) Bull Chem Soc Jpn 68:1611

    Google Scholar 

  17. Mittal SK, Singh PP (1995) Indian J Chem 34A:1009

    Google Scholar 

  18. Gupta AP, Varshney PK (1997) React Funct Polym 32:67

    Article  Google Scholar 

  19. Tandon S, Pandit B, Chudasama U (1996) Trans Met Chem 21:7

    Article  Google Scholar 

  20. Nabi SA, Usmani S, Rahman N (1996) Ann Chim Fr 21:521

    Google Scholar 

  21. Quereshi SZ, Rahman N (1987) Bull Chem Soc Jpn 60:2627

    Google Scholar 

  22. Quereshi SZ, Rahman N (1987) Bull Chem Soc Fr 6:959

    Google Scholar 

  23. Snell FD, Snell CT (1949) Colorimetric methods of analysis, vol II. D Van Nostrand, Princeton, pp 335–741

  24. Furman NH (1962) Standard methods of chemical analysis, 6th edn, vol I. Van Nostrand, Princeton, pp 928–930

  25. Reilley CN, Schmid RW, Sadek FS (1959) J Chem Edu 35:555

    Google Scholar 

  26. Day RA Jr, Under Wood AL (2001) Quantitative analysis, 6th edn. Prentice-Hall, New Delhi, p 539

    Google Scholar 

  27. Quereshi M, Gupta JP, Sharma V (1973) Anal Chem 45:1901

    Google Scholar 

  28. Rawat JP, Mujtaba SQ (1975) Can J Chem 53:286

    Google Scholar 

  29. Nabi SA, Siddiqi ZM (1985) Bull Chem Soc Jpn 58:724

    CAS  Google Scholar 

  30. Alberti G, Torroca E, Conte A (1966) J Inorg Nucl Chem 28:607

    Article  CAS  Google Scholar 

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Acknowledgements

The authors are grateful to the Council of Scientific and Industrial Research, (CSIR), New Delhi, India, for providing financial assistance.

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Authors and Affiliations

  1. Department of Chemistry, Indian Institute of Technology, Roorkee 247667, India

    V. K. Gupta & Premvir Singh

  2. Department of Chemistry, Aligarh Muslim University, Aligarh 202002, India

    Nafisur Rahman

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  1. V. K. Gupta
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  2. Premvir Singh
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  3. Nafisur Rahman
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Correspondence to V. K. Gupta.

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Gupta, V.K., Singh, P. & Rahman, N. Synthesis, characterization, and analytical application of zirconium(IV) selenoiodate, a new cation exchanger. Anal Bioanal Chem 381, 471–476 (2005). https://doi.org/10.1007/s00216-004-2949-7

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  • DOI: https://doi.org/10.1007/s00216-004-2949-7

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