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Preparation and properties of a new chelating resin containing imidazolyl azo groups

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Abstract

A new chelating resin incorporating imidazolyl azo groups into a matrix of polystyrene divinylbenzene has been prepared. The exchange capacity of the resin for the ions mercury (II), silver(I) and lead(II) as a function of pH has been determined. The resin exhibits no affinity to alkali, or alkaline earth metals. It is highly selective for only mercury(II) and silver(I). In column operation it has been observed that mercury(II) in trace quantities is very effectively removed from river water spiked with mercury(II) at the usual pH of natural waters.

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References

  1. Sigel H (ed) (1973–80) Metal ions in biological systems, vols 2(1973), 5(1976), 6(1976), 10(1980), 15(1983), 16(1983), 17(1984), 20(1986), 23(1988), 24(1988). Dekker, New York

    Google Scholar 

  2. Pearson RG (1963) J Am Chem Soc 85: 3533

    Article  CAS  Google Scholar 

  3. Myers RT (1978) Inorg Chem 17: 952

    Article  CAS  Google Scholar 

  4. Sugii A, Ogawa N, Inuma Y, Tamamura H (1981) Talanta 28: 551

    Article  CAS  Google Scholar 

  5. Ghosh JP, Das HR (1981) Talanta 28: 274

    Article  CAS  Google Scholar 

  6. Suresh K Sahni, Reedijk J (1984) Coord Chem Review 59: 1 (and references therein)

    Article  Google Scholar 

  7. Sengupta B, Laskar S, Das J (1988) Ind J Technol 26: 139

    CAS  Google Scholar 

  8. Syamal A, Singh MM (1994) Ind J Chem 33A: 58

    CAS  Google Scholar 

  9. Konar B, Basu S (1994) Fresenius J Anal Chem 348: 281

    Article  CAS  Google Scholar 

  10. Gold DH, Gregor HP (1960) J Phys Chem 64: 1461

    Article  CAS  Google Scholar 

  11. Welleman JA, Hulsbergen FB, Reedijk J (1981) Makromol Chem 182: 785

    Article  CAS  Google Scholar 

  12. Drago RS, Gaul JH (1979) Inorg Chem 18: 2019

    Article  CAS  Google Scholar 

  13. Collman JP, Gagne RR, Kouba J, Lausberg-Wahren H (1974) J Am Chem Soc 96: 6800

    Article  CAS  Google Scholar 

  14. Gold DH, Gregor HP (1960) J Phys Chem 64: 1464

    Article  CAS  Google Scholar 

  15. Kesicki EA, De Rosch MA, Freeman LH, Walton CL, Harvey DF, Trogler WC (1993) Inorg Chem 32: 5851

    Article  CAS  Google Scholar 

  16. Robert A Scott, David M Dooley (1985) J Am Chem Soc 107: 4348

    Article  Google Scholar 

  17. Navon G, Panigel R (1989) Inorg Chem 28: 1405

    Article  CAS  Google Scholar 

  18. Katritzky AR, Rees CW (1984) Comp Heterocyclic Chem 5: 347

    Google Scholar 

  19. Mc Garvey JJ, Lawthers I, Heremans K, Toftlund H (1984) J Chem Soc Chem Commun 1575 (and references therein)

  20. Fuchs Y, Lofters S, Dieter T, Shi W, Morgon R, Strekas TC, Gafney HD, Baker AD (1987) J Am Chem Soc, 109: 2691

    Article  CAS  Google Scholar 

  21. Dakers MA, Hill MNS, Lockhart JC, Ruston DJ (1994) J Chem Soc, Dalton Trans 209

  22. Masciocchi N, Moret M, Cairati P, Sironi A, Attilio Ardizzoia G, La Moniea G (1995) J Chem Soc, Dalton Trans 1671 (and references therein)

  23. Mahmoud MR, Abdel-Hamide RA, Abdel Wahal AA (1982) Bull Soc Chim Belg 91: 11

    CAS  Google Scholar 

  24. Liu CY (1987) Anal Chim Acta 192 (1): 85

    Article  CAS  Google Scholar 

  25. Davies RV, Kennedy J, Lane ES, Williams JL (1959) J Appl Chem, 9: 368

    Article  CAS  Google Scholar 

  26. Ficken GE, Lane ES (1957) Anal Chim Acta 16: 207

    Article  CAS  Google Scholar 

  27. Vogel AI (1989) A Text book of quantitative inorganic analysis, 5th edn. ELBS and Longman, p 180

  28. Bhattacharyya SS, Das AK (1988) Atomic Spectrosc 9: 68

    CAS  Google Scholar 

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Chattopadhyay, P., Sinha, C. & Pal, D.K. Preparation and properties of a new chelating resin containing imidazolyl azo groups. Fresenius J Anal Chem 357, 368–372 (1997). https://doi.org/10.1007/s002160050171

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  • DOI: https://doi.org/10.1007/s002160050171

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