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Local mass transfer measurements in an inclined enclosure at high Rayleigh number

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Abstract

An electrochemical technique is used to study local mass transfer coefficients on surfaces of inclined enclosures over the range 1.1×104 < RaH < 1.4×1010 for a nominal Schmidt number of 2280. Scaling with gcosθ instead of g in the Rayleigh number correlates the data well at low angles of inclination; however, as either the aspect ratio or the angle of inclination increase, the longitudinal density stratification causes the data to deviate from a power law scaling.

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Notes

  1. We assume that for the fluid of interest, density decreases with temperature

Abbreviations

ΔCi::

Concentration difference for species i(mol/l)

Di::

Diffusion coefficient of species i (m2/s)

F::

Faraday’s constant (96,487 C/g mol)

g::

Acceleration due to gravity (9.8 m/s2)

h::

Mass transfer coefficient

H::

Thickness of fluid layer between electrodes (m)

i::

Species of interest (copper ions)

I::

Current (A)

L::

Length of cathode surface (m)

ni::

Valence of transferred ion

Pr::

Prandtl number (ν/α)

RaL::

Mass transfer Rayleigh number based on cathode length [gbulk-ρc) L3/ρν Di]

RaH::

Mass transfer Rayleigh number based on enclosure height [gbulk-ρc)H3/ρν Di]

Rax::

Local mass transfer Rayleigh number [gbulk-ρc) x3/ρν Di]

Sc::

Schmidt number (ν/Di)

Sh::

Sherwood number (hL/Di)

Shx::

Local Sherwood number (hx/Di)

ti::

Transference number

W::

Width of cathode plate (m)

x::

Position from leading edge of cathode surface (m)

δ::

Boundary layer thickness (m)

λr::

Width between adjacent rolls (m)

ν::

Kinematic viscosity (m2/s)

θ::

Angle of enclosure inclination from horizontal (degrees)

θ*::

Transition angle from longitudinal rolls to unicellular flow (degrees)

ρ::

Density (kg/m3)

References

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Goldstein, R.J., Chiang, H.D., Srinivasan, V. et al. Local mass transfer measurements in an inclined enclosure at high Rayleigh number. Heat Mass Transfer 41, 991–998 (2005). https://doi.org/10.1007/s00231-005-0630-0

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  • DOI: https://doi.org/10.1007/s00231-005-0630-0

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