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A novel preparation method of maleic anhydride grafted syndiotactic polystyrene and its blend performance with nylon6

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Summary

This work is intended to provide a method for the preparation of maleic anhydride grafted syndiotactic polystyrene (sPS-g-MA). In particular, a novel solid reaction method by a radical grafting approach is investigated. The grafting reaction is performed at a solid state, where the syndiotactic polystyrene (sPS) is swollen in solvent at relatively low temperature compared to the conventional melt modification method. The formation of sPS-g-MA is directly confirmed by Fourier transform infrared spectroscopy and by the morphology observation of sPS/polyamide-6 (Nylon6) blends, when sPS-g-MA is used as a reactive compatibilizer.

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Authors and Affiliations

  1. M-Project Team, R&D Center, Samsung General Chemicals Co. Ltd., San 222-2, Dokgod-Ri, Daesan-Up, Seosan-Si, Chung-Nam, 356-711, Republic of Korea, , , , , , KR

    Jae Gon Lim, Jung Hyun Baik & Won Mook Choi

  2. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China, , , , , , CN

    Xue Quan Zhang

  3. National Institute of Standard and Technology, Polymers Division, 100 Bureau Drive, Stop 8544, gaithersburg, MD 20899-8544 USA, , , , , , US

    Younggon Son

  4. Center of Advanced Functional Polymers, Dept. of Chemical & Biomolecular Eng., Korea Advanced Institute of Science and Technology, 373-1, Kusong-dong, Yusong-gu, Taejon, 305-701, Republic of Korea email: oopark@kaist.ac.kr, Tel.: +82-42-869-3923, Fax: +82-42-869-3910, , , , , , KR

    O Ok Park

Authors
  1. Jae Gon Lim
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  2. Jung Hyun Baik
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  3. Xue Quan Zhang
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  4. Younggon Son
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  5. Won Mook Choi
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  6. O Ok Park
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Additional information

Received: 27 February 2002 / Revised version: 26 April 2002 / Accepted: 30 April 2002

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Lim, J., Baik, J., Zhang, X. et al. A novel preparation method of maleic anhydride grafted syndiotactic polystyrene and its blend performance with nylon6. Polymer Bulletin 48, 397–405 (2002). https://doi.org/10.1007/s00289-002-0046-7

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  • DOI: https://doi.org/10.1007/s00289-002-0046-7

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