Abstract
In this work, a robust and easy-to-handle strategy was developed to fabricate silver nanoparticles (Ag NPs)-decorated filter paper as surface-enhanced Raman spectroscopy substrate using dip-coating method only with the assistance of chloride ions. Filter paper was modified with chloride ions for chemisorption of Ag NPs, overcoming the electrostatic repulsion between Ag NPs and paper. The effect of laser-induced substrate deformation was studied. The enhancement factor of the substrate was higher than 6.4 × 105 with a limit of detection of 1 × 10−8 M for 4-mercaptobenzoic acid. The Ag NPs-decorated paper substrate exhibits a good uniformity and can be stored for more than 2 months with negligible degradation. This substrate has great potential for detecting food contaminations, environment polluters and biomolecules.
Similar content being viewed by others
References
A. Campion, P. Kambhampati, Surface-enhanced Raman scattering. Chem. Soc. Rev. 27, 241 (1998)
C. Haynes, A. McFarland, R. Duyne, Surface-enhanced Raman spectroscopy. Anal. Chem. 77, 338A (2005)
D. Cialla, A. März, R. Böhme, F. Theil, K. Weber, M. Schmitt, J. Popp, Surface-enhanced Raman spectroscopy (SERS): progress and trends. Anal. Bioanal. Chem. 403, 27 (2012)
A. Craig, A. Franca, J. Irudayaraj, Surface-enhanced Raman spectroscopy applied to food safety. Annu. Rev. Food Sci. Technol. 4, 369 (2013)
X. Lin, W. Hasi, X. Lou, S. Lin, F. Yang, B. Jia, Y. Cui, D. Ba, D. Lin, Z. Lu, Rapid and simple detection of sodium thiocyanate in milk using surface-enhanced Raman spectroscopy based on silver aggregates. J. Raman Spectrosc. 2, 162–167 (2014)
R.S. Golightly, W.E. Doering, M.J. Natan, Surface-enhanced Raman spectroscopy and homeland security: a perfect match? ACS Nano 3, 2859 (2009)
K. Hering, D. Cialla, K. Ackermann, T. Dörfer, R. Möller, H. Schneidewind, R. Mattheis, W. Fritzsche, P. Rösch, J. Popp, SERS: a versatile tool in chemical and biochemical diagnostics. Anal. Bioanal. Chem. 390, 113 (2008)
L. Kang, P. Xu, B. Zhang, H. Tsai, X. Han, H.L. Wang, Laser wavelength-and power-dependent plasmon-driven chemical reactions monitored using single particle surface enhanced Raman spectroscopy. Chem. Commun. 49, 3389 (2013)
W. Xie, S. Schlücker, Medical applications of surface-enhanced Raman scattering. Phys. Chem. Chem. Phys. 15, 5329 (2013)
M. Fleischmann, P.J. Hendra, A.J. McQuillan, Raman spectra of pyridine adsorbed at a silver electrode. Chem. Phys. Lett. 26, 163 (1974)
G. Frens, Controlled nucleation for the regulation of the particle size in monodisperse gold suspensions. Nat. Phys. Sci. 241, 20 (1973)
C. Lee, D. Meisel, Adsorption and surface-enhanced Raman of dyes on silver and gold sols. J. Phys. Chem. 60439, 3391 (1982)
S.W. Lee, Y.B. Shin, K.S. Jeon, S.M. Jin, Y.D. Suh, S. Kim, J.J. Lee, M.G. Kim, Electron beam lithography-assisted fabrication of Au nano-dot array as a substrate of a correlated AFM and confocal Raman spectroscopy. Ultramicroscopy 108, 1302 (2008)
F.S. Ou, M. Hu, I. Naumov, A. Kim, W. Wu, A.M. Bratkovsky, X. Li, R.S. Williams, Z. Li, Hot-spot engineering in polygonal nanofinger assemblies for surface enhanced Raman spectroscopy. Nano Lett. 11, 2538 (2011)
N.G. Greeneltch, M.G. Blaber, A.I. Henry, G.C. Schatz, R.P. Van Duyne, Immobilized nanorod assemblies: fabrication and understanding of large area surface-enhanced Raman spectroscopy substrates. Anal. Chem. 85, 2297 (2013)
Y. Tanoue, K. Sugawa, T. Yamamuro, T. Akiyama, Densely arranged two- dimensional silver nanoparticle assemblies with optical uniformity over vast areas as excellent surface-enhanced Raman scattering substrates. Phys. Chem. Chem. Phys. 15, 15802 (2013)
S. Nie, S.R. Emory, Probing single molecules and single nanoparticles by surface-enhanced Raman scattering. Science 275, 1102 (1997)
R. Zhang, Y. Zhang, Z.C. Dong, S. Jiang, C. Zhang, L.G. Chen, L. Zhang, Y. Liao, J. Aizpurua, Y. Luo, J.L. Yang, J.G. Hou, Chemical mapping of a single molecule by plasmon-enhanced Raman scattering. Nature 498, 82 (2013)
E.W. Nery, L.T. Kubota, Sensing approaches on paper-based devices: a review. Anal. Bioanal. Chem. 405, 7573 (2013)
L. Polavarapu, L.M. Liz-Marzán, Towards low-cost flexible substrates for nanoplasmonic sensing. Phys. Chem. Chem. Phys. 15, 5288 (2013)
W.W. Yu, I.M. White, Inkjet-printed paper-based SERS dipsticks and swabs for trace chemical detection. Analyst 138, 1020 (2013)
L.L. Qu, Q.X. Song, Y.T. Li, M.P. Peng, D.W. Li, L.X. Chen, J.S. Fossey, Y.T. Long, Fabrication of bimetallic microfluidic surface-enhanced Raman scattering sensors on paper by screen printing. Anal. Chim. Acta 792, 86 (2013)
R. Zhang, B.B. Xu, X.Q. Liu, Y.L. Zhang, Y. Xu, Q.D. Chen, H.B. Sun, Highly efficient SERS test strips. Chem. Commun. 48, 5913 (2012)
S.C. Tseng, C.C. Yu, D. Wan, H.L. Chen, L.A. Wang, M.C. Wu, W.F. Su, H.C. Han, L.C. Chen, Eco-friendly plasmonic sensors: using the photothermal effect to prepare metal nanoparticle-containing test papers for highly sensitive colorimetric detection. Anal. Chem. 84, 5140 (2012)
Y. Meng, Y. Lai, X. Jiang, Q. Zhao, J. Zhan, Silver nanoparticles decorated filter paper via self-sacrificing reduction for membrane extraction surface-enhanced Raman spectroscopy detection. Analyst 138, 2090 (2013)
M.L. Cheng, B.C. Tsai, J. Yang, Silver nanoparticle-treated filter paper as a highly sensitive surface-enhanced Raman scattering (SERS) substrate for detection of tyrosine in aqueous solution. Anal. Chim. Acta 708, 89 (2011)
Y. Chen, H. Cheng, K. Tram, S. Zhang, Y. Zhao, L. Han, Z. Chen, S. Huan, A paper-based surface-enhanced resonance Raman spectroscopic (SERRS) immunoassay using magnetic separation and enzyme-catalyzed reaction. Analyst 138, 2624 (2013)
W.W. Yu, I.M. White, A simple filter-based approach to surface enhanced Raman spectroscopy for trace chemical detection. Analyst 137, 1168 (2012)
C.H. Lee, M.E. Hankus, L. Tian, P.M. Pellegrino, S. Singamaneni, Highly sensitive surface enhanced Raman scattering substrates based on filter paper loaded with plasmonic nanostructures. Analyst 138, 8953 (2011)
Y.H. Ngo, D. Li, G.P. Simon, G. Garnier, Gold nanoparticle–paper as a three-dimensional surface enhanced raman scattering substrate. Langmuir 28, 8782 (2012)
Y. Hui, D. Li, G.P. Simon, G. Garnier, Effect of cationic polyacrylamides on the aggregation and SERS performance of gold nanoparticles-treated paper. J. Colloid Interface Sci. 392, 237 (2013)
E.J. Zeman, G.C. Schatz, An accurate electromagnetic theory study of surface enhancement factors for silver, gold, copper, lithium, sodium, aluminum, gallium, indium, zinc, and cadmium. J. Phys. Chem. 91, 634 (1987)
C.J. Orendorff, A. Gole, T.K. Sau, C.J. Murphy, Surface-enhanced Raman spectroscopy of self-assembled monolayers: sandwich architecture and nanoparticle shape dependence. Anal. Chem. 77, 3261 (2005)
M.A.S. Azizi Samir, F. Alloin, A. Dufresne, Review of recent research into cellulosic whiskers, their properties and their application in nanocomposite field. Biomacromolecules 6, 612 (2005)
Y. Habibi, L.A. Lucia, O.J. Rojas, Cellulose nanocrystals: chemistry, self-assembly, and applications. Chem. Rev. 110, 3479 (2010)
X. Ji, X. Song, J. Li, Y. Bai, W. Yang, X. Peng, Size control of gold nanocrystals in citrate reduction: the third role of citrate. J. Am. Chem. Soc. 129, 13939 (2007)
S.E.J. Bell, N.M.S. Sirimuthu, Surface-enhanced Raman spectroscopy as a probe of competitive binding by anions to citrate-reduced silver colloids. J. Phys. Chem. A 109, 7405 (2005)
M. Kim, K. Itoh, pH dependence of surface-enhanced Raman scattering spectra from 2, 2′-bipyridine adsorbed on silver colloids. J. Phys. Chem. 91, 126 (1987)
L.J. Xu, C. Zong, X.S. Zheng, P. Hu, J.M. Feng, B. Ren, Label-free detection of native proteins by surface-enhanced Raman spectroscopy using iodide-modified nanoparticles. Anal. Chem. 86, 2238 (2014)
H. Liu, Y. Sun, Z. Jin, L. Yang, J. Liu, Capillarity-constructed reversible hot spots for molecular trapping inside silver nanorod arrays light up ultrahigh SERS enhancement. Chem. Sci. 4, 3490 (2013)
M.S. Schmidt, J. Hübner, A. Boisen, Large area fabrication of leaning silicon nanopillars for surface enhanced Raman spectroscopy. Adv. Mater. 24, OP11 (2012)
P. He, H. Liu, Z. Li, Y. Liu, X. Xu, J. Li, Electrochemical deposition of silver in room-temperature ionic liquids and its surface-enhanced Raman scattering effect. Langmuir 20, 10260 (2004)
C.E. Taylor, J.E.P.E.M. Berton, G.G.G. An, M.H. Schoenfisch, Surface enhancement factors for Ag and Au surfaces relative to Pt surfaces for monolayers of thiophenol. Appl. Spectrosc. 53, 1212 (1999)
J. Zheng, Y. Zhou, X. Li, Y. Ji, T. Lu, Surface-enhanced Raman scattering of 4-aminothiophenol in assemblies of nanosized particles and the macroscopic surface of silver. Langmuir 19, 632 (2003)
B. Ren, X.F. Lin, Z.L. Yang, G.K. Liu, R.F. Aroca, B.W. Mao, Z.Q. Tian, Surface-enhanced Raman scattering in the ultraviolet spectral region: UV-SERS on rhodium and ruthenium electrodes. J. Am. Chem. Soc. 125, 9598 (2003)
W.L. Zhai, D.W. Li, L.L. Qu, J.S. Fossey, Y.T. Long, Multiple depositions of Ag nanoparticles on chemically modified agarose films for surface-enhanced Raman spectroscopy. Nanoscale 4, 137 (2012)
F. Adar, E. Lee, S. Mamedov, A. Whitley, Experimental evaluation of the depth resolution of a Raman microscope. Microsc. Microanal. 16, 360 (2010)
Acknowledgments
The work was supported by the International S&T Cooperation Program of China (Grant No. 2011DFA31770).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Hasi, WLJ., Lin, X., Lou, XT. et al. Chloride ion-assisted self-assembly of silver nanoparticles on filter paper as SERS substrate. Appl. Phys. A 118, 799–807 (2015). https://doi.org/10.1007/s00339-014-8800-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-014-8800-x