Abstract
In this work, the Fe80P13C7 amorphous alloys containing a different amount of 53, 180, 241 and 270 at. ppm oxygen were synthesized and their magnetocaloric effect (MCE) was investigated. It was found that doping of oxygen can effectively regulate the Curie temperature (TC), magnetic entropy change (- ∆SM) and refrigerant capacity (RCFWHM) of alloys. Especially, with 241 ppm oxygen doping, the alloy showed TC of 597 K, - ∆SM of 2.47 J kg−1 k−1 and RCFWHM of 103.96 J kg−1 under 1.5 T, which were larger than that of most Fe-based amorphous alloys reported to date. The result from X-ray photoelectron spectroscopy confirmed that appropriate oxygen doping tends to translate interatomic bonds from p-d hybrid into Fe-Fe bonds, supporting the large TC and MCE. Our finding elucidates a new understanding of the role of oxygen in magnetic performance and may open up a new possible pathway for improving the MCE of Fe-based amorphous alloys.
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References
O. Gutfleisch, M.A. Willard, E. Brück, C.H. Chen, S.G. Sankar, J.P. Liu, Magnetic materials and devices for the 21st century: stronger, lighter, and more energy efficient. Adv. Mater. 23, 821–842 (2011)
A. Smith, C.R.H. Bahl, R. Bjãrk, K. Engelbrecht, K.K. Nielsen, N. Pryds, Materials challenges for high performance magnetocaloric refrigeration devices. Adv. Energy Mater. 2, 1288–1318 (2012)
K.A. Gschneidnerjr, V.K. Pecharsky, A.O. Tsokol, Recent developments in magnetocaloric materials. Rep. Rrog. Phys. 68, 1479–1539 (2005)
V. Franco, J.S. Blazquez, B. Ingale, A. Conde, The magnetocaloric effect and magnetic refrigeration near room temperature: materials and models. ChemInform 44, 305–342 (2013)
V.K. Pecharsky, K.A. Gschneidner, Giant magnetocaloric effect in Gd5(Si2Ge2). Appl. Phys. Lett. 78, 4494–4497 (1997)
X.B. Liu, Z. Altounian, Effect of Co content on magnetic entropy change and structure of La(Fe1 − xCox)11.4Si1.6. J. Magn. Magn. Mater. 264, 209–213 (2003)
P. Gębara, P. Pawlik, Broadening of temperature working range in magnetocaloric La(Fe Co, Si)13-based multicomposite. J. Magn. Magn. Mater. 442, 145–151 (2017)
R. Caballero-Flores, V. Franco, A. Conde, K. Knipling, M. Willard, Influence of Co and Ni addition on the magnetocaloric effect in Fe88–2xCoxNixZr7B4Cu1 soft magnetic amorphous alloys. Appl. Phys. Lett. 96, 182506 (2010)
S.J. Pang, T. Zhang, K. Asami, A. Inoue, Synthesis of Fe-Cr-Mo-C-B-P bulk metallic glasses with high corrosion resistance. Acta Mater. 50, 489–497 (2002)
W.M. Yang, H.S. Liu, Y.C. Zhao, A. Inoue, K. Jiang, J.T. Huo, H. Ling, Q. Li, B.L. Shen, Mechanical properties and structural features of novel Fe-based bulk metallic glasses with unprecedented plasticity. Sci. Rep. 4, 6233–6239 (2014)
J.W. Li, J.Y. Law, H.R. Ma, A.N. He, Q.K. Man, H. Men, J.T. Huo, C.T. Chang, X.M. Wang, R.W. Li, Magnetocaloric effect in Fe–Tm–B–Nb metallic glasses near room temperature. J. Non-Cryst. Solids 425, 114–117 (2015)
F. Hu, Q. Luo, B.L. Shen, Thermal, magnetic and magnetocaloric properties of FeErNbB metallic glasses with high glass-forming ability. J. Non-Cryst. Solids 512, 184–188 (2019)
A. Waske, B. Schwarz, N. Mattern, J. Eckert, Magnetocaloric (Fe-B)-based amorphous alloys. J. Magn. Magn. Mater. 329, 101–104 (2013)
D.A. Shishkin, A.S. Volegov, N.V. Baranov, The thermomechanical stability of Fe-based amorphous ribbons exhibiting magnetocaloric effect. Appl. Phys. A 122, 1002–1007 (2016)
Y.Y. Wang, K. Hou, X.F. Bi, Hydrogenated Fe90M10 (M: Zr and Sc) amorphous alloys with enhanced room-temperature magnetocaloric effect. J. Alloys Compd. 689, 564–569 (2016)
J.W. Li, J.Y. Law, J.T. Huo, A.N. He, Q.K. Man, C.T. Chang, H. Men, J.Q. Wang, X.M. Wang, R.W. Li, Magnetocaloric effect of Fe-RE-B-Nb (RE = Tb, Ho or Tm) bulk metallic glasses with high glass-forming ability. J. Alloys Compd. 644, 346–349 (2015)
A. Kupczyk, J. Swierczek, M. Hasiak, K. Prusik, J. Zbroszczyk, P. Gębara, Microstructure and some thermomagnetic properties of amorphous Fe-(Co)-Mn-Mo-B alloys. J. Alloys Compd. 735, 253–260 (2018)
H.Y. Zhang, R. Li, T. Xu, F.M. Liu, T. Zhang, Near room-temperature magnetocaloric effect in FeMnPBC metallic glasses with tunable Curie temperature. J. Magn. Magn. Mater. 347, 131–135 (2013)
G.F. Wang, H.L. Li, Z.R. Zhao, X.F. Zhang, Stable magnetocaloric effect and refrigeration capacity in Co-doped FeCoMnZrNbB amorphous ribbons near room temperature. J. Alloys Compd. 692, 793–796 (2016)
P. Gębara, M. Hasiak, Investigation of critical behavior in the vicinity of ferromagnetic to paramagnetic phase transition in the Fe75Mo8Cu1B16 alloy. J. Appl. Phys. 124, 083904 (2018)
A. Łukiewska, J. Olszewskia, M. Hasiakb, P. Gębara, Magnetocaloric effect in amorphous and partially crystallized Fe80Zr7Cr6Nb2Cu1B4 alloy. Acta Phys. Pol. A 133, 676–679 (2018)
Y.Y. Wang, X.F. Bi, The role of Zr and B in room temperature magnetic entropy change of FeZrB amorphous alloys. Appl. Phys. Lett. 95, 262501 (2009)
Z.F. Lei, X.J. Liu, Y. Wu, H. Wang, S.H. Jiang, S.D. Wang, X.D. Hui, Y.D. Wu, B. Gault, P. Kontis, D. Raabe, L. Gu, Q.H. Zhang, H.W. Chen, H.T. Wang, J.B. Liu, K. An, Q.S. Zeng, T.G. Nieh, Z.P. Lu, Enhanced strength and ductility in a high-entropy alloy via ordered oxygen complexes. Nature 563, 546–550 (2018)
W.M. Yang, J. Huo, H.S. Liu, J.W. Li, L.J. Song, Q. Li, L. Xue, B.L. Shen, A. Inoue, Extraordinary magnetocaloric effect of Fe-based bulk glassy rods by combining fluxing treatment and J-quenching technique. J. Alloys Compd. 684, 29–33 (2016)
C. Liu, Q. Li, J.T. Huo, L. Xie, W.M. Yang, C.T. Chang, Y.F. Sun, Effect of preparation cooling rate on magnetocaloric effect of Fe80P13C7 amorphous alloy. J. Magn. Magn. Mater. 475, 249–256 (2019)
H.X. Li, J.E. Gao, Z.B. Jiao, Y. Wu, Z.P. Lu, Glass-forming ability enhanced by proper additions of oxygen in a Fe-based bulk metallic glass. Appl. Phys. Lett. 95, 161905 (2009)
C.T. Chang, J.H. Zhang, B.L. Shen, W.H. Wang, A. Inoue, Pronounced enhancement of glass-forming ability of Fe–Si–B–P bulk metallic glass in oxygen atmosphere. J. Mater. Res. 29, 1217–1222 (2014)
J. Pang, K.Q. Qiu, C.J. Wang, D.P. Wang, A.D. Wang, C.T. Chang, X.M. Wang, C.T. Liu, Oxidation and refreshing behaviors of P-containing Fe-based amorphous ribbons. J. Non-Crystal. Solids 471, 137–141 (2017)
X.D. Fan, H. Men, A.B. Ma, B.L. Shen, Soft magnetic properties in Fe84-xB10C6Cux nanocrystalline alloys. J. Magn. Magn. Mater. 326, 22–27 (2013)
R. O’handley, Physics of ferromagnetic amorphous alloys. J. Appl. Phys. 62, 15–49 (1987)
H.B. Ling, Q. Li, H.X. Li, J.J. Zhang, C.T. Chang, S. Yi, Preparation and characterization of quaternary magnetic Fe80-xCoxP14B6 bulk metallic glasses. J. Appl. Phys. 115, 330–332 (2014)
M.Q. Zuo, S.Y. Meng, Q. Li, H.X. Li, C.T. Chang, Y.F. Sun, Effect of metalloid elements on magnetic properties of Fe-based bulk metallic glasses. Intermetallics 83, 83–86 (2017)
C.M. Pang, L. Chen, H. Xu, W. Guo, Z.W. Lv, J.T. Huo, M.J. Cai, B.L. Shen, X.L. Wang, C.C. Yuan, Effect of Dy, Ho, and Er substitution on the magnetocaloric properties of Gd–Co–Al–Y high entropy bulk metallic glasses. J. Alloys Compd. 827, 154101 (2020)
T. Hashimoto, T. Numasawa, M. Shino, T. Okada, Magnetic refrigeration in the temperature range from 10 K to room temperature: the ferromagnetic refrigerants. Cryogenics 21, 647–653 (1981)
M.E. Wood, W.H. Potter, General analysis of magnetic refrigeration and its optimization using a new concept: Maximization of refrigerant capacity. Cryogenics 25, 667–683 (1985)
P. Gebara, M. Hasiak, Determination of phase transition and critical behavior of the as-cast GdGeSi-(x) type alloys (where x = Ni, Nd and Pr). Materials 14, 185–197 (2021)
I. Chihi, M. Baazaoui, S. Mahjoub, W. Cheikhrouhou-Koubaa, M. Oumezzine, K. Farah, Study of the magnetic and magnetocaloric properties of new perovskite-type materials: La0.6Ba0.2Sr0.2Mn1−xFexO3. Appl. Phys. A 125, 627–634 (2019)
P. Gębara, Á. Díaz-García, J.Y. Law, V. Franco, Magnetocaloric response of binary Gd–Pd and ternary Gd-(Mn, Pd) alloys. J. Magn. Magn. Mater. 500, 166175 (2020)
A. Kaal, O.E. Marrakechi, S. Sayouri, M. Tlemçani, H. Lassri, M. Kellati, Magnetic exchange coupling in amorphous Fe82-xHoxB18 alloys. Phys. B 325, 98–105 (2003)
H. Chen, S.X. Zhou, B.S. Dong, J.J. Jin, T.Q. Liu, P.F. Guan, A general rule for transition metals doping on magnetic properties of Fe-based metallic glasses. J. Alloys Compd. 819, 153062 (2020)
S. Das, K. Choudhary, A. Chernatynskiy, H.C. Yim, A.K. Bandyopadhyay, S. Mukherjee, Spin-exchange interaction between transition metals and metalloids in soft-ferromagnetic metallic glasses. J. Phys. Condens. Matter 28, 216003 (2016)
P. Oelhafen, E. Hauser, H.J. Güntherodt, K.H. Bennemann, New type of d-band-metal alloys: the valence-band structure of the metallic glasses Pd–Zr and Cu–Zr. Phys. Rev. Lett. 43, 1134–1137 (1979)
H.X. Li, C.Q. Li, D. Cao, W.M. Yang, Q. Li, Z.P. Lu, Influences of oxygen on plastic deformation of a Fe-based bulk metallic glass. Scripta Mater. 135, 24–28 (2017)
C.C. Yuan, J.F. Xiang, X.K. Xi, W.H. Wang, NMR signature of evolution of ductile-to-brittle transition in bulk metallic glasses. Phys. Rev. Lett. 107, 236403 (2011)
S.X. Zhou, B.S. Dong, J.Y. Qin, D.R. Li, S.P. Pan, X.F. Bian, Z.B. Li, The relationship between the stability of glass-forming Fe-based liquid alloys and the metalloid-centered clusters. J. Appl. Phys. 112, 023514 (2012)
X.M. Xue, H.G. Jiang, Z.T. Sui, B.Z. Ding, Z.Q. Hu, Influence of phosphorus addition on the surface tension of liquid iron and segregation of phosphorus on the surface of Fe–P alloy. Metal. Mater. Tran. B 27, 71–79 (1996)
Q. Luo, B. Schwarz, N. Mattern, J. Shen, J. Eckert, Roles of hydrogenation, annealing and field in the structure and magnetic entropy change of Tb-based bulk metallic glasses. AIP Adv. 3, 032134 (2013)
P. Yu, J.Z. Zhang, L. Xia, Fe87Zr7B4Co2 amorphous alloy with excellent magneto-caloric effect near room temperature. Intermetallics 95, 85–88 (2018)
V. Franco, A. Conde, L.F. Kiss, Magnetocaloric response of FeCrB amorphous alloys: Predicting the magnetic entropy change from the Arrott–Noakes equation of state. J. Appl. Phys. 104, 033903 (2008)
J.Y. Law, R.V. Ramanujan, V. Franco, Tunable curie temperatures in Gd alloyed Fe-B-Cr magnetocaloric materials. J. Alloys Compd. 508, 14–19 (2010)
Acknowledgements
This work was supported by the University Natural Science Research Project of Anhui Province (Grant No. KJ2020A0225), the Open Project of Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials (Grant No. GFST2020KF05) and the Youth Foundation of Anhui University of Technology (Grant No. QZ202004).
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Hou, L., Xiang, X., Huang, Y. et al. Influences of oxygen on the magnetocaloric properties of a Fe-based amorphous alloy. Appl. Phys. A 127, 501 (2021). https://doi.org/10.1007/s00339-021-04659-7
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DOI: https://doi.org/10.1007/s00339-021-04659-7