From two-dimensional model networks to microcapsules

Abstract.

The synthesis of microcapsules for technical, cosmetic, and pharmaceutical purposes has attracted much interest in recent years. The design of new capsules requires profound knowledge of their mechanical properties. Rheological studies provide interesting information on intrinsic membrane features and they can also be used to obtain information on bursting processes and shear-induced release of encapsulated compounds. In this article we shall discuss the basic rheological properties of different types of ultra-thin membranes, which can be used to form stable capsules walls. We have also analyzed the typical structures of these cross-linked films using Brewster-angle microscopy. Tiny oil or water droplets, which are surrounded by ultra-thin membranes, form simple types of microcapsules. In addition to the interface shear rheology, we have measured the Young's modulus (elongational modulus) and the Poisson ratio using a modified spinning drop apparatus. The shear-induced deformation and orientation of microcapsules was investigated in optical rheometers (rheoscopes). In the regime of small deformations the results were in fairly good agreement with a theoretical model recently proposed by Barthès-Biesel. Due to the simple synthesis and well-defined structure, microcapsules can also serve as model systems to understand the complicated flow properties of red blood cells (erythrocytes).