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Determination of rutin using a CeO2 nanoparticle-modified electrode

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Abstract.

CeO2 nanoparticles approximately 12 nm in size were synthesized and subsequently characterized by XRD, TEM and UV-vis spectroscopy. Then, a gold electrode modified with CeO2 nanoparticles was constructed and characterized by electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV). The modified electrode demonstrated strong catalytic effects with high stability towards electrochemical oxidation of rutin. The anodic peak currents (measured by differential pulse voltammetry) increased linearly with the concentration of rutin in the range of 5.0 × 10−7–5.0 × 10−4 mol · L−1. The detection limit (S/N = 3) was 2.0 × 10−7 mol · L−1. The relative standard deviation (RSD) of 8 successive scans was 3.7% for 5.0 × 10−6 mol · L−1 rutin. The method showed excellent sensitivity and stability, and the determination of rutin in tablets was satisfactory.

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Authors and Affiliations

  1. School of Chemistry and Materials Science, Anhui Normal University, 241000, Wuhu, P.R. China

    Yan Wei, Guangfeng Wang, Maoguo Li, Cong Wang & Bin Fang

  2. Department of Chemistry, Wannan Medical College, 241001, Wuhu, P.R. China

    Yan Wei

  3. Anhui Key Laboratory of Functional Molecular Solids, 241000, Wuhu, P.R. China

    Guangfeng Wang, Maoguo Li & Bin Fang

Authors
  1. Yan Wei
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  2. Guangfeng Wang
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  3. Maoguo Li
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  4. Cong Wang
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  5. Bin Fang
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Correspondence to Bin Fang.

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Wei, Y., Wang, G., Li, M. et al. Determination of rutin using a CeO2 nanoparticle-modified electrode. Microchim Acta 158, 269–274 (2007). https://doi.org/10.1007/s00604-006-0716-5

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  • DOI: https://doi.org/10.1007/s00604-006-0716-5

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