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Dynamic gas extraction of iodine in combination with a silver triangular nanoplate-modified paper strip for colorimetric determination of iodine and of iodine-interacting compounds

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Abstract

A method is described for sensitive and selective detection of iodine by using a paper strip modified with silver triangular nanoplates (AgTNPs). It is based on the extraction of iodine from a solution into a flow of air via dynamic gas extraction and transferring it through a reactive paper modified with AgTNPs. The interaction of AgTNPs with iodine results in a color change from blue to white. This can be visually detected and monitored by digital colorimetry. The dynamic gas extraction is highly selective for volatile compounds so that a sample pretreatment is minimal. Due to the sensitivity of AgTNPs for iodine, the limit of its detection is as low as 7 μg L−1, and the analytical range is of 20–200 μg L−1. The method also was applied in a new approach for determination of organic compounds that can interact with iodine. The organic compound is exposed to an excess of iodine, and this is followed by detection of residual iodine as described above. The method was applied to the determination of ascorbic acid, caffeine and the drug metamizole.

Schematic representation of a procedure of organic iodine-interacting compounds (Org.) determination. It is based on their iodination followed by gas extraction of the residual iodine, its interaction with silver triangular nanoplates and colorimetric detection with a scanner.

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Acknowledgements

This work was supported by the Russian Foundation for Basic Research [grant number 18-53-00014-Bel_a] and the Belarusian Republican Foundation for Fundamental Research [grant number F18R-237].

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Authors and Affiliations

  1. Department of Chemistry, Southern Federal University, Zorge St., 7, 344090, Rostov-on-Don, Russia

    Marina O. Gorbunova & Anastasiya A. Baulina

  2. Pharmaceutical Faculty, Rostov State Medical University of the Ministry of Healthcare of Russian Federation, Nakhichevansky lane, 29, 344022, Rostov-on-Don, Russia

    Marina O. Gorbunova & Margarita S. Kulyaginova

  3. Department of Chemistry, Lomonosov Moscow State University, Leninskie gory, 1/3, 119991, Moscow, Russia

    Vladimir V. Apyari, Aleksei A. Furletov, Vladimir E. Bochenkov & Stanislava G. Dmitrienko

  4. Scientific-Research Institute of Chemical Reagents and Special Purity Chemicals of National Research Center “Kurchatov Institute”, Bogorodsky Val St., 3, 107076, Moscow, Russia

    Pavel A. Volkov

  5. B.I. Stepanov Institute of Physics, National Academy of Science of Belarus, Nezalezhnasti Ave., 68-2, 220072, Minsk, Belarus

    Aleksandr S. Starukhin

Authors
  1. Marina O. Gorbunova
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  2. Anastasiya A. Baulina
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  3. Margarita S. Kulyaginova
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  4. Vladimir V. Apyari
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  5. Aleksei A. Furletov
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  7. Vladimir E. Bochenkov
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Correspondence to Vladimir V. Apyari.

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Gorbunova, M.O., Baulina, A.A., Kulyaginova, M.S. et al. Dynamic gas extraction of iodine in combination with a silver triangular nanoplate-modified paper strip for colorimetric determination of iodine and of iodine-interacting compounds. Microchim Acta 186, 188 (2019). https://doi.org/10.1007/s00604-019-3300-5

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