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1D and 2D Systems Derived from Polynuclear [ML(N3)2] n (M = Zn(II) or Cd(II) and L is 2-Picoline-N-oxide or 4-Methylpyrimidine)

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Summary.

Four new polynuclear complexes: [Zn(2picNO)(N3)2] n , [Zn(4Mepym)(N3)2] n , [Cd(2picNO)(N3)2] n , and [Cd(4Mepym)(N3)2] n (2picNO = 2-picoline-N-oxide and 4Mepym = 4-methylpyrimidine) have been synthesized and characterized by single-crystal X-ray diffraction. The structures of the zinc(II) complexes feature five-coordinate zinc atoms, (μ-1,1) azido bridges, monodentate organic ligands, and 1D chains. The cadmium(II) azide complexes contain distorted octahedral metal atoms linked by alternate di-(μ-1,1) and di-(μ-1,3) azido bridges in cis arrangement and these chains are connected by 2picNO bridges giving a honeycomb 2D framework or by 4Mepym bridges forming extended 2D network structure.

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Authors and Affiliations

  1. Institut für Physikalische und Theoretische Chemie, Technische Universität Graz, A-8010, Graz, Austria

    Franz A. Mautner & Christian Gspan

  2. Department of Chemistry, Faculty of Science, Alexandria University, P.O. Box 426 Ibrahimia, 21321, Alexandria, Egypt

    Mohamed A. S. Goher & Morsy A. M. Abu-Youssef

Authors
  1. Franz A. Mautner
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  2. Christian Gspan
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  3. Mohamed A. S. Goher
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  4. Morsy A. M. Abu-Youssef
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Correspondence to Franz A. Mautner.

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Mautner, F., Gspan, C., Goher, M. et al. 1D and 2D Systems Derived from Polynuclear [ML(N3)2] n (M = Zn(II) or Cd(II) and L is 2-Picoline-N-oxide or 4-Methylpyrimidine). Monatshefte für Chemie 136, 107–117 (2005). https://doi.org/10.1007/s00706-004-0240-4

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  • DOI: https://doi.org/10.1007/s00706-004-0240-4

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