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Synthesis of 2,3-Dihydrothiopyran-4-ones from 3-Oxo-1-pentene-4-ynes

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Summary.

3-Oxo-1-pentene-4-ynes were converted with sodium sulfide or hydrogensulfide to give 2,6-disubstituted 2,3-dihydrothiopyran-4-one derivatives. The starting materials were prepared in two steps from terminal alkynes and α,β-unsaturated aldehydes.

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Authors and Affiliations

  1. Institut für Reine und Angewandte Chemie, Carl von Ossietzky-Universität Oldenburg, Oldenburg, Germany

    Anna Rosiak & Jens Christoffers

  2. Institut für Organische Chemie, Universität Stuttgart, Stuttgart, Germany

    Anna Rosiak & Ralf M. Müller

Authors
  1. Anna Rosiak
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  2. Ralf M. Müller
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  3. Jens Christoffers
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Correspondence to Jens Christoffers.

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Rosiak, A., Müller, R. & Christoffers, J. Synthesis of 2,3-Dihydrothiopyran-4-ones from 3-Oxo-1-pentene-4-ynes. Monatsh. Chem. 138, 13–26 (2007). https://doi.org/10.1007/s00706-006-0571-4

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  • DOI: https://doi.org/10.1007/s00706-006-0571-4

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