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Synthesis, characteristics and biological activity of pentacoordinated spirophosphoranes derived from amino acids

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Summary.

The reactions of phosphorus trichloride with various amino acids afford the pentacoordinated spirophosphoranes. The reaction procedures were traced by 31P NMR spectra techniques. A new crystal structure of alanine derivative was characterized, which is a slightly distorted TBP structure. Besides, this kind of spirophosphoranes are potent inhibitors to tyrosinase.

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Authors and Affiliations

  1. Department of Chemistry, The Key Laboratory for Chemical Biology of Fujian Province, Xiamen University, Xiamen, China

    L. Yu, Z. Liu, H. Fang, Q. L. Zeng & Y. F. Zhao

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  1. L. Yu
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  2. Z. Liu
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  3. H. Fang
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  4. Q. L. Zeng
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  5. Y. F. Zhao
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Yu, L., Liu, Z., Fang, H. et al. Synthesis, characteristics and biological activity of pentacoordinated spirophosphoranes derived from amino acids. Amino Acids 28, 369–372 (2005). https://doi.org/10.1007/s00726-005-0207-8

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  • DOI: https://doi.org/10.1007/s00726-005-0207-8

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